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    Compositions based on resins having silicon atoms attached to hydrolyzable groups derived from vinyl silanes and mercaptofunctional compounds
    4.
    发明公开
    Compositions based on resins having silicon atoms attached to hydrolyzable groups derived from vinyl silanes and mercaptofunctional compounds 失效
    基于具有连接到由乙烯基硅烷和巯基官能化合物衍生的可水解组的硅氧烷的树脂的组合物

    公开(公告)号：EP0231514A3

    公开(公告)日：1989-08-30

    申请号：EP86118030.5

    申请日：1986-12-24

    Applicant: PPG INDUSTRIES, INC.

    Inventor： Dowbenko, Rostyslaw ,  Singer, Debra Lynn ,  Blackburn, William Pelham ,  Williams, Frank Clair, Jr.

    IPC: C08G85/00 ,  C08L101/10

    CPC classification number: C09D201/10 ,  C08G18/4692 ,  C08G18/6295 ,  C08G18/837 ,  C08L75/04 ,  C09D143/04 ,  C08L43/04 ,  C08L2666/10

    Abstract: Disclosed is a resin containing at least one molecule having in a terminal and/or side chain thereof at least one group corresponding to the following formula (I)
    wherein
    Q is the residue of a substance selected from the group consisting of a polyester resin, an acrylic resin, a urethane resin, a polyamide resin, and a polyether resin, each Y, which may be the same or different, represents a hydrolyzable group, each R, which may be the same or different, represents a C 1 -C 4 alkyl group, a vinyl group or an allyl group, each R', which may be the same or different, represents H or a C 1 -C 4 alkyl group, a represents an integer of from 0 to 2, b represents an integer of from 0 to 6, and n represents an integer of from 1 to 2. Also disclosed is a curable composition based on a resin corresponding to formula (1) and the composition additionally containing an organic polyol and/or a reactive silicon-containing constituent different from the resin of formula (I) which silicon-containing constituent contains a hydrolyzable group bonded to silicon. Also disclosed is a curable composition containing (A) a first silicon-containing resin containing at least one molecule having in a terminal and/or side chain thereof at least one silicon atom bonded to a group Y, wherein Y represents a hydrolyzable group; and (B) a second silicon-containing resin, different from the first silicon-containing resin, the second silicon-containing resin being a resin of the invention. In preferred compositions, the second silicon-containing resin serves as a flexibilizer for the composition.

    Compositions based on resins having silicon atoms attached to hydrolyzable groups derived from vinyl silanes and mercaptofunctional compounds
    6.
    发明公开
    Compositions based on resins having silicon atoms attached to hydrolyzable groups derived from vinyl silanes and mercaptofunctional compounds 失效
    基于含有键合到可水解基团和其中硅原子的树脂组合物是由乙烯基硅烷，和巯基官能化合物制备。

    公开(公告)号：EP0231514A2

    公开(公告)日：1987-08-12

    申请号：EP86118030.5

    申请日：1986-12-24

    Applicant: PPG INDUSTRIES, INC.

    Inventor： Dowbenko, Rostyslaw ,  Singer, Debra Lynn ,  Blackburn, William Pelham ,  Williams, Frank Clair, Jr.

    IPC: C08G85/00 ,  C08L101/10

    CPC classification number: C09D201/10 ,  C08G18/4692 ,  C08G18/6295 ,  C08G18/837 ,  C08L75/04 ,  C09D143/04 ,  C08L43/04 ,  C08L2666/10

    Abstract: Disclosed is a resin containing at least one molecule having in a terminal and/or side chain thereof at least one group corresponding to the following formula (I)
    wherein

    Q is the residue of a substance selected from the group consisting of a polyester resin, an acrylic resin, a urethane resin, a polyamide resin, and a polyether resin, each Y, which may be the same or different, represents a hydrolyzable group, each R, which may be the same or different, represents a C 1 -C 4 alkyl group, a vinyl group or an allyl group, each R', which may be the same or different, represents H or a C 1 -C 4 alkyl group,
    a represents an integer of from 0 to 2,
    b represents an integer of from 0 to 6, and
    n represents an integer of from 1 to 2.

    Also disclosed is a curable composition based on a resin corresponding to formula (1) and the composition additionally containing an organic polyol and/or a reactive silicon-containing constituent different from the resin of formula (I) which silicon-containing constituent contains a hydrolyzable group bonded to silicon.
    Also disclosed is a curable composition containing (A) a first silicon-containing resin containing at least one molecule having in a terminal and/or side chain thereof at least one silicon atom bonded to a group Y, wherein Y represents a hydrolyzable group; and (B) a second silicon-containing resin, different from the first silicon-containing resin, the second silicon-containing resin being a resin of the invention.
    In preferred compositions, the second silicon-containing resin serves as a flexibilizer for the composition.

