Ethylene polymer particles, production method thereof and molded article using the same
    1.
    发明公开
    Ethylene polymer particles, production method thereof and molded article using the same 有权
    Ethylenpolymerteilchen,HerstellungsverfahrendafürundFormkörperunter Verwendung davon

    公开(公告)号:EP2341085A2

    公开(公告)日:2011-07-06

    申请号:EP11154968.9

    申请日:2007-07-23

    IPC分类号: C08F10/02 C08F4/654

    摘要: The present invention relates to a method for producing an ethylene polymer, comprising:
    a step of polymerizing olefins including ethylene, in the presence of an olefin polymerization catalyst comprising:
    [A] a solid titanium catalyst component including magnesium, halogen, titanium and a polyether compound represented by the following general formula (2), and

    [B] an organometallic compound catalyst component including a metal element selected from group I, group II and group XIII of the periodic table; and
    (c) a step of subjecting the polymer obtained in the above step to a temperature of not less than 100°C and not more than a melting point of the polymer for 15 minutes to 24 hours;

    wherein m is an integer of 1≤m≤10; R 11 to R 36 represent each independently a hydrogen atom or a substituent having at least one element selected from carbon, hydrogen, oxygen, fluorine, chlorine, bromine, iodine, nitrogen, sulfur, phosphorus, boron and silicon; when m represents 2 or more, a plurality of R 11 s and R 12 s may each be the same or different; and any of R 11 to R 36 may together form a ring other than a benzene ring.

    摘要翻译: 乙烯聚合物的制造方法技术领域本发明涉及乙烯聚合物的制造方法,包括:在烯烃聚合催化剂存在下,使包含乙烯的烯烃聚合的工序,所述催化剂包含:[A]包含镁,卤素,钛和聚醚的固体钛催化剂组分 由下列通式(2)表示的化合物和[B]包含选自元素周期表第I族,第II族和第ⅩⅢ族的金属元素的有机金属化合物催化剂组分; 和(c)将上述步骤得到的聚合物在聚合物熔点不低于100℃且不低于15分钟至24小时的温度下进行; 其中m为1‰¤m‰¤10的整数; R 11〜R 36各自独立地表示氢原子或具有选自碳,氢,氧,氟,氯,溴,碘,氮,硫,磷,硼和硅中的至少一种元素的取代基。 当m表示2或更大时,多个R 11和R 12可各自相同或不同; 并且R 11至R 36中的任何一个可以一起形成除苯环以外的环。

    Olefin thermoplastic elastomer compositions
    2.
    发明公开
    Olefin thermoplastic elastomer compositions 失效
    Olefinthermoplastische Elastomerzusammensetzungen

    公开(公告)号:EP1016689A2

    公开(公告)日:2000-07-05

    申请号:EP00105908.8

    申请日:1996-06-28

    IPC分类号: C08L23/02 C08L23/16

    摘要: An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/α-olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an α-olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having:

    (1) a molar ratio of (a) units derived from ethylene to (b) units derived from the α-olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b));
    (2) an iodine value of 1 to 50; and
    (3) an intrinsic viscosity (η), as measured in decalin at 135°, of 0.1 dl/g to 10 dl/g.

    摘要翻译: 包含10至小于60重量份的结晶聚烯烃树脂(A)和90至大于40重量份的乙烯/α-烯烃/非共轭多烯共聚物橡胶(B)的烯烃热塑性弹性体组合物,其总量 组分(A)和(B)为100重量份,所述橡胶(B)可通过乙烯,具有3-20个碳原子的α-烯烃和非共轭多烯在茂金属催化剂存在下的无规共聚得到, 具有:(1)衍生自乙烯的单元与(b)衍生自具有3至20个碳原子的α-烯烃的单元的摩尔比为40:60至95:5((a):( b)) ; (2)碘值为1〜50; 和(3)在135℃的萘烷中测定的特性粘度(η)为0.1dl / g〜10dl / g。

    Olefin copolymers and processes for preparing same
    9.
    发明公开
    Olefin copolymers and processes for preparing same 失效
    Olefincopolytere和Verfahren zur Herstellung

    公开(公告)号:EP0955321A2

    公开(公告)日:1999-11-10

    申请号:EP99105417.2

    申请日:1989-12-21

    IPC分类号: C08F210/16 C08F4/64

    摘要: In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from α-olefin of 3 ∼ 20 carbon atoms, said ethylene copolymers having

    [A] a density of 0.85 ∼ 0.92 g/cm 3 ,
    [B] an intrinsic viscosity [η] as measured in decalin at 135°C of 0.1 ∼ 10 dl/g,
    [C] a ratio ( M ¯ w/ M ¯ n) of a weight average molecular weight ( M ¯ w) to a number average molecular weight ( M ¯ n) as measured by GPC of 1.2 ∼ 4, and
    [D] a ratio (MFR 10 /MFR 2 ) of MFR 10 under a load of 10 kg to MFR 2 under a load of 2.16 kg at 190°C of 8 ∼ 50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译: 根据本发明,提供由乙烯衍生的结构单元(a)和衍生自3〜20个碳原子的α-烯烃的结构单元(b)组成的乙烯共聚物,所述乙烯共聚物的密度为0.85〜 0.92g / cm 3,在135℃的萘烷中测定的特性粘度Ä等于0.1〜10dl / g,重均分子量(Mw)与a的比例(Mw / Mn) 通过GPC测定的数均分子量(Mn)为1.2〜4,在负载为2.16kg的载荷为10kg的MFR10与MFR2的MFR(MFR10 / MFR2)在190℃时为8〜50, 分子量分布窄,流动性好。