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    STRONG CONDUCTIVE POLYMER MICROFIBER AND METHOD OF MAKING THE SAME
    3.
    发明公开
    STRONG CONDUCTIVE POLYMER MICROFIBER AND METHOD OF MAKING THE SAME 审中-公开
    强导电聚合物微纤维及其制备方法

    公开(公告)号：EP3227478A2

    公开(公告)日：2017-10-11

    申请号：EP15837134.4

    申请日：2015-12-03

    申请人： King Abdullah University of Science and Technology

    发明人： ZHOU, Jian ,  LI, Er, Qiang ,  LUBINEAU, Gilles ,  THORODDSEN, Sigurdur, T. ,  MULLE, Matthieu

    IPC分类号： D01D5/06 ,  D01D5/12 ,  D01D10/02 ,  D01F6/74 ,  D01F6/94

    CPC分类号： D01F6/74 ,  D01D5/06 ,  D01D5/12 ,  D01D10/02 ,  D01F6/94

    摘要： A method comprising: providing at least one first composition comprising at least one conjugated polymer and at least one solvent, wet spinning the at least one first composition to form at least one first fiber material, hot-drawing the at least one fiber to form at least one second fiber material. In lead embodiments, high-performance poly(3,4-ethylenedioxy-thiophene)/poly(styrenesulfonate) (PEDOT/PSS) conjugated polymer microfibers were fabricated via wet-spinning followed by hot-drawing. In these lead embodiments, due to the combined effects of the vertical hot-drawing process and doping/de-doping the microfibers with ethylene glycol (EG), a record electrical conductivity of 2804 S·cm−1 was achieved. This is believed to be a six-fold improvement over the best previously reported value for PEDOT/PSS fibers (467 S·cm−1) and a twofold improvement over the best values for conductive polymer films treated by EG de-doping (1418 S·cm−1). Moreover, these lead, highly conductive fibers experience a semiconductor-metal transition at 313 K. They also have superior mechanical properties with a Young's modulus up to 8.3 GPa, a tensile strength reaching 409.8 MPa and a large elongation before failure (21%). The most conductive fiber also demonstrates an extraordinary electrical performance during stretching/unstretching: the conductivity increased by 25% before the fiber rupture point with a maximum strain up to 21%. Simple fabrication of the semi-metallic, strong and stretchable wet-spun PEDOT/PSS microfibers can make them available for conductive smart electronics. A dramatic improvement in electrical conductivity is needed to make conductive polymer fibers viable candidates in applications such as flexible electrodes, conductive textiles, and fast-response sensors and actuators.

    摘要翻译： 该方法包括：提供包含至少一种共轭聚合物和至少一种溶剂的至少一种第一组合物，湿纺所述至少一种第一组合物以形成至少一种第一纤维材料，热拉伸所述至少一种纤维以形成 至少一种第二纤维材料。 在主导的实施方案中，通过湿纺然后热拉伸来制造高性能聚（3,4-亚乙基二氧噻吩）/聚（苯乙烯磺酸盐）（PEDOT / PSS）共轭聚合物微纤维。 在这些引线实施例中，由于垂直热拉伸工艺和用乙二醇（EG）掺杂/去掺杂微纤维的组合效应，实现了2804S·cm -1的记录电导率。 相对于先前报道的PEDOT / PSS纤维的最佳值（467S·cm -1），这被认为是六倍的改进，并且相对于通过EG去掺杂（1418S·cm -1）处理的导电聚合物膜的最佳值有两倍的改善 ·cm -1）。 此外，这些导电高导电纤维在313 K时发生半导体 - 金属转变。它们还具有优异的机械性能，其杨氏模量高达8.3 GPa，拉伸强度达到409.8 MPa，失效前的延伸率高达21％。 最具导电性的纤维在拉伸/非拉伸时也表现出非凡的电性能：在纤维断裂点之前电导率增加了25％，最大应变高达21％。 半金属，坚固且可拉伸的湿纺PEDOT / PSS微纤维的简单制造可以使它们适用于导电智能电子产品。 在导电聚合物纤维应用中，例如柔性电极，导电纺织品和快速响应传感器和致动器中，导电聚合物纤维是可行的候选材料，需要电导率的显着提高。

    METHOD OF MAKING FABRICS FROM DYEABLE AND FLAME-RETARDED THERMOPLASTIC POLYURETHANE FIBERS
    4.
    发明授权
    METHOD OF MAKING FABRICS FROM DYEABLE AND FLAME-RETARDED THERMOPLASTIC POLYURETHANE FIBERS 有权
    从可染色和阻燃热塑性聚氨酯纤维制造织物的方法

    公开(公告)号：EP3067446B1

    公开(公告)日：2017-09-20

    申请号：EP16159886.7

    申请日：2013-10-09

    申请人： Lubrizol Advanced Materials, Inc.

