ORGANISCHES ELEKTRONISCHES BAUTEIL, VERWENDUNG EINES ZINKKOMPLEXES ALS P-DOTIERUNGSMITTEL FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN
    2.
    发明公开
    ORGANISCHES ELEKTRONISCHES BAUTEIL, VERWENDUNG EINES ZINKKOMPLEXES ALS P-DOTIERUNGSMITTEL FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN 审中-公开
    ORGANISCHES ELEKTRONISCHES BAUTEIL,VERWENDUNG EINES ZINKKOMPLEXES ALS P-DOTIERUNGSMITTELFÜRORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN

    公开(公告)号:EP3201962A1

    公开(公告)日:2017-08-09

    申请号:EP15771577.2

    申请日:2015-09-28

    申请人: OSRAM OLED GmbH

    IPC分类号: H01L51/50

    摘要: The invention relates to an organic electronic component having a matrix containing a zinc complex as a p-dopant, said zinc complex in turn containing at least one ligand L of the following structure: formula (I) wherein R
    1 and R
    2 can be oxygen, sulphur, selenium, NH or NR
    4 independently from one another, wherein R
    4 is selected from the group containing alkyl or aryl and which can be bonded to R
    3 , and wherein R
    3 is selected from the group containing alkyl, long-chain alkyl, cycloalkyl, halogen-alkyl, aryl, arylene, halogen-aryl, heteroaryl, heteroarylene, heterocyclic-alkylene, heterocycloalkyl, halogen-heteroaryl, alkenyl, halogen-alkenyl, alkynyl, halogen-alkynyl, ketoaryl, halogen-ketoaryl, ketoheteroaryl, ketoalkyl, halogen-ketoalkyl, ketoalkenyl, halogen-ketoalkenyl, halogen-alkyl-aryl, halogen-alkyl-heteroaryl, wherein, for suitable groups, one or a number of non-adjacent CH
    2 -groups can be replaced by -O-, -S-, -NH-, -NR°°°-, -SiR°R°°-, -CO-, -COO-, -COR°OR°°-, -OCO-, -OCO-O-, -SO2-, -S-CO-, -CO-S-, -O-CS-, -CS-O-, -CY1=CY2 or -C≡C- independently from one another, and in such a way that O and/or S atoms are not directly bonded to one another, and are replaced optionally with aryl- or heteroaryl preferably containing between 1 and 30 C atoms (terminal CH
    3 -groups are understood to be CH
    2 -groups in the sense of CH2 -H).

    摘要翻译: 本发明涉及具有含锌配合物作为p-掺杂剂的基体的有机电子元件,所述锌配合物又含有至少一种具有以下结构的配体L:式(I)其中R1和R2可以是氧,硫 ,硒,NH或NR 4彼此独立地,其中R 4选自包含烷基或芳基并且可以与R 3键合的基团,并且其中R 3选自烷基,长链烷基,环烷基,卤素取代的烷基, 烷基,芳基,亚芳基,卤素 - 芳基,杂芳基,杂亚芳基,杂环亚烷基,杂环烷基,卤素 - 杂芳基,烯基,卤代烯基,炔基,卤代炔基,酮芳基,卤代酮基芳基,酮杂芳基, 酮基,卤代 - 酮基烯基,卤代 - 烷基 - 芳基,卤代 - 烷基 - 杂芳基,其中对于合适的基团,一个或多个不相邻的CH 2 - 基团可以被-O - , - ,-NR 0° - , - SiR°R° - , - CO - , - COO - , - COR 0 OR 0 - , - OCO - , - O CO-O - , - CO-S - , - O-CS-,-CS-O-,-CY1 = CY2或-C≡C-彼此独立, 使得O和/或S原子不直接彼此键合,并且任选地被优选含有1至30个C原子的芳基 - 或杂芳基取代(末端CH 3 - 基团理解为在意义上的CH 2 - 基团 的CH 2 -H)。

    HAUPTGRUPPENMETALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN
    6.
    发明公开
    HAUPTGRUPPENMETALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN 有权
    主族金属络合物作为P-掺杂剂用于有机电子基体材料

    公开(公告)号:EP2845239A2

    公开(公告)日:2015-03-11

    申请号:EP13723470.4

    申请日:2013-05-14

    IPC分类号: H01L51/00

    摘要: The present invention relates to a main group metal complex of groups 13 to 16 comprising at least one ligand of the structure (I), where R
    1 und R
    2 can be, independently of each other, oxygen, sulfur, selenium, NH or NR
    4 , where R
    4 is selected from the group consisting of alkyl or aryl and can be connected to R
    3 ; and R
    3 is selected from the group consisting of alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, halogenalkyl, aryl, arylene, halogenaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, halogenheteroaryl, alkenyl, halogenalkenyl, alkynyl, halogenalkynyl, ketoaryl, halogenketoaryl, ketoheteroaryl, ketoalkyl, halogenketoalkyl, ketoalkenyl, halogenketoalkenyl, wherein in suitable radicals one or more non-adjacent CH
    2 -groups can be substituted independently of one another by -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO
    2 -, -S-CO-, -CO-S-, -CY1=CY2 or -C≡C-, specifically in such a way that O and/or S atoms are not connected directly to one another, are likewise optionally substituted with aryl- or heteroaryl preferably containing 1 to 30 C atoms, as a dopant for matrix materials in organic electronic components.

