摘要:
The present invention relates to a method for producing an ethylene polymer, comprising: a step of polymerizing olefins including ethylene, in the presence of an olefin polymerization catalyst comprising: [A] a solid titanium catalyst component including magnesium, halogen, titanium and a polyether compound represented by the following general formula (2), and
[B] an organometallic compound catalyst component including a metal element selected from group I, group II and group XIII of the periodic table; and (c) a step of subjecting the polymer obtained in the above step to a temperature of not less than 100°C and not more than a melting point of the polymer for 15 minutes to 24 hours;
wherein m is an integer of 1≤m≤10; R 11 to R 36 represent each independently a hydrogen atom or a substituent having at least one element selected from carbon, hydrogen, oxygen, fluorine, chlorine, bromine, iodine, nitrogen, sulfur, phosphorus, boron and silicon; when m represents 2 or more, a plurality of R 11 s and R 12 s may each be the same or different; and any of R 11 to R 36 may together form a ring other than a benzene ring.
摘要:
An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/α-olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an α-olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having:
(1) a molar ratio of (a) units derived from ethylene to (b) units derived from the α-olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b)); (2) an iodine value of 1 to 50; and (3) an intrinsic viscosity (η), as measured in decalin at 135°, of 0.1 dl/g to 10 dl/g.
摘要:
In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from α-olefin of 3 ∼ 20 carbon atoms, said ethylene copolymers having [A] a density of 0.85 ∼ 0.92 g/cm 3 , [B] an intrinsic viscosity [η] as measured in decalin at 135°C of 0.1 ∼ 10 dl/g, [C] a ratio ( M ¯ w/ M ¯ n) of a weight average molecular weight ( M ¯ w) to a number average molecular weight ( M ¯ n) as measured by GPC of 1.2 ∼ 4, and [D] a ratio (MFR 10 /MFR 2 ) of MFR 10 under a load of 10 kg to MFR 2 under a load of 2.16 kg at 190°C of 8 ∼ 50, and being narrow in molecular weight distribution and excellent in flowability.
摘要:
The invention relates to a catalyst component which can provide, in combination with a transition metal compound, a catalyst for ethylenically unsaturated monomer polymerization, a catalyst comprising the catalyst component and a transition metal compound, and a process for ethylenically unsaturated monomer polymerization using the catalyst. The catalyst component comprises a compound obtained by the reaction of, in any order, (i) a compound comprising a metal of Group 13 of the periodic table; (ii) a compound capable of reacting with the compound (i) to be bonded to two or more of the Group 13 metal; (iii) a compound capable of reacting the compound (i); and optionally (iv) a hydrocarbon compound or the like.
摘要:
In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from α-olefin of 3 ∼ 20 carbon atoms, said ethylene copolymers having
[A] a density of 0.85 ∼ 0.92 g/cm 3 , [B] an intrinsic viscosity [η] as measured in decalin at 135°C of 0.1 ∼ 10 dl/g, [C] a ratio ( M ¯ w/ M ¯ n) of a weight average molecular weight ( M ¯ w) to a number average molecular weight ( M ¯ n) as measured by GPC of 1.2 ∼ 4, and [D] a ratio (MFR 10 /MFR 2 ) of MFR 10 under a load of 10 kg to MFR 2 under a load of 2.16 kg at 190°C of 8 ∼ 50, and being narrow in molecular weight distribution and excellent in flowability.
摘要:
Ethylene copolymer compositions comprising one or more ethylene/α-olefin copolymers and a low-density polyethylene obtained by high-pressure radical polymerization, a crystalline polyolefin, an olefin type elastomer or a graft modified ethylene (co)polymer. The compositions comprise an ethylene/α-olefin copolymer obtainable by using a catalyst for olefin polymerization containing an organoaluminium oxy-compound (a) and at least two specific metallocene compounds (b), or which have specific properties. The compositions are excellent in moldability and from them films having high transparency and high mechanical strength can be produced. When the ethylene/α-olefin composition contains the graft modified ethylene (co)polymer, a film having high transparency and good adhesion to highly polar materials can be produced.