    发明人： Vedula, Ravi R. ,  Lee, Mouh-Wahng ,  Farkas, Julius

    IPC分类号： D01F1/07 ,  C08G18/38 ,  C08L75/04 ,  D01F1/10 ,  D01F6/70 ,  D01F6/94 ,  D03D15/08 ,  D04B1/18

    CPC分类号： D01F6/70 ,  C08G18/3206 ,  C08G18/3889 ,  C08G18/4238 ,  C08G18/6651 ,  C08G18/7671 ,  D01F1/07 ,  D01F1/10 ,  D01F6/94 ,  D03D15/00 ,  D03D15/08 ,  D10B2401/041 ,  Y10T442/30 ,  Y10T442/40 ,  Y10T442/60

    摘要： The invention relates to a method of making a fabric comprising: preparing a thermoplastic polyurethane composition, wherein said thermoplastic polyurethane composition comprises: a thermoplastic polyurethane comprising the reaction product of: (i) one or more polyols, (ii) one or more diisocyanates, (iii) one or more chain extenders, (iv) optionally one or more crosslinking agents, and (v) one or more functional modifiers, wherein each said functional modifier is a reaction product of an aminodiol and a Bronsted acid and wherein the functional modifier is incorporated into the backbone of the thermoplastic polyurethane; melt-spinning said thermoplastic polyurethane composition into a fiber; and processing the fiber into a fabric and a method of producing an article of clothing.

    摘要翻译： 本发明涉及一种制造织物的方法，包括：制备热塑性聚氨酯组合物，其中所述热塑性聚氨酯组合物包含：热塑性聚氨酯，其包含以下物质的反应产物：（i）一种或多种多元醇，（ii）一种或多种二异氰酸酯， （iii）一种或多种扩链剂，（iv）任选的一种或多种交联剂，和（v）一种或多种功能调节剂，其中每种所述功能调节剂是氨基二醇和布朗斯台德酸的反应产物，并且其中功能调节剂 被掺入到热塑性聚氨酯的骨架中; 将所述热塑性聚氨酯组合物熔纺成纤维; 和将纤维加工成织物和生产衣物的方法。

    FLAME-RETARDANT FIBER, METHOD FOR PRODUCING SAME, FABRIC USING FLAME-RETARDANT FIBER, AND RESIN COMPOSITE MATERIAL USING FLAME-RETARDANT FIBER
    9.
    发明公开
    FLAME-RETARDANT FIBER, METHOD FOR PRODUCING SAME, FABRIC USING FLAME-RETARDANT FIBER, AND RESIN COMPOSITE MATERIAL USING FLAME-RETARDANT FIBER 有权
    阻燃纤维，用于生产火焰THEREOF面料和锁定纤维树脂复合材料具有阻燃纤维

    公开(公告)号：EP2947186A1

    公开(公告)日：2015-11-25

    申请号：EP14740507.0

    申请日：2014-01-09

    申请人： Kuraray Co., Ltd.

    发明人： UEHATA, Akihiro ,  OKAMOTO, Tetsuya ,  IKEDA, Takayuki

    IPC分类号： D01F6/94 ,  D01F6/74

    CPC分类号： D01F6/62 ,  C08J5/04 ,  C08J2367/03 ,  C08J2379/08 ,  C08J2467/03 ,  C08J2479/08 ,  D01D5/08 ,  D01F1/04 ,  D01F1/06 ,  D01F1/106 ,  D01F6/74 ,  D01F6/94 ,  Y10T428/249921

    摘要： Provided is a flame-retardant fiber having improved light resistance and/or colorability. The flame-retardant fiber is a fiber including a fiber-forming polymer. The fiber-forming polymer contains a polymer blend comprising a polyetherimide polymer (A) and a thermoplastic polymer (B) having a glass transition temperature lower than that of the polymer (A); and the fiber-forming polymer further contains a functional additive (C) that provides light resistance, colorability, or both of light resistance and colorability. The mass ratio (A)/(B) of the polymer (A) to the polymer (B) is from 50/50 to 90/10, and the content of the functional additive (C) is from 0.5 to 10% by mass relative to 100% by mass of the total mass (A + B + C) of the polymer (A), the thermoplastic polymer (B), and the functional additive (C).

    摘要翻译： 本发明提供一种阻燃纤维具有改善的耐光性和/或颜色的能力。 所述的阻燃性纤维是包含纤维形成性聚合物的纤维。 所述形成纤维的聚合物中含有的聚合物共混物，其包含具有玻璃化转变温度比聚合物（A）的低聚醚酰亚胺聚合物（A）和热塑性聚合物（B）; 和成纤聚合物进一步含有功能性添加剂（C）那样提供耐光性，颜色的能力，或二者的耐光性和颜色的能力的。 聚合物（A）与聚合物（B）的质量比（A）/（B）为50/50至90/10，所述功能性添加剂（C）的含量为0.5〜10质量％ 相对于100质量％的聚合物（A）的总质量（A + B + C）质量份，热塑性聚合物（B），以及功能添加剂（C）。