摘要:
Provided is a production method for a water-absorbing resin in which an absorption capacity without pressure of the resulting water-absorbing resin is high and a water-absorbing resin can be efficiently obtained. The production method for a water-absorbing resin including a polymerization step of polymerizing a monomer composition containing an internal crosslinking agent and a monomer to obtain a crosslinked hydrogel polymer, and a drying step of drying the crosslinked hydrogel polymer to obtain a dry polymer, in which the crosslinked hydrogel polymer to be subjected to the drying step contains 50 ppm or more of hydrogen peroxide with respect to the solid content mass of the crosslinked hydrogel polymer, and the crosslinked hydrogel polymer is heated during the drying step so that a maximum reaching temperature of the crosslinked hydrogel polymer exceeds 160°C, and/or the dry polymer is heated after the drying step so that a maximum reaching temperature of the dry polymer exceeds 160°C.
摘要:
[Problem] To provide, at low cost, a disposable diaper that presents no difficulties in disposable diaper manufacture in humid climates, and that has a minimal amount of flowback, and rapid absorption time. [Solution]Provided is a particulate water-absorbing agent having as the principal component a poly (meth) acrylic acid (salt)-based water absorbing resin, wherein the water-absorbing agent has a particle size distribution of a weight average particle diameter of 300 to 500 µm, a blocking ratio after moisture absorption when left for one hour at 25°C and 90% relative humidity of 20% or less, a surface tension of 60 mN/m or more, and a gel capillary absorption (GCA) of 28.0 g/g or more.
摘要:
To provide a water absorbing agent which is excellent in balance between absorbency and liquid permeability against pressure and is excellent in flowability at the time of moisture absorption. The water absorbing agent comprises water absorbent resin particles and an organic surface additive, wherein: the organic surface additive having (i) a reactive group for a functional group of a surface of each water absorbent resin particle and (ii) a hydrophobic group exists on the surface of the water absorbent resin particle, and the hydrophobic group has a hydrocarbon group whose carbon number is 8 or more, and a ratio of an oxyalkylene group in a molecular mass of the organic surface additive is 0 or more and 25 mass% or less.
摘要:
To provide a disposable diaper enabling reduction in re-wet amount and having an excellent speed of incorporating liquid regardless of concentration and configuration of a water-absorbing agent in an absorbent material. A water-absorbing agent having excellent Gel Capillary Absorption (GCA) and Free Gel Bed Permeability (FGBP) is obtained by crushing a crosslinked hydrogel polymer obtained in a polymerization step to have a specific weight average particle diameter while fluid retention capacity and a surface tension of a water-absorbing agent are adjusted in a specific range, drying the crushed crosslinked hydrogel polymer, and then adding a liquid permeability enhancer thereto during surface crosslinking or after surface crosslinking.
摘要:
The production method of a water absorbent resin composition including a particulate water absorbent resin, wherein: 95 wt % or more of particles whose particle diameter is less than 850 µm and not less, than 106 µm are contained, and a weight average particle diameter of the particles is less than 500 µm and not less than 300 µ m and a logarith mic standard deviation (σξ) of a particle size distribution is 0.45 or less, and a water-soluble component of the water absorbent composition is 35 wt % or less, and a multivalent metal component is contained, and an extraction rate of the multivalent metal component is 5.0 wt % or more and less than 100 wt %, thereby providing the water absorbent resin composition, free from any coagulation of particles in high humidity, which has superiror absorbent property in terms of an absorbency and a diffusing absorbency under pressure.
摘要:
The present invention has an object to provide a novel water-swellable crosslinked polymer composition which exhibits excellent saltwater absorption speed and capacity under a load. This object can be achieved in the case where, in a water-swellable crosslinked polymer composition comprising a blend of water-swellable crosslinked polymer particles of basicity in water and water-swellable crosslinked polymer particles of acidity in water, the water-swellable crosslinked polymer particles of basicity in water are unified with the water-swellable crosslinked polymer particles of acidity in water through ionic bondings in a state where water is present between the particles, wherein the ionic bondings are formed in a state where water is present between the particles by neutralization of at least part of acid groups of the water-swellable crosslinked polymer particles of acidity in water with the water-swellable crosslinked polymer particles of basicity in water.