摘要:
The present invention relates to a laminate comprising an olefinic thermoplastic elastomer which comprises:
(a) a substratum layer comprising an olefinic thermoplastic elastomer composition(A) having the following characteristics ① to ③:
① 9 ≦ Y-0.43X ≦ 27 wherein X denotes the JIS A-hardness value (a dimensionless value) of the olefinic thermoplastic elastomer composition determined according to the prescription of JIS K6301 and Y represents the compression set value (expressed by %) of the olefinic thermoplastic elastomer composition determined according to the prescription of JIS K6301 under a condition of 70 °C and 22 hours, ② a tensile strength value in the range from 5 to 30 MPa determined according to the prescription of JIS K6301 and ③ an elongation set value of 18% or less determined according to the prescription of JIS K6301, and
(b) a surface skin layer comprising an ultra high molecular weight polyolefin composition(B) having an intrinsic viscosity [η] measured in decalin at 135 °C in the range from 3.5 to 8.3 dl/g; and a constructional gasket comprising the olefinic thermoplastic elastomer composition(A).
摘要:
An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/ alpha -olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an alpha -olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having: (1) a molar ratio of (a) units derived from ethylene to (b) units derived from the alpha -olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b)); (2) an iodine value of 1 to 50; and (3) an intrinsic viscosity ( eta ), as measured in decalin at 135 DEG , of 0.1 dl/g to 10 dl/g.
摘要:
An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/ alpha -olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an alpha -olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having: (1) a molar ratio of (a) units derived from ethylene to (b) units derived from the alpha -olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b)); (2) an iodine value of 1 to 50; and (3) an intrinsic viscosity ( eta ), as measured in decalin at 135 DEG , of 0.1 dl/g to 10 dl/g.
摘要:
The present invention relates to a laminate comprising an olefinic thermoplastic elastomer which comprises: (a) a substratum layer comprising an olefinic thermoplastic elastomer composition(A) having the following characteristics 1○ to 3○:1○9 ≦ Y-0.43X ≦ 27 wherein X denotes the JIS A-hardness value (a dimensionless value) of the olefinic thermoplastic elastomer composition determined according to the prescription of JIS K6301 and Y represents the compression set value (expressed by %) of the olefinic thermoplastic elastomer composition determined according to the prescription of JIS K6301 under a condition of 70 °C and 22 hours,2○ a tensile strength value in the range from 5 to 30 MPa determined according to the prescription of JIS K6301 and3○ an elongation set value of 18% or less determined according to the prescription of JIS K6301, and (b) a surface skin layer comprising an ultra high molecular weight polyolefin composition(B) having an intrinsic viscosity [η] measured in decalin at 135 °C in the range from 3.5 to 8.3 dl/g; and a constructional gasket comprising the olefinic thermoplastic elastomer composition(A).
摘要:
The present invention relates to an olefinic thermoplastic elastomer composition which comprises a crystalline polyolefin resin (A), an ethylene- alpha -olefin-non-conjugated polyene copolymer rubber(B) and at least one rubber(C) selected from polyisobutylene, butyl rubber and a propylene-ethylene copolymer rubber having a propylene content of 50 mol% or more or an ethylene- alpha -olefin copolymer(D) having a density of 0.870 to 0.940 (g/cm ) and an ethylene content of 85 mol% or more, said ethylene- alpha -olefin-non-conjugated polyene copolymer rubber(B) being a crosslinked thermoplastic elastomer composition, being obtained by random copolymerization of ethylene, an alpha -olefin having 3 to 20 carbon atoms and a non-conjugated polyene in the presence of a metallocene catalyst, (1) containing the unit (a) derived from the ethylene and the unit (b) derived from the alpha -olefin in a molar ratio of 40/60 to 95/5 (a)/(b), (2) having an iodine value of 1 to 50 and (3) having an intrinsic viscosity eta measured in decalin at 135 DEG C of 1.0 to 10 dl/g; and relates to a method for manufacturing the same.
