公开(公告)号：EP3505345A1

公开(公告)日：2019-07-03

申请号：EP17843747.1

申请日：2017-08-25

申请人： Mitsui Chemicals, Inc. ,  Chemat Technology, Inc.

发明人： HANAWA, Takayuki ,  OKAZAKI, Koju ,  OHSHIMIZU, Kaoru ,  OIKI, Motoharu ,  TAKAMATSU, Ken ,  ZHENG, Haixing

IPC分类号： B32B27/30 ,  B05D5/00 ,  B05D5/06 ,  G02B1/11 ,  C09J133/00

摘要： It is a main object of the present invention to impart higher antifogging properties and antireflective function to the hydrophilic material formed of a crosslinked resin and having a surface enriched with hydrophilic groups, which material was previously proposed by the inventors. The laminate of the present invention includes a water absorbing layer (B), an antireflective function-imparting layer (C) and a hydrophilic layer (A) provided in this order on a substrate, wherein the hydrophilic layer (A) is formed of a crosslinked resin having an anionic, cationic or nonionic hydrophilic group, and has a gradient of hydrophilic groups (intensity of hydrophilic group on surface of the hydrophilic layer (A)/intensity of hydrophilic group at 1/2 of thickness of the hydrophilic layer (A)) of not less than 1.1; the water absorbing layer (B) is formed of a crosslinked resin having a water absorption rate per unit mass (g) of in the range of 5 to 500 wt%; and the refractive index of a layer forming the layer (C) satisfies a specific condition.

公开(公告)号：EP3505344A1

公开(公告)日：2019-07-03

申请号：EP17843746.3

申请日：2017-08-25

申请人： Mitsui Chemicals, Inc.

发明人： HANAWA, Takayuki ,  OKAZAKI, Koju

IPC分类号： B32B27/30 ,  B05D5/00 ,  C09D133/00

摘要： It is a main object of the present invention to impart higher antifogging properties to the hydrophilic material formed of a crosslinked resin, having a surface enriched with hydrophilic groups, previously proposed by the inventors. The laminate of the present invention includes a water absorbing layer (B) and a hydrophilic layer (A) provided in this order on a substrate, wherein the hydrophilic layer (A) is formed of a crosslinked resin having an anionic, cationic or nonionic hydrophilic group, and has a gradient of hydrophilic groups (intensity of hydrophilic group on surface of the hydrophilic layer (A)/intensity of hydrophilic group at 1/2 of thickness of the hydrophilic layer (A)) of not less than 1.1; and the water absorbing layer (B) is formed of a crosslinked resin having a water absorption rate per unit mass (g) of in the range of 5 to 500 wt%.

公开(公告)号：EP3270192A1

公开(公告)日：2018-01-17

申请号：EP16761746.3

申请日：2016-03-08

申请人： Mitsui Chemicals, Inc.

发明人： OKAZAKI, Koju ,  HANAWA, Takayuki

IPC分类号： G02B1/118 ,  B32B3/30 ,  C08J5/18 ,  G02B1/18 ,  G02B5/30

CPC分类号： B32B3/30 ,  B32B15/04 ,  B32B2307/412 ,  B32B2307/42 ,  B32B2457/20 ,  C08J5/18 ,  G02B1/118 ,  G02B1/18 ,  G02B5/30 ,  G02B5/3058

摘要： In the present invention, there is provided a hydrophilic monolayer film that is excellent in antifogging properties, antifouling properties, the durability of antifogging properties and antifouling properties, and smoothness and that has an antireflective function or a surface structure that serves as a polarizer. There is also provided a method for easily producing such a monolayer film. The monolayer film that is to be produced has a surface structure with multiple protrusions and depressions. The distance between the peaks of adjoining protrusions among such multiple protrusions is in the range of 1 nm to 800 nm. The monolayer film is formed of a crosslinked resin produced by curing of a polymerizable composition that contains a compound having a specific hydrophilic group and a functional group with a polymerizable carbon-carbon double bond and a compound having two or more (meth)acryloyl groups. A gradient of the concentration of hydrophilic groups (Sa2/Da2) in the monolayer film is not less than 1.1 wherein Sa is the concentration of at least one type of hydrophilic groups selected from anionic hydrophilic groups, cationic hydrophilic groups, and a hydroxyl group at the top layer, and Da is the depth concentration of the hydrophilic groups at 1/2 of the thickness of the monolayer film.

