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    Process for preparing ethylene-alpha-olefin-nonconjugated polyene random copolymer, copolymer obtained thereby, and uses of the copolymer
    3.
    发明公开
    Process for preparing ethylene-alpha-olefin-nonconjugated polyene random copolymer, copolymer obtained thereby, and uses of the copolymer 失效
    一种用于生产乙烯/α-烯烃/非共轭Polyenkopolymeren的过程中，共聚物如此制备和它们的用途

    公开(公告)号：EP1323749A2

    公开(公告)日：2003-07-02

    申请号：EP03004253.5

    申请日：1995-12-20

    申请人： MITSUI CHEMICALS, INC.

    发明人： Sagane, Toshihiro ,  Tsutsui, Toshiyuki ,  Kawasaki, Masaaki ,  Okada, Keiji ,  Nakahama, Hidenari ,  Tojo, Tetsuo

    IPC分类号： C08F210/18

    CPC分类号： C08F210/18 ,  C08F4/65912 ,  C08F4/65927 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08L9/00 ,  C08L23/16 ,  C08L91/00 ,  C08L2312/00 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  Y10S526/943 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/17 ,  C08F2500/21 ,  C08F210/14 ,  C08F210/08

    摘要： Disclosed is an ethylene-α-olefin-nonconjugated polyene random copolymer having such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the α-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 64/36 [(a)/(b)], (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (η) is more than 0.3 dl/g and less than 5.0 10 dl/g, (iv) the intensity ratio D of Tαβ to Tαα in the 13 C-NMR spectrum, Tαβ/Tαα is not more than 0.5, (v) the B value is 1.00 to 1.50 and (vi) the glass transition temperature Tg is not higher than -50°C. Also disclosed is a vulcanizable rubber composition containing the random copolymer. A process of preparing this copolymer by using a metallocene catalyst containing a specified metallocene compound is also disclosed. The ethylene-α-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low temperature flexibility and heat resistance.

    摘要翻译： 公开了在研究了乙烯±烯烃 - 非共轭多烯无规共聚物性质没有（i）所述共聚物含有（a）衍生自乙烯的单元和单元从3个或更多碳原子的±烯烃的（b）以摩尔 为40/60至64/36比例大于0.3分升/ g且小于[（A）/（b）]，（ⅱ）碘值为1至50，（ⅲ）的特性粘度（·）5.0 10分升/克，（ⅳ）T的强度比D±Ť²在13 C-NMR谱±±，T±²/ T±±是不大于0.5，（v）的B值是1:00到 1:50和（vi）玻璃化转变温度Tg为不高于-50℃ 所以圆盘游离缺失是含有该无规共聚物的可硫化橡胶组合物。 通过使用金属茂催化剂含有游离缺失特定的金属茂化合物gibt盘制造该共聚物的方法。 所述乙烯±烯烃 - 非共轭多烯无规共聚物和该橡胶组合物具有优异的机械强度，耐候性，耐臭氧性，加工性，低温柔软性和耐热性。

    Rubber modifier
    4.
    发明公开
    Rubber modifier 失效
    改性剂的橡胶

    公开(公告)号：EP1065240A3

    公开(公告)日：2001-03-21

    申请号：EP00122232.2

    申请日：1997-09-30

    申请人： Mitsui Chemicals, Inc.

    发明人： Kawasaki, Masaaki ,  Koda, Taku ,  Hakuta, Takashi ,  Tojo, Tetsuo

    IPC分类号： C08L23/16

    CPC分类号： C08L23/16 ,  C08L2205/02 ,  C08L2666/04

    摘要： A rubber modifier which can improve the workability in roll kneading and in extrusion of rubber without deteriorating the material properties of the rubber and which is superior in the performance of handling and working is provided. The rubber modifier comprises an ethylene/α -olefin copolymer rubber (A) composed of one or more copolymers selected from the group consisting of a copolymer of ethylene and an α - olefin having 3 - 20 carbon atoms and a copolymer of ethylene, an α -olefin having 3 - 20 carbon atoms and a non-conjugated polyene, the copolymer rubber (A) having the parameters: an ethylene/α -olefin mole ratio in the range of 51/49 to 87/13, an intrinsic viscosity [η ] determined in decahydronaphthalene at 135 °C in the range of 0.8 to 2.5 dl/g and an iodine value in the range of 0 to 40.

    Olefin thermoplastic elastomer compositions
    5.
    发明公开
    Olefin thermoplastic elastomer compositions 失效
    烯烃热塑性弹性体组合物

    公开(公告)号：EP1016689A3

    公开(公告)日：2000-09-13

    申请号：EP00105908.8

    申请日：1996-06-28

    申请人： MITSUI CHEMICALS, INC.

