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    HAUPTGRUPPENMETALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN
    3.
    发明公开
    HAUPTGRUPPENMETALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN 有权
    主族金属络合物作为P-掺杂剂用于有机电子基体材料

    公开(公告)号：EP2845239A2

    公开(公告)日：2015-03-11

    申请号：EP13723470.4

    申请日：2013-05-14

    申请人： Siemens Aktiengesellschaft ,  OSRAM OLED GmbH

    发明人： MALTENBERGER, Anna ,  PETRUKHINA, Marina A. ,  SCHMID, Günter ,  WEMKEN, Jan Hauke

    IPC分类号： H01L51/00

    CPC分类号： H01L51/0077 ,  C07F9/94 ,  C09K11/06 ,  C09K2211/188 ,  H01L51/002 ,  H01L51/009 ,  H01L51/506 ,  Y02E10/549 ,  Y02P70/521

    摘要： The present invention relates to a main group metal complex of groups 13 to 16 comprising at least one ligand of the structure (I), where R
    1 und R
    2 can be, independently of each other, oxygen, sulfur, selenium, NH or NR
    4 , where R
    4 is selected from the group consisting of alkyl or aryl and can be connected to R
    3 ; and R
    3 is selected from the group consisting of alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, halogenalkyl, aryl, arylene, halogenaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, halogenheteroaryl, alkenyl, halogenalkenyl, alkynyl, halogenalkynyl, ketoaryl, halogenketoaryl, ketoheteroaryl, ketoalkyl, halogenketoalkyl, ketoalkenyl, halogenketoalkenyl, wherein in suitable radicals one or more non-adjacent CH
    2 -groups can be substituted independently of one another by -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO
    2 -, -S-CO-, -CO-S-, -CY1=CY2 or -C≡C-, specifically in such a way that O and/or S atoms are not connected directly to one another, are likewise optionally substituted with aryl- or heteroaryl preferably containing 1 to 30 C atoms, as a dopant for matrix materials in organic electronic components.

    METALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN
    4.
    发明公开
    METALLKOMPLEXE ALS P-DOTANDEN FÜR ORGANISCHE ELEKTRONISCHE MATRIXMATERIALIEN 有权
    金属络合物作为P-掺杂剂用于有机电子基体材料

    公开(公告)号：EP2845240A1

    公开(公告)日：2015-03-11

    申请号：EP13724548.6

    申请日：2013-05-14

    申请人： Siemens Aktiengesellschaft ,  OSRAM OLED GmbH

    发明人： MALTENBERGER, Anna ,  SCHMID, Günter ,  WEMKEN, Jan Hauke ,  PECQUEUR, Sébastien

    IPC分类号： H01L51/00 ,  H01L51/50 ,  H01L51/42

    CPC分类号： H01L51/009 ,  H01L51/42 ,  H01L51/506 ,  Y02E10/549

    摘要： The invention relates to a bi- or polynuclear metal complex of a metal of groups Vb/VIb/VIIb, or rather groups 5-7, having at least one ligand of the structure (a), wherein R
    1 and R
    2 , independently of each other, can be oxygen, sulfur, selenium, NH, or NR
    4 , wherein R
    4 is selected from the group containing alkyl or aryl and can be bonded to R
    3 ; and R
    3 is selected from the group containing alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, haloalkyl, aryl, arylenes, haloaryl, heteroaryl, heteroarylenes, heterocycloalkylenes, heterocycloalkyl, haloheteroaryl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, ketoaryl, haloketoaryl, ketoheteroaryl, ketoalkyl, haloketoalkyl, ketoalkenyl, haloketoalkenyl, wherein for suitable residues, one or more non-adjacent CH
    2 groups can be replaced, independently of each other, with -O-, -S-, -NH-, -NR°-, -SiR°R°°-, -CO-, -COO-, -OCO-, -OCO-O-, -SO2-, -S-CO-, -CO-S-, -CY1=CY2, or -C≡C- in such a way that O and/or S atoms are not bonded directly to each other, likewise optionally are replaced with aryl or heteroaryl preferably containing 1 to 30 C atoms, as a p-type doping agent for matrix materials of electronic components.