摘要:
The invention relates to an organic electronic component having a matrix containing a zinc complex as a p-dopant, said zinc complex in turn containing at least one ligand L of the following structure: formula (I) wherein R 1 and R 2 can be oxygen, sulphur, selenium, NH or NR 4 independently from one another, wherein R 4 is selected from the group containing alkyl or aryl and which can be bonded to R 3 , and wherein R 3 is selected from the group containing alkyl, long-chain alkyl, cycloalkyl, halogen-alkyl, aryl, arylene, halogen-aryl, heteroaryl, heteroarylene, heterocyclic-alkylene, heterocycloalkyl, halogen-heteroaryl, alkenyl, halogen-alkenyl, alkynyl, halogen-alkynyl, ketoaryl, halogen-ketoaryl, ketoheteroaryl, ketoalkyl, halogen-ketoalkyl, ketoalkenyl, halogen-ketoalkenyl, halogen-alkyl-aryl, halogen-alkyl-heteroaryl, wherein, for suitable groups, one or a number of non-adjacent CH 2 -groups can be replaced by -O-, -S-, -NH-, -NR°°°-, -SiR°R°°-, -CO-, -COO-, -COR°OR°°-, -OCO-, -OCO-O-, -SO2-, -S-CO-, -CO-S-, -O-CS-, -CS-O-, -CY1=CY2 or -C≡C- independently from one another, and in such a way that O and/or S atoms are not directly bonded to one another, and are replaced optionally with aryl- or heteroaryl preferably containing between 1 and 30 C atoms (terminal CH 3 -groups are understood to be CH 2 -groups in the sense of CH2 -H).
摘要:
The present invention relates to a main group metal complex of groups 13 to 16 comprising at least one ligand of the structure (I), where R 1 und R 2 can be, independently of each other, oxygen, sulfur, selenium, NH or NR 4 , where R 4 is selected from the group consisting of alkyl or aryl and can be connected to R 3 ; and R 3 is selected from the group consisting of alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, halogenalkyl, aryl, arylene, halogenaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, halogenheteroaryl, alkenyl, halogenalkenyl, alkynyl, halogenalkynyl, ketoaryl, halogenketoaryl, ketoheteroaryl, ketoalkyl, halogenketoalkyl, ketoalkenyl, halogenketoalkenyl, wherein in suitable radicals one or more non-adjacent CH 2 -groups can be substituted independently of one another by -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO 2 -, -S-CO-, -CO-S-, -CY1=CY2 or -C≡C-, specifically in such a way that O and/or S atoms are not connected directly to one another, are likewise optionally substituted with aryl- or heteroaryl preferably containing 1 to 30 C atoms, as a dopant for matrix materials in organic electronic components.
摘要:
The invention relates to a method for producing an organic electronic component, wherein the component comprises at least one organic electronic layer having a matrix, wherein the matrix contains a metal complex as a dopant, which metal complex comprises at least one metal atom M and at least one ligand L bonded to the metal atom M, wherein the ligands L have the following structure independently of each other: wherein E 1 and E 2 can be oxygen, sulfur, selenium, NH, or NR' independently of each other, wherein R' is selected from the group containing alkyl or aryl and can be bonded to the substituted benzene ring of the ligand L; and the substituents R 1 are selected independently of each other from the group comprising branched or unbranched, fluorinated aliphatic hydrocarbons having 1 to 10 C atoms, wherein n = 1 to 5; and the substituents R 2 are selected independently of each other from the group comprising –CN, branched or unbranched aliphatic hydrocarbons having 1 to 10 C atoms, aryl, and heteroaryl, wherein m = 0 to at most 5 - n; wherein the deposition of the dopant of the at least one organic electronic layer occurs by means of gas-phase deposition by use of a source, wherein the source is designed in such a way that the dopant experiences impacts with at least one wall of the source.
摘要:
The invention relates to a bi- or polynuclear metal complex of a metal of groups Vb/VIb/VIIb, or rather groups 5-7, having at least one ligand of the structure (a), wherein R 1 and R 2 , independently of each other, can be oxygen, sulfur, selenium, NH, or NR 4 , wherein R 4 is selected from the group containing alkyl or aryl and can be bonded to R 3 ; and R 3 is selected from the group containing alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, haloalkyl, aryl, arylenes, haloaryl, heteroaryl, heteroarylenes, heterocycloalkylenes, heterocycloalkyl, haloheteroaryl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, ketoaryl, haloketoaryl, ketoheteroaryl, ketoalkyl, haloketoalkyl, ketoalkenyl, haloketoalkenyl, wherein for suitable residues, one or more non-adjacent CH 2 groups can be replaced, independently of each other, with -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO2-, -S-CO-, -CO-S-, -CY1=CY2, or -C≡C- in such a way that O and/or S atoms are not bonded directly to each other, likewise optionally are replaced with aryl or heteroaryl preferably containing 1 to 30 C atoms, as a p-type doping agent for matrix materials of electronic components.