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    POLYMER ADSORBENT
    3.
    发明公开
    POLYMER ADSORBENT 审中-公开
    POLYMERADSORBENS

    公开(公告)号：EP2808080A1

    公开(公告)日：2014-12-03

    申请号：EP13740672.4

    申请日：2013-01-26

    申请人： Nippon Filcon Co., Ltd.

    发明人： INOUE Yoshinori ,  KAJIWARA Takehiro ,  SAITO Mitsuru

    IPC分类号： B01J20/26 ,  C02F1/28 ,  C08J3/12

    CPC分类号： B01J39/185 ,  B01J20/264 ,  B01J20/3007 ,  B01J20/305 ,  B01J20/3064 ,  B01J20/3085 ,  B01J39/07 ,  B01J39/19 ,  B01J41/13 ,  B01J45/00 ,  B01J47/127 ,  B01J2220/445 ,  C02F1/285 ,  C02F2101/20 ,  C08J3/005 ,  C08J9/26 ,  C08J9/40 ,  C08J2201/0464 ,  C08J2327/06 ,  C08J2400/104 ,  C08J2425/14 ,  C08J2433/06

    摘要： Problem
    To provide a method for easily producing an adsorbing material used for the removal and recovery of metals and ions in a solution, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes.
    Means for Resolution
    A polymer adsorbent for metals and ions, which is highly durable and has various adsorptive functional groups and forms applicable for various purposes, is produced by a) preparing a reactive polymer having a large number of halogenated alkyl groups or glycidyl groups in the molecule, b) preparing a base material polymer insoluble in water and alcohols, c) dissolving the reactive polymer and the base material polymer in an organic solvent to give a mixed solution, d) removing the organic solvent to give a solid carrier in a desired form, and e) allowing a halogenated alkyl group or a glycidyl group in the solid carrier to react with an amine compound having a functional group capable of adsorbing metals and ions, thereby introducing an adsorptive functional group.

    摘要翻译： 问题提供一种容易地制造用于除去和回收溶液中的金属和离子的吸附材料的方法，其是高度耐用的并且具有适用于各种目的的各种吸附官能团和形式。 解决方法用于金属和离子的聚合物吸附剂，其耐久性高，具有各种吸附官能团和适用于各种目的的形式，是通过以下方法制备的：a）制备具有大量卤代烷基或缩水甘油基的反应性聚合物 分子，b）制备不溶于水和醇的基础材料聚合物，c）将反应性聚合物和基础材料聚合物溶解在有机溶剂中以得到混合溶液，d）除去有机溶剂，得到所需的固体载体 形式，和e）使固体载体中的卤代烷基或缩水甘油基与具有能够吸附金属和离子的官能团的胺化合物反应，从而引入吸附官能团。

    FIBROUS METAL ADSORBENT
    4.
    发明公开
    FIBROUS METAL ADSORBENT 审中-公开
    纤维金属吸附剂

    公开(公告)号：EP2893975A1

    公开(公告)日：2015-07-15

    申请号：EP13836156.3

    申请日：2013-08-26

    申请人： Nippon Filcon Co., Ltd.

    发明人： INOUE Yoshinori ,  KATOH Toshifumi ,  KAJIWARA Takehiro ,  SAITO Mitsuru

    IPC分类号： B01J20/26 ,  B01J20/30 ,  C02F1/28 ,  C08F8/30 ,  C08G81/02 ,  D01D5/08

    CPC分类号： B01J20/3007 ,  B01J20/261 ,  B01J20/262 ,  B01J20/265 ,  B01J20/28023 ,  B01J20/3014 ,  B01J20/3085 ,  B01J20/321 ,  B01J20/3212 ,  B01J20/3227 ,  B01J20/327 ,  B01J20/328 ,  B01J20/3293 ,  B29C47/0004 ,  B29C47/0014 ,  B29D99/0078 ,  B29K2277/00 ,  B29K2279/00 ,  B29K2995/0068 ,  C02F1/28 ,  C02F1/286 ,  C02F2101/20 ,  C08F8/30 ,  C08G81/02 ,  C08L23/06 ,  D01F6/34

    摘要： Provided is a fibrous adsorbing material used for the adsorption and recovery of metals in a solution, which is a fibrous metal-adsorbing material that can be produced using existing production facilities without using special facilities or complicated operations, has high durability, is easy to diversify, and can be processed into various forms. The fibrous metal-adsorbing material is produced by a) a step of preparing an acrylate polymer having a large number of glycidyl groups in the molecule, b) a step of kneading a low-melting-point fiber matrix polymer therewith, c) a step of making the resulting mixture into a fibrous form by an melt-blend spinning method, and d) a step of allowing a long-chain ligand having an amino group or an imino group to react with glycidyl groups on the fiber surface to introduce a metal-adsorbing functional group. The fibrous metal-adsorbing material has high durability, is easy to diversify, and has various forms.

