摘要:
An absorbent regenerator 15 is divided into at least two parts and includes: a rich solution supply line L 1 through which a rich solution 14 is supplied to the absorbent regenerator 15 from a CO 2 absorber 13; a lean solution supply line L 2 through which a lean solution 16 is supplied to the CO 2 absorber 13 from the absorbent regenerator 15; a lean-rich solution heat exchanger 17 that is provided at an intersection of the lean solution supply line L 2 and the rich solution supply line L 1 to exchange heat between the lean solution 16 and the rich solution 14; a branch portion 18 that branches some 14a of the rich solution 14 at a downstream side of the lean-rich solution heat exchanger 17 on the rich solution supply line L 1 ; and a first mixing portion 20a that mixes the some 14a of the rich solution 14 branched at the branch portion 18 with a semi-lean solution 19 in which CO 2 has been partially removed from the rich solution 14 in the absorbent regenerator 15.
摘要:
An absorption column 13 is equipped with: a CO 2 absorption section 13A for absorbing CO 2 from CO 2 -containing exhaust gas 11A using a lean solution 12B; a main rinse section 13C for recovering an entrained CO 2 absorbent using rinse water 20; a rinse water circulation line L 1 for circulating a rinse water 20 containing the CO 2 absorbent recovered in a liquid storage section 21 of the main rinse section 13C; a pre-rinse section 13B provided between the CO 2 absorption section 13A and the main rinse section 13C; a rinse section extraction liquid supply line L 2 for extracting a portion 20a of the rinse water 20 containing the CO 2 absorbent from the rinse water circulation line L 1 , and introducing the same into a reflux section 17 of an absorption liquid regeneration tower 14; and a refluxed water supply line L 3 for extracting a portion of refluxed water from a side closer to a column bottom part of the reflux section 17 than an introduction position thereof, introducing the same as pre-rinse water 20b for the pre-rinse section 13B, and connected on the pre-rinse section 13B side.
摘要:
A composite amine absorbent is an absorbent dissolved in water for absorbing CO 2 or H 2 S in gas, or both of them, which comprises: 1) at least one amine compound, and 2) a disulfide compound as an oxidative degradation inhibitor for the absorbent, wherein the disulfide compound is a compound represented by the following Chemical Formula (I).
R 1 -S - S-R 2 ·· · (I)
in the formula, R 1 or R 2 is any one of an alkyl group with 1 to 4 carbon atoms, a hydroxyethyl group, a carboxyethyl group, a cyclohexyl group, and a dibutylthiocarbamoyl group.
摘要:
An absorbing liquid which absorbs the CO 2 or H 2 S or both contained in a gas, and which comprises 1) at least one tertiary-monoamine main agent selected from a tertiary-monoamine group and 2) at least one secondary-diamine first additive selected from a secondary-diamine group, the secondary-diamine concentration being within the range of 0.05 to 0.5 in terms of the additive concentration index represented by the following expression (I). (Additive concentration index) = [(secondary-diamine acid dissociation index) (pKa)/(tertiary-monoamine acid dissociation index) (pKa)] (index ratio) × [(secondary-diamine molar concentration) (mol/L)/(tertiary-monoamine molar concentration) (mol/L)] (molar ratio) (I).
摘要:
A gas-liquid contactor is obtained by including a header pipe (101) for supplying washing water (20a), a kind of liquid, in a direction perpendicular to a vertical axis direction, the header pipe being disposed above a packed bed contacting section (110) through which exhaust gas (11A), a kind of gas, moves upward and passes; and spray nozzles (102) for discharging spray water (105), the nozzles being disposed, in an upward orientation, with predetermined intervals on the header pipe (101). Next, the spray water (105) that has been discharged from the spray nozzles (102) is supplied at a low liquid flow rate. Also, the discharged spray water (105) becomes a liquid film (105a) and falls downward along the surface of the header pipe (101), and then falls and spreads in the packed bed contacting section (110), so that the liquid (washing water (20a)) is made to contact the gas (exhaust gas (11A)) moving upward through the packed bed contacting section (110). Accordingly, the washing water (20a) is used to clear and remove water-soluble substances contained in the exhaust gas (11A).
摘要:
A gas-liquid contactor is obtained by including a header pipe (101) for supplying washing water (20a), a kind of liquid, in a direction perpendicular to a vertical axis direction, the header pipe being disposed above a packed bed contacting section (110) through which exhaust gas (11A), a kind of gas, moves upward and passes; and spray nozzles (102) for discharging spray water (105), the nozzles being disposed, in an upward orientation, with predetermined intervals on the header pipe (101). Next, the spray water (105) that has been discharged from the spray nozzles (102) is supplied at a low liquid flow rate. Also, the discharged spray water (105) becomes a liquid film (105a) and falls downward along the surface of the header pipe (101), and then falls and spreads in the packed bed contacting section (110), so that the liquid (washing water (20a)) is made to contact the gas (exhaust gas (11A)) moving upward through the packed bed contacting section (110). Accordingly, the washing water (20a) is used to clear and remove water-soluble substances contained in the exhaust gas (11A).