摘要:
Provided is a propylene-based polymer comprising constituent units derived from propylene in an amount of more than 90 mol % (provided that the total amount of constituent units in the polymer is 100 mol %), and satisfying the following requirements [1] and [2-1]: [1] the syndiotactic pentad fraction (rrrr fraction) as measured by 13 C-NMR is 85% or greater; and [2-1] the melting point (Tm) determined by differential scanning calorimetry (DSC) is 145°C or higher.
摘要:
Provided is a propylene-based polymer comprising constituent units derived from propylene in an amount of more than 90 mol % (provided that the total amount of constituent units in the polymer is 100 mol %), and satisfying the following requirements [1] and [2-1]: [1] the syndiotactic pentad fraction (rrrr fraction) as measured by 13 C-NMR is 85% or greater; and [2-1] the melting point (Tm) determined by differential scanning calorimetry (DSC) is 145°C or higher.
摘要:
The bridged metallocene compound of formula (I)
wherein Y is carbon, silicon, germanium or tin, M is titanium, zirconium or hafnium, R 1 to R 4 are all hxdrogen, R 13 and R 14 are each unsubstituted or substituted aryl groups, at least one of which is a substituted aryl group, and R 5 to R 12 , Q and j are as defined in claim 1, and its use in the polymerisation of α-olefins.
摘要:
A composition having excellent transparency, flexibility, rubber elasticity, thermal resistance, impact resistance, abrasion resistance and the like, a composition having excellent rigidity and impact resistance as well as excellently balanced in whitening resistance, abrasion resistance and heat sealability, and a composition having excellent rubbery properties, thermal resistance, abrasion resistance and flexibility are provided. A composition comprising a specific propylene·α-olefin copolymer for which, in a signal chart measured by 13 C-NMR and predetermined such that the peak present at the highest magnetic field among the signals originating from CH (methine) of the constituent unit derived from an α-olefin having 4 to 20 carbon atoms is to be at 34.4 ppm, an absorption intensity A at about 22.0 to 20.9 ppm and an absorption intensity B at about 19.0 to 20.6 ppm satisfy the following relational expressions (i) and (ii) with respect to an absorption intensity C at about 19.0 to 22.0 ppm, which is assignable to propylene methyl: A / C × 100 ≤ 8 , and B / C × 100 ≥ 60 a molded product thereof, and the α-olefin-based copolymer are provided.
摘要:
Disclosed is a synthetic lubricating oil comprising an α-olefin (co)polymer defined by the following features (i) to (v):
(i) said (co)polymer contains constituent units derived from (a) at least one monomer selected from α-olefins of 8 to 20 carbon atoms in amounts of 90 to 100% by mol and contains constituent units derived from (b) ethylene in amounts of 0 to 10% by mol, (ii) the dynamic viscosity at 100°C is in the range of 8 to 500 mm 2 /s, (iii) the number-average molecular weight (Mn), as measured by gel permeation chromatography, is in the range of 500 to 15,000, (iv) said (co)polymer satisfies the following formulas (I) and (II):
A ≤ 24.0×Exp(-0.0239×K) (I)
B ≤ 0.0775×K (II)
wherein A is a content (%) of a (co)polymer having a molecular weight, as measured by gel permeation chromatography, of not more than 1,000, B is a content (%) of a (co)polymer having a molecular weight of not less than 20,000, and K is a dynamic viscosity (mm 2 /s) at 100°C, and (v) the molecular weight distribution (Mw/Mn) is in the range of 1.1 to 1.8.
Also disclosed is a lubricating oil composition comprising the above-mentioned synthetic lubricating oil and a low-viscosity base oil. The synthetic lubricating oil and the lubricating oil composition have high thermal oxidation stability and are excellent in viscosity index, low-temperature viscosity properties and shear stability.
摘要:
The invention relates to a catalyst component which can provide, in combination with a transition metal compound, a catalyst for ethylenically unsaturated monomer polymerization, a catalyst comprising the catalyst component and a transition metal compound, and a process for ethylenically unsaturated monomer polymerization using the catalyst. The catalyst component comprises a compound obtained by the reaction of, in any order, (i) a compound comprising a metal of Group 13 of the periodic table; (ii) a compound capable of reacting with the compound (i) to be bonded to two or more of the Group 13 metal; (iii) a compound capable of reacting the compound (i); and optionally (iv) a hydrocarbon compound or the like.
摘要:
The invention relates to a catalyst component which can provide, in combination with a transition metal compound, a catalyst for ethylenically unsaturated monomer polymerization, a catalyst comprising the catalyst component and a transition metal compound, and a process for ethylenically unsaturated monomer polymerization using the catalyst. The catalyst component comprises a compound obtained by the reaction of, in any order, (i) a compound comprising a metal of Group 13 of the periodic table; (ii) a compound capable of reacting with the compound (i) to be bonded to two or more of the Group 13 metal; (iii) a compound capable of reacting the compound (i); and optionally (iv) a hydrocarbon compound or the like.