摘要:
This invention relates to a method of producing a compound represented by the following general formula (3):
[wherein R is a bivalent aliphatic group having a carbon number of 1-16 or a bivalent aromatic group], which comprises a step (i) of reacting a compound represented by the following general formula (1):
with a carboxylic acid halide represented by the following general formula (2):
[wherein R is a bivalent aliphatic group having a carbon number of 1-16 or a bivalent aromatic group and X is a halogen atom] in the presence of a basic compound to form an ester, and a step (ii) of conducting a heat treatment after the step (i) to decompose an oligomer in the ester.
摘要:
The invention provides a phosphate compound having an unsaturated double bond and a metal salt thereof; a dental material containing a phosphate compound having an unsaturated double bond and/or a metal salt thereof; and a dental composition containing a phosphate compound having an unsaturated double bond and/or a metal salt thereof. The phosphate compound of the invention provides a dental material and a dental composition such as a bonding material, adhesive material and a dental luting agent that are highly stable during storage, convenient for handling, and that exhibit higher adhesiveness and bond durability.
摘要:
This invention provides a rubber composition comprising 1-10 parts by mass of sulfur and 0.1-10 parts by mass of a compound represented by the following general formula (1) or a composition containing the compound as a main component based on 100 parts by mass of a rubber component as well as a pneumatic tire in which at least one of a carcass (4) and a belt (6) includes a layer composed of steel cords covered with a coating rubber, characterized in that the above rubber composition is used as the coating rubber covering the steel cords in at least one of the carcass (4) and the belt (6):
(wherein R represents a divalent aliphatic group having a carbon number of 1-16 or a divalent aromatic group).
摘要:
A (meth)acrylic ester compound represented by the general formula (1) and a dental material containing the compound,
wherein, in the formula, R 11 represents a divalent aromatic group; R 12 represents a hydrogen atom or a methyl group; R 13 represents an aryl group; R 14 represents a hydrogen atom or a methyl group; and X 11 represents an oxygen atom or a sulfur atom. The dental material and the dental composition which each contains the compound represented by the general formula (1) according to the present invention are useful because they are superior in curability and also combine transparency, X-ray contrast property, and low polymerization shrinkage while retaining various properties required for dental materials (for example, flexural strength and the like). Furthermore, a polymerizable composition containing the (meth)acrylic ester compound represented by the general formula (1) which can be polymerized and molded within a short period of time by photopolymerization. It gives a cured resin which is excellent in the transparency, optical properties (refractive index and Abbe's number), heat resistance, mechanical properties and the like. Also provided is an optical part obtained by polymerizing the polymerizable composition.
摘要:
Disclosed are: a phosphate ester compound having an unsaturated double bond and a metal salt thereof; a dental material comprising at least one member selected from the phosphate ester compound and/or the metal salt thereof; and a dental composition comprising a polymerizable compound and a polymerization initiator, wherein the polymerizable compound has the unsaturated double bond and/or a salt thereof. The phosphate ester compound enables to provide a dental material or a dental composition such as a bonding material, an adhesive/cohesive material having excellent storage stability, easy to handle, and having a higher adhesion property and higher adhesion durability.
摘要:
Disclosed is a rubber composition wherein 1-10 parts by mass of sulfur and 0.1-10 parts by mass of a compound represented by the general formula (1) below or a composition mainly containing such a compound are compounded per 100 parts by mass of a rubber component. Also disclosed is a pneumatic tire wherein at least one of a carcass (4) and a belt (6) includes a layer which is composed of a steel cord covered with a coating rubber, which pneumatic tire is characterized in that the above-described rubber composition is used as the coating rubber covering the steel cord in at least one of the carcass (4) and the belt (6). (1) (In the formula, R represents a divalent aliphatic group having 1-16 carbon atoms or a divalent aromatic group.)
摘要:
This invention relates to a method for producing a carboxylic acid chloride, which efficiently decomposes a Vilsmeier reagent type compound in a carboxylic acid chloride lacking a thermal stability or a carboxylic acid chloride hardly distilled in practice due to a high boiling point with a simple operation and has no adverse effect on a subsequent step, and more particularly to a method for producing a carboxylic acid chloride, characterized by comprising reacting a carboxylic acid with a chlorinating agent in the presence of a catalyst, removing the excessive chlorinating agent from a reaction system after the reaction, and then further adding 1.0 to 3.0 equivalents of the starting carboxylic acid based on the catalyst to the reaction system to decompose a Vilsmeier reagent type compound remaining in the reaction system.
摘要:
An analysis unit determining at least two boundaries by determining; in a coordinate system indicating a correlation between a luminance contrast value between a luminance of an attention portion and a luminance of a background portion, and a luminance average value of an index including the attention portion and the background portion; the boundary between a region where a subject has a visibility and a region where the subject does not have the visibility for each combination of stimulus values of a color stimulus of a visual target.