摘要:
The present invention relates to an olefinic thermoplastic elastomer composition which comprises a crystalline polyolefin resin (A), an ethylene-α-olefin-non-conjugated polyene copolymer rubber(B) and at least one rubber(C) selected from polyisobutylene, butyl rubber and a propylene-ethylene copolymer rubber having a propylene content of 50 mol% or more or an ethylene-α-olefin copolymer(D) having a density of 0.870 to 0.940 (g/cm 3 ) and an ethylene content of 85 mol% or more, said ethylene-α-olefin-non-conjugated polyene copolymer rubber(B) being a crosslinked thermoplastic elastomer composition, being obtained by random copolymerization of ethylene, an α-olefin having 3 to 20 carbon atoms and a non-conjugated polyene in the presence of a metallocene catalyst, (1) containing the unit (a) derived from the ethylene and the unit (b) derived from the α-olefin in a molar ratio of 40/60 to 95/5 [(a)/(b)], (2) having an iodine value of 1 to 50 and (3) having an intrinsic viscosity[η] measured in decalin at 135°C of 1.0 to 10 dl/g; and relates to a method for manufacturing the same.
摘要翻译:(A),乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(B)和至少一种选自聚异丁烯,丁基橡胶(C)的橡胶(C)的烯烃类热塑性弹性体组合物, 和丙烯含量为50摩尔%以上的丙烯 - 乙烯共聚物橡胶或密度为0.870〜0.940(g / cm 3)且乙烯含量为85摩尔%以上的乙烯-α-烯烃共聚物(D) ,所述乙烯-α-烯烃 - 非共轭多烯共聚物橡胶(B)是一种交联热塑性弹性体组合物,它是通过乙烯,具有3-20个碳原子的α-烯烃和非共轭多烯在聚 (a)含有来自乙烯的单元(a)和来自α-烯烃的单元(b)的摩尔比为40/60〜95/5 [(a)/(b )],(2)碘值为1〜50,(3)特性粘度[η] mea 在135℃的十氢化萘中确定为1.0至10dl / g; 并涉及其制造方法。
摘要:
An olefin thermoplastic elastomer composition comprising 10 to less than 60 parts by weight of a crystalline polyolefin resin (A) and 90 to more than 40 parts by weight of an ethylene/α-olefin/nonconjugated polyene copolymer rubber (B), the total amount of components (A) and (B) being 100 parts by weight, said rubber (B) being obtainable by random copolymerization of ethylene, an α-olefin having 3 to 20 carbon atoms and a nonconjugated polyene in the presence of a metallocene catalyst and having:
(1) a molar ratio of (a) units derived from ethylene to (b) units derived from the α-olefin having 3 to 20 carbon atoms of 40:60 to 95:5 ((a):(b)); (2) an iodine value of 1 to 50; and (3) an intrinsic viscosity (η), as measured in decalin at 135°, of 0.1 dl/g to 10 dl/g.
摘要:
A glass run channel comprising a glass run channel body (2) composed of a bottom wall (1a) and side walls (1b) extending from two opposite edges of the bottom wall (1a), the glass run channel body (2) having a substantially U-shaped section and provided with a groove (1c), and tonguelike draining parts (3,3) protruding from vicinities of distal edges of the side walls (1b,1b) toward to the bottom wall (1a) of the glass run channel body (2) so as to become proximate to each other. Each of the tongue like draining parts has a window glass contact part (4) composed of a surface to be bought into contact with a window glass, which comprises a layer of a thermoplastic elastomer and a layer of an ultrahigh molecular weight polyolefin composition. The layer of ultrahigh molecular weight polyolefin composition is arranged so as to contact a window glass. The ultrahigh molecular weight polyolefin composition comprises at least a polyolefin (composition) having a specified intrinsic viscosity and an olefinic thermoplastic elastomer. The glass run channel is excellent in the durability, tight contactability with a window glass exhibited when the window glass is held closed and supple slide exhibited when a window glass is closed or opened and, even when twisted or bent, is free from a creasing of the ultrahigh molecular weight polyolefin composition layer.