摘要翻译： 在本发明中，提供了一种具有优异的防雾性，防污性，防雾性和防污性以及平滑性并且具有防反射功能或用作偏振片的表面结构的亲水性单层膜。 还提供了一种容易生产这种单层膜的方法。 要生产的单层膜具有带多个凸起和凹陷的表面结构。 这种多个突起之间的相邻突起的峰之间的距离在1nm至800nm的范围内。 单层膜由交联树脂形成，所述交联树脂通过使包含具有特定亲水性基团和具有可聚合碳 - 碳双键的官能团的化合物的聚合性组合物与具有两个或更多个（甲基）丙烯酰基的化合物固化而产生。 单层膜中亲水基团浓度（Sa2 / Da2）的梯度不小于1.1，其中Sa是至少一种选自阴离子亲水基团，阳离子亲水基团和羟基的亲水基团的浓度， 顶层，Da是单层膜厚度的1/2处的亲水基团的深度浓度。

公开(公告)号：EP2985324A1

公开(公告)日：2016-02-17

申请号：EP14782728.1

申请日：2014-04-07

申请人： Mitsui Chemicals, Inc.

发明人： OKAZAKI, Koju ,  HANAWA, Takayuki ,  KUMA, Shigetoshi

IPC分类号： C09D143/00 ,  B32B27/28 ,  C09D5/02 ,  C09D5/16 ,  C09D7/12 ,  C09D201/02 ,  C09D201/06 ,  C09D201/10

CPC分类号： C09D133/26 ,  B32B27/283 ,  B32B2307/21 ,  B32B2307/554 ,  B32B2307/712 ,  B32B2307/718 ,  B32B2307/728 ,  B32B2551/00 ,  C09D5/02 ,  C09D5/16 ,  C09D5/1668 ,  C09D7/40 ,  C09D133/068 ,  C09D133/14 ,  C09D143/00 ,  C09D143/04 ,  C09D201/10

摘要： Provided are a film in which the balance between hydrophilicity and abrasion resistance is superior, decrease in hydrophilicity by water is minimal, and the weather resistance is also superior; as well as a polymer and a polymer composition that can yield such a film. The film of the invention is prepared from a specific copolymer (i) having a sulfonic acid-containing group, an epoxy group, and a specific alkoxysilyl group in a molecule, or from a composition including the copolymer (i).

摘要翻译： 提供亲水性和耐磨性之间的平衡优异的膜，水的亲水性降低，耐候性也优异; 以及可产生这种膜的聚合物和聚合物组合物。 本发明的膜由分子中具有含磺酸基，环氧基和特定烷氧基甲硅烷基的特定共聚物（i）或包含共聚物（i）的组合物制备。

公开(公告)号：EP3138862A1

公开(公告)日：2017-03-08

申请号：EP15785524.8

申请日：2015-04-30

申请人： Mitsui Chemicals, Inc.

发明人： HANAWA, Takayuki ,  KUMA, Shigetoshi

IPC分类号： C08G18/38 ,  C08G18/24 ,  C08K5/521 ,  C08L75/04 ,  G02B1/04 ,  G02C7/02

CPC分类号： C08K5/521 ,  B29D11/00442 ,  C08G18/24 ,  C08G18/242 ,  C08G18/38 ,  C08G18/3876 ,  C08G18/388 ,  C08G18/755 ,  C08L75/04 ,  G02B1/04 ,  G02C7/02

摘要： Provided is a polymerizable composition for an optical material including (A) isocyanates having two or more isocyanato groups, which include at least an isophorone diisocyanate, (B) at least one predetermined thiol having two or more mercapto groups, (C) an acidic phosphoric acid ester represented by General Formula (1), and (D) a tin compound represented by General Formula (2), in which the acidic phosphoric acid ester (C) is contained in an amount of 0.05 parts by weight to 0.9 parts by weight, with respect to a total of 100 parts by weight of the isocyanates (A) and the thiols (B), and the tin compound (D) is contained in such an amount that the content of tin is 0.05 parts by weight to 0.3 parts by weight, with respect to a total of 100 parts by weight of the isocyanates (A) and the thiols (B).

摘要翻译： 提供了一种用于在光学材料，其包括（A）异氰酸酯具有两个或更多异氰酸酯基团，其包括至少在异佛尔酮二异氰酸酯，（B）至少一个预定的硫醇具有两个或更多个巯基在酸性磷酸酯可聚合组合物，（C） 由通式（1），和（D）锡化合物由通式（2）表示，其中，所述酸性磷酸酯（C）是在0.05份的量（重量）（重量）载于0.9份代表羧酸酯 ，与按重量计异氰酸酯（A）和硫醇（B）的相对于总量为100份，和锡化合物（D）包含在寻求量做了锡的含量为12:05重量份至0.3份 按重量计，以重量计异氰酸酯（A）和硫醇（B）的相对于总计100重量份。