    发明人： Kawasaki, Masaaki ,  Okada, Keiji ,  Tojo, Tetsuo ,  Kobayashi, Kyoko ,  Itoh, Yuichi ,  Uchiyama, Akira ,  Tsutsui, Toshiyuki ,  Sagane, Toshihiro

    IPC分类号： C08L23/02 ,  C08L23/16

    CPC分类号： C08L23/02 ,  A61J1/03 ,  B65D23/003 ,  B65D51/28 ,  C08K5/14 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/142 ,  C08L23/16 ,  C08L23/22 ,  C08L91/00 ,  C08L2205/03 ,  C08L2207/04 ,  C08L2312/00 ,  C08L2666/04

    摘要： An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/α-olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an α-olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having: (1) a molar ratio of (a) units derived from ethylene to (b) units derived from the α-olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b)); (2) an iodine value of 1 to 50; and (3) an intrinsic viscosity (η), as measured in decalin at 135°, of 0.1 dl/g to 10 dl/g.

    摘要翻译： 一种烯烃热塑性弹性体组合物，它包含10至小于60重量份的结晶聚烯烃树脂（A）和90至40重量份以上的乙烯/α-烯烃/非共轭多烯共聚物橡胶（B），总量 的组分（A）和（B）为100重量份，所述橡胶（B）可通过乙烯，具有3-20个碳原子的α-烯烃和非共轭多烯在茂金属催化剂存在下的无规共聚获得，和 （a）源自乙烯的单元与（b）源自具有3至20个碳原子的α-烯烃的单元的摩尔比为40:60至95:5（（a）:( b）） ; （2）碘值为1至50; 和（3）在135℃萘烷中测定的特性粘度（η）为0.1dl / g-10dl / g。

    Foam processable rubber compositions and vulcanized rubber foam-molded products of the same
    7.
    发明公开
    Foam processable rubber compositions and vulcanized rubber foam-molded products of the same 失效
    Schaumkautschukzusammensetzungen und vulkanisierterGummischaumformkörper

    公开(公告)号：EP0842979A1

    公开(公告)日：1998-05-20

    申请号：EP97119998.9

    申请日：1997-11-14

    申请人： Mitsui Chemicals, Inc.

    发明人： Kawasaki, Masaaki ,  Nonaka, Shuichi ,  Kunizane, Masao ,  Koda, Taku ,  Tojo, Tetsuo

    IPC分类号： C08L23/16

    CPC分类号： C08L23/16 ,  C08K3/06 ,  C08K5/09 ,  C08K5/20 ,  C08K5/39 ,  C08K5/47 ,  C08L23/20 ,  C08L91/00 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2312/00 ,  C08L2666/04

    摘要： Disclosed is a foam processable rubber composition which comprises an ethylene/α-olefin of 3 to 20 carbon atoms/non-conjugated polyene copolymer rubber (A), a crystalline polyolefin resin (B) having a melting point of 100 to 150 °C and a foaming agent (C), in specific proportions. The copolymer rubber (A) has an ethylene/α-olefin molar ratio of 60/40 to 80/20, an intrinsic viscosity (η), as measured in decalin at 135 °C, of 0.7 to 2 dl/g, and an iodine value of 10 to 50. A vulcanized rubber foam-molded product can be obtained by vulcanizing and foaming the rubber composition. The rubber composition can provide vulcanized rubber foam-molded products having excellent vulcanization properties such as weathering resistance, heat resistance, ozone resistance and tear strength. Besides, the rubber composition exhibits excellent precision moldability and productivity of vulcanized rubber foam-molded products in transfer molding, injection molding and cast molding.

    摘要翻译： 公开了一种可发泡加工的橡胶组合物，其包含3至20个碳原子的乙烯/α-烯烃/非共轭多烯共聚物橡胶（A），熔点为100至150℃的结晶聚烯烃树脂（B） 发泡剂（C）。 共聚物橡胶（A）的乙烯/α-烯烃摩尔比为60/40〜80/20，在135℃的萘烷中测定的特性粘度（η）为0.7〜2d / g， 碘值为10〜50。硫化橡胶发泡成型体可以通过硫化和发泡橡胶组合物得到。 橡胶组合物可以提供具有优异的硫化性能如耐候性，耐热性，耐臭氧性和撕裂强度的硫化橡胶发泡成型产品。 此外，橡胶组合物在传递成型，注射成型和铸造成型中表现出优异的成型性和硫化橡胶发泡成型体的生产率。