    Abstract translation: 公开的是含有具有在末端和/或侧链上的至少一组对应于下式（I） worin Q是物质从组中选择的残基组成的聚酯中的至少一种分子的树脂 树脂的丙烯酸类树脂，聚氨酯树脂，聚酰胺树脂，和聚醚树脂，各Y，其可以是相同或不同的，可水解基团darstellt，每个R可以相同或不同，是C1 darstellt C4烷基，在烯丙基，每一个R”为乙烯基或，其可以是相同或不同的，darstellt H或C1-C4烷基，从0至2的整数的darstellt，b darstellt从整数的 0至6，并且n darstellt 1至2。所以盘的游离缺失整数是基于对应于式（I）树脂的可固化组合物和另外含有有机多元醇和/或反应性含硅组分differentFrom的组合物 式（I）其中硅containi的树脂 纳克组分包含与硅键合可水解基团。 所以本发明提供一种可固化组合物含有（a）含有具有在末端和/或侧链的至少一个分子的第一含聚硅氧烷的树脂键合到Y基团的至少一个硅原子，worin Y表示可水解基团; 和（B）的第二含硅的树脂，从所述第一含硅的树脂不同，第二含硅氧烷树脂是本发明的的树脂。 在优选的组合物，所述第二含硅的树脂用作用于组合物中的增韧剂。

    Aromatic acid catalysts providing improved humidity resistance
    7.
    发明公开
    Aromatic acid catalysts providing improved humidity resistance 失效
    芳香酸催化剂提供改善的耐湿性

    公开(公告)号：EP0144810A3

    公开(公告)日：1986-04-02

    申请号：EP84113624

    申请日：1984-11-12

    Applicant: PPG INDUSTRIES, INC.

    Inventor： Singer, Debra Lynn ,  Dowbenko, Rostyslaw ,  McCollum, Gregory James ,  O'Dwyer, James Brendan

    IPC: C08K05/42 ,  C09D03/48

    CPC classification number: C08K5/42

    Abstract: Curable compositions with improved humidity resistance are composed of an active hydrogen-containing resin which is essentially free of glycidyl groups, a curing agent present externally and / or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a sulfonic acid having a molecular weight of less than 500 and represented by the following formula:
    wherein:
    Z is a radical independently selected from C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 18 aryl, halogen, alkoxy, hydroxyl, and aryloxy; R is independently selected from hydrogen, C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl and C 6 to C 18 aryl; y is an integer from 0 to 4; w is an integer from 0 to 2; x is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 2.

    Aminoplast curable compositions containing disulfonic acid esters as latent acid catalysts
    8.
    发明公开
    Aminoplast curable compositions containing disulfonic acid esters as latent acid catalysts 失效
    含有不饱和酸酯的氨基酸可固化组合物作为酸性催化剂

    公开(公告)号：EP0142805A3

    公开(公告)日：1986-03-19

    申请号：EP84113625

    申请日：1984-11-12

    Applicant: PPG INDUSTRIES, INC.

    Inventor： Singer, Debra Lynn ,  Dowbenko, Rostyslaw ,  McCollum, Gregory James

    IPC: C08K05/42 ,  C09D03/52

    CPC classification number: C07C309/00 ,  C08K5/42 ,  C08L61/20

    Abstract: An improved curable composition capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent and a sulfonate as latent acid catalyst. The catalyst is represented by the following structural formula:
    wherein Z is a radical independently selected from C, to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 18 aryl, halogen, alkoxy, hydroxyl, and aryloxy; R is independently selected from hydrogen, C, to C 20 alkyl, C 3 to C 20 cycloalkyl, and C 6 to C 18 aryl; R' is independently selected from C, to C 20 alkyl, C 3 to C 20 cycloalkyl, hydroxyalkyl, and hydroxycycloalkyl;
    y is an integer from 0 to 4, w is an integer from 0 to 2, and x is an integer from 1 to 3.

    Curable composition
    9.
    发明公开
    Curable composition 失效
    固化的组合物。

    公开(公告)号：EP0144810A2

    公开(公告)日：1985-06-19

    申请号：EP84113624.5

    申请日：1984-11-12

    Applicant: PPG INDUSTRIES, INC.

    Inventor： Singer, Debra Lynn ,  Dowbenko, Rostyslaw ,  McCollum, Gregory James ,  O'Dwyer, James Brendan

    IPC: C08K5/42 ,  C09D3/48

    CPC classification number: C08K5/42

    Abstract: Curable compositions with improved humidity resistance are composed of an active hydrogen-containing resin which is essentially free of glycidyl groups, a curing agent present externally and / or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a sulfonic acid having a molecular weight of less than 500 and represented by the following formula:
    wherein:

    Z is a radical independently selected from C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl, C 6 to C 18 aryl, halogen, alkoxy, hydroxyl, and aryloxy;
    R is independently selected from hydrogen, C 1 to C 20 alkyl, C 3 to C 20 cycloalkyl and C 6 to C 18 aryl;
    y is an integer from 0 to 4;
    w is an integer from 0 to 2;
    x is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 2.

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