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1.发明授权PRODUCING PROCESS OF FLUOROARYL MAGNESIUM DERIVATIVE AND PRODUCING PROCESS OF (FLUOROARYL)BORANE COMPOUND 失效用于生产氟化ARYLMAGNESIUMDERIVATE及其制造方法（氟化）-BORVERBINDUNGEN
公开(公告)号：EP0825195B1
公开(公告)日：2003-11-12
申请号：EP97902682.0
申请日：1997-02-12
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公开(公告)号：EP2428501B1
公开(公告)日：2018-12-12
申请号：EP10772168.0
申请日：2010-04-30
发明人： TANAKA, Tomoaki , KATSUMI, Ikuyo
摘要： Disclosed are: a diaryliodonium salt mixture which is a precursor of a BF 4 salt or the like of a diaryliodonium compound, can be produced in the form of crystals at ambient temperature, can be purified in a simple manner, can be produced with high efficiency, and can be induced into a BF 4 salt or the like salt that has excellent solubility in a monomer or the like; and a process for producing the diaryliodonium salt mixture. Also disclosed is a production process which can achieve good yield and can produce reduced amounts of byproducts, and is therefore applicable to the industrial mass production of a diaryliodonium compound. The diaryliodonium salt mixture is characterized by containing at least two specific diaryliodonium salts.
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3.发明公开DIARYL IODONIUM SALT MIXTURE AND PROCESS FOR PRODUCTION THEREOF, AND PROCESS FOR PRODUCTION OF DIARYL IODONIUM COMPOUND 审中-公开二芳基碘盐结构和工艺用于为二芳基碘相关生产及其制造方法
公开(公告)号：EP2428501A1
公开(公告)日：2012-03-14
申请号：EP10772168.0
申请日：2010-04-30
发明人： TANAKA, Tomoaki , KATSUMI, Ikuyo
摘要： Disclosed are: a diaryliodonium salt mixture which is a precursor of a BF 4 salt or the like of a diaryliodonium compound, can be produced in the form of crystals at ambient temperature, can be purified in a simple manner, can be produced with high efficiency, and can be induced into a BF 4 salt or the like salt that has excellent solubility in a monomer or the like; and a process for producing the diaryliodonium salt mixture. Also disclosed is a production process which can achieve good yield and can produce reduced amounts of byproducts, and is therefore applicable to the industrial mass production of a diaryliodonium compound. The diaryliodonium salt mixture is characterized by containing at least two specific diaryliodonium salts.
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4.发明公开PROCESS FOR THE PREPARATION OF FLUORINATED ARYLMAGNESIUM DERIVATIVES AND PROCESS FOR THE PREPARATION OF (FLUORINATED ARYL)BORON COMPOUNDS 失效用于生产氟化ARYLMAGNESIUMDERIVATE及其制造方法（氟化）-BORVERBINDUNGEN
公开(公告)号：EP0825195A1
公开(公告)日：1998-02-25
申请号：EP97902682.0
申请日：1997-02-12
摘要： The first invention relates to a process for preparing fluorinated arylmagnesium derivatives by reacting a fluorinated aromatic compound with a halogenated hydrocarbon and magnesium in an ethereal solvent or a mixture thereof with a hydrocarbon. According to this process, the objective compound can efficiently be prepared in one reaction step at a low cost. The obtained arylmagnesium derivatives are useful as reagents for introducing fluorinated aromatic groups into various organic compounds. The second invention relates to a process for preparing (fluorinated aryl) boron compounds by adding an ethereal solution of a fluorinated arylmagnesium derivative and an ethereal solution of a boron halide to a hydrocarbon having a boiling point higher than that of the solvent and reacting the arylmagnesium derivative with the boron halide while distilling away the solvent. This process makes it possible to prepare objective boron compounds selectively and at a low cost, thus being industrially advantageous. The obtained boron compounds are useful as co-catalysts for metallocence catalysts.