    摘要翻译： 本发明提供一种用于吸附和回收溶液中的金属的纤维状吸附材料，其为不使用特殊设备或复杂操作而可使用现有生产设备生产的纤维金属吸附材料，具有高耐久性，易于多样化 ，并且可以被处理成各种形式。 纤维状金属吸附材料通过a）制备分子中具有大量缩水甘油基的丙烯酸酯聚合物的步骤，b）捏合低熔点纤维基质聚合物的步骤，c）步骤 通过熔融共混纺丝法将所得混合物制成纤维状，和d）使具有氨基或亚氨基的长链配体与纤维表面上的缩水甘油基反应以引入金属 吸附官能团。 纤维状金属吸附材料具有高耐久性，易于多样化并且具有各种形式。

    POLYMER FOR FILLER FOR PREPROCESSING COLUMN
    5.
    发明公开
    POLYMER FOR FILLER FOR PREPROCESSING COLUMN 有权
    MESSVERFAHREN VON PERFLUOROVERBINDUNGEN MIT EINEMFÜLLSTOFF

    公开(公告)号：EP2314635A1

    公开(公告)日：2011-04-27

    申请号：EP09806701.0

    申请日：2009-08-10

    申请人： Wako Pure Chemical Industries, Ltd. ,  Nippon Filcon Co., Ltd.

    发明人： INOUE Yoshinori ,  YOSHIDA Kimiko ,  KUBOTA Mamoru ,  UEMORI Hitoshi

    IPC分类号： C08F220/32 ,  C08F220/36 ,  G01N1/10 ,  G01N30/00 ,  G01N30/06 ,  G01N30/88

    CPC分类号： G01N30/96 ,  B01J41/14 ,  B01J41/20 ,  B01J2220/54 ,  C08F8/30 ,  C08F8/32 ,  C08F220/32 ,  C08F220/36 ,  C08F224/00 ,  C08F236/20 ,  C08F236/22 ,  G01N30/02 ,  Y10T436/141111 ,  Y10T436/145555 ,  Y10T436/147777 ,  Y10T436/173845 ,  Y10T436/182 ,  Y10T436/193333 ,  Y10T436/201666 ,  B01D15/363

    摘要： [SUMMARY]
    It is a subject of the present invention to provide a novel polymer; a filler for measuring a perfluoro compound having an acidic group at terminal which comprises said polymer; a column filled with said filler; and a measuring method for a perfluoro compound having an acidic group at terminal by using said column; as well as a filler for measuring a drug comprising the above-described polymer; a column filled with said filler; and a measuring method for a drug by using said column.
    The present invention relates to a polymer obtained by introducing an anion exchanging group to a glycidyl group in a polymer obtained by polymerizing the compound represented by the following general formula [1]:

    and the compound represented by the following general formula [2]:

    a filler (column) for measuring an acidic group binding perfluoro compound at terminal which comprises said polymer; a method for measuring said perfluoro compound by using said column; a filler (column) for measuring a drug which comprises the above-described polymer; and a method for measuring a drug by using said column.

    摘要翻译： 发明内容本发明的主题是提供一种新的聚合物; 用于测量包含所述聚合物的末端具有酸性基团的全氟化合物的填料; 填充有所述填料的柱; 以及通过使用所述柱在末端具有酸性基团的全氟化合物的测定方法; 以及用于测量包含上述聚合物的药物的填料; 填充有所述填料的柱; 以及使用该柱的药物的测定方法。 本发明涉及通过将由以下通式[1]表示的化合物聚合而获得的聚合物中的缩水甘油基引入阴离子交换基团和由以下通式[2]表示的化合物获得的聚合物：a 用于测量包含所述聚合物的末端处的结合全氟化合物的酸性基团的填料（柱） 通过使用所述柱测量所述全氟化合物的方法; 用于测量包含上述聚合物的药物的填料（柱）; 以及通过使用所述柱来测定药物的方法。