    VERFAHREN ZUR HERSTELLUNG EINES ORGANISCHEN ELEKTRONISCHEN BAUTEILS UND EIN ORGANISCHES ELEKTRONISCHES BAUTEIL

    公开(公告)号:EP3201959A1

    公开(公告)日:2017-08-09

    申请号:EP14825342.0

    申请日:2014-12-22

    申请人: OSRAM OLED GmbH

    摘要: The invention relates to a method for producing an organic electronic component, wherein the component comprises at least one organic electronic layer having a matrix, wherein the matrix contains a metal complex as a dopant, which metal complex comprises at least one metal atom M and at least one ligand L bonded to the metal atom M, wherein the ligands L have the following structure independently of each other: wherein E
    1 and E
    2 can be oxygen, sulfur, selenium, NH, or NR' independently of each other, wherein R' is selected from the group containing alkyl or aryl and can be bonded to the substituted benzene ring of the ligand L; and the substituents R
    1 are selected independently of each other from the group comprising branched or unbranched, fluorinated aliphatic hydrocarbons having 1 to 10 C atoms, wherein n = 1 to 5; and the substituents R
    2 are selected independently of each other from the group comprising –CN, branched or unbranched aliphatic hydrocarbons having 1 to 10 C atoms, aryl, and heteroaryl, wherein m = 0 to at most 5 - n; wherein the deposition of the dopant of the at least one organic electronic layer occurs by means of gas-phase deposition by use of a source, wherein the source is designed in such a way that the dopant experiences impacts with at least one wall of the source.

    摘要翻译: 本发明涉及一种用于制造有机电子部件的方法,其中所述部件包含至少一个具有基体的有机电子层,其中所述基体含有金属络合物作为掺杂剂,所述金属络合物包含至少一个金属原子M和 至少一个与金属原子M键合的配体L,其中配体L彼此独立地具有以下结构:其中E1和E2可以彼此独立地为氧,硫,硒,NH或NR',其中R'为 选自含有烷基或芳基的基团并且可以与配体L的取代苯环键合; 并且取代基R 1彼此独立地选自具有1至10个C原子的支链或非支链的氟化脂族烃,其中n = 1至5; 并且取代基R 2彼此独立地选自-CN,具有1至10个C原子的支链或无支链脂族烃,芳基和杂芳基,其中m = 0至至多5-n; 其中所述至少一个有机电子层的掺杂剂的沉积借助于通过使用源的气相沉积而发生,其中所述源被设计为使得所述掺杂剂经历与所述源的至少一个壁 。

    METALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN
    8.
    发明公开
    METALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN 有权
    金属络合物作为P-掺杂剂用于有机电子基体材料

    公开(公告)号:EP2845240A1

    公开(公告)日:2015-03-11

    申请号:EP13724548.6

    申请日:2013-05-14

    IPC分类号: H01L51/00 H01L51/50 H01L51/42

    摘要: The invention relates to a bi- or polynuclear metal complex of a metal of groups Vb/VIb/VIIb, or rather groups 5-7, having at least one ligand of the structure (a), wherein R
    1 and R
    2 , independently of each other, can be oxygen, sulfur, selenium, NH, or NR
    4 , wherein R
    4 is selected from the group containing alkyl or aryl and can be bonded to R
    3 ; and R
    3 is selected from the group containing alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, haloalkyl, aryl, arylenes, haloaryl, heteroaryl, heteroarylenes, heterocycloalkylenes, heterocycloalkyl, haloheteroaryl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, ketoaryl, haloketoaryl, ketoheteroaryl, ketoalkyl, haloketoalkyl, ketoalkenyl, haloketoalkenyl, wherein for suitable residues, one or more non-adjacent CH
    2 groups can be replaced, independently of each other, with -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO2-, -S-CO-, -CO-S-, -CY1=CY2, or -C≡C- in such a way that O and/or S atoms are not bonded directly to each other, likewise optionally are replaced with aryl or heteroaryl preferably containing 1 to 30 C atoms, as a p-type doping agent for matrix materials of electronic components.