摘要翻译： 第一发明涉及一种用于通过在对醚溶剂或与烃或其混合物进行反应与卤代烃和镁含氟芳香族化合物制备氟化芳基镁衍生物的方法。 。根据该方法，目的化合物可以有效地在一个反应步骤以低成本制备。 所获得的芳基镁衍生物作为试剂用于引入含氟芳香族基团引入各种有机化合物是有用的。 第二发明涉及一种方法，用于通过向一个氟化芳基镁衍生物和以具有比溶剂更高的沸点的烃卤化硼的醚溶液的醚溶液和使下芳基镁制备（氟化芳基）硼化合物 与卤化硼衍生物同时蒸掉溶剂。 这个过程使得有可能选择性地制备目标硼化合物和以低成本，因此是工业上有利的。 将所得到的硼化合物作为助催化剂为metallocence催化剂是有用的。
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公开(公告)号：EP0804425A2
公开(公告)日：1997-11-05
申请号：EP95926512.0
申请日：1995-07-27
发明人： SATO, Yoshinari , SAKANE, Kazuo , TABUCHI, Seiichiro , MITSUI, Hitoshi , KATSUMI, Ikuyo , SATOH, Yuichi
IPC分类号： C07D243 , A61K31 , A61P1 , A61P25 , C07D401 , C07D403 , C07D405 , C07D409 , C07D413 , C07D417 , C07D487
CPC分类号： C07D243/24
摘要： Benzodiazepine derivatives of formula (I) wherein R1 is aryl which may have one or more suitable substituent(s), R2 is C3-C8 cycloalkyl which may have one or more suitable substituent(s), A is lower alkylene, R3 is a heterocyclic group selected from the group consisting of tetrahydrofuryl, dioxolanyl, furyl, thienyl, isoxazolyl, pyridyl, benzimidazolyl, benzothiazolyl, benzoxazolyl, benzopyranyl, quinolyl, isoquinolyl, tetrahydroisoquinolyl, benzothienyl and benzofuryl, each of which may have one or more suitable substituent(s), or a pharmaceutically acceptable salt thereof, which are useful as a medicament.
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公开(公告)号：EP2617752B1
公开(公告)日：2018-07-25
申请号：EP11825164.4
申请日：2011-09-13
发明人： TANAKA, Tomoaki , KATSUMI, Ikuyo
CPC分类号： C08F4/52 , C08F4/00 , C08G59/686
摘要： The objective of the present invention is to provide a composition used as a thermal-latent polymerization initiator which does not catalyze a polymerization at ordinary temperature but can catalyze at lower temperature and which has an excellent catalytic ability. In addition, the objective of the present invention is to provide a thermal-latent polymerization initiator consisting of the composition, a method of polymerization using the thermal-latent polymerization initiator, and a curable composition containing the thermal-latent polymerization initiator. The composition according to the present invention is characterized in comprising tris (pentafluorophenyl) borane and an amine compound having a specific piperidine structure.
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7.发明授权
公开(公告)号：EP1817318B1
公开(公告)日：2013-08-28
申请号：EP06712741.5
申请日：2006-01-25
发明人： KATSUMI, Ikuyo
IPC分类号： C07F5/02
CPC分类号： C07F5/027
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8.发明公开COMPOSITION USABLE AS HEAT-LATENT POLYMERIZATION INITIATOR 有权ALSWÄRMELATENTERPOLYMERISATIONSINITIATOR NUTZBARE ZUSAMMENSETZUNG
公开(公告)号：EP2617752A1
公开(公告)日：2013-07-24
申请号：EP11825164.4
申请日：2011-09-13
发明人： TANAKA, Tomoaki , KATSUMI, Ikuyo
CPC分类号： C08F4/52 , C08F4/00 , C08G59/686
摘要： The objective of the present invention is to provide a composition used as a thermal-latent polymerization initiator which does not catalyze a polymerization at ordinary temperature but can catalyze at lower temperature and which has an excellent catalytic ability. In addition, the objective of the present invention is to provide a thermal-latent polymerization initiator consisting of the composition, a method of polymerization using the thermal-latent polymerization initiator, and a curable composition containing the thermal-latent polymerization initiator. The composition according to the present invention is characterized in comprising tris (pentafluorophenyl) borane and an amine compound having a specific piperidine structure.
摘要翻译： 本发明的目的是提供一种用作热潜伏型聚合引发剂的组合物，其不会在常温下催化聚合反应，而是能够在较低的温度下催化并具有优异的催化能力。 此外，本发明的目的是提供一种由该组合物组成的热潜电聚合引发剂，使用该热潜聚合引发剂的聚合方法和含有该潜热聚合引发剂的固化性组合物。 根据本发明的组合物的特征在于包含三（五氟苯基）硼烷和具有特定哌啶结构的胺化合物。
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9.发明公开
公开(公告)号：EP1817318A1
公开(公告)日：2007-08-15
申请号：EP06712741.5
申请日：2006-01-25
发明人： KATSUMI, Ikuyo
IPC分类号： C07F5/02
CPC分类号： C07F5/027
摘要： A method for stabilizing an aryl boron compound of formula (1): wherein Ar1, Ar2, and Ar3 are aryl groups, including mixing a compound which has higher affinity for the aryl boron compound than water, as a stabilizer, in a solution or slurry containing the aryl boron compound in a hydrocarbon solvent; and a stabilized composition obtained thereby. The stabilizing method and the stabilized composition of the present invention make it possible to store aryl boron compounds stably over a long term, while keeping their high purity, in the form of forming a substantially homogeneous system in the case of a solution or in the form of forming a substantially homogeneous system by heating in the case of slurry.
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