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1.发明公开PROCEDE DE SYNTHESE DE 2,5-DI(HYDROXYMETHYL)FURANE ET DE 2,5-DI(HYDROXYMETHYL)TETRAHYDROFURANE PAR HYDROGENATION SELECTIVE DE FURANE-2,5-DIALDEHYDE 有权合成PROCESS FOR -2,5-二（羟甲基）呋喃和2,5-二（羟甲基）呋喃-2,5-二醛的四氢呋喃BY SELECTIV加氢
公开(公告)号：EP2900648A1
公开(公告)日：2015-08-05
申请号：EP13779316.2
申请日：2013-09-26
申请人： Roquette Frères
IPC分类号： C07D307/12 , C07D307/40
CPC分类号： C07D307/42 , C07D307/12 , C07D307/40
摘要： The present invention relates to a method for selective hydrogenation of furan-2,5-dialdehyde (DFF) into 2,5-di(hydroxymethyl)furan (DHMF) and into 2,5-di(hydroxymethyl)tetrahydrofuran (DHMTHF). In relation to the prior art, which uses C6 sugars or 5-hydroxymethyl furaldehyde (5-HMF) as raw materials, said method can be performed at low temperatures (lower than 120 °C, preferably 80 °C), while consuming low amounts of catalyst relative to the initial reagent (in particular less than 5 %, preferably less than 2 % relative to the weight of the reagent). The heterogeneous catalyst used can also be recycled from one reaction to another. Finally, the choice of experimental conditions enables the selective formation of DHMF or DHMTHF.
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2.发明公开PROCEDE DE SYNTHESE DE L'ACIDE 2,5-FURANE DICARBOXYLIQUE A PARTIR D'UNE COMPOSITION CONTENANT DU FURANE-2,5-DIALDEHYDE 有权方法合成的2,5-呋喃二羧酸从与呋喃-2,5-二醛A组合物
公开(公告)号：EP2900649A1
公开(公告)日：2015-08-05
申请号：EP13779317.0
申请日：2013-09-26
申请人： Roquette Frères
IPC分类号： C07D307/46 , C07D307/68
CPC分类号： C07D307/68 , C07D307/46
摘要： The present invention relates to a method for synthesising 2,5-furandicarboxylic acid (FDCA) from furan-2,5-dialdehyde (DFF). Said method is industrially applicable due to the simplicity and availability of the reagents used, and due to the experimental conditions on which said method is based: the method requires low temperatures and enables a reaction under atmospheric pressure, the reaction times being relatively short. Furthermore, the method does not lead to the formation of salts that need to be treated downstream from the method, and the catalytic ratio relative to the initial product is particularly low.
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公开(公告)号：EP2900649B1
公开(公告)日：2018-07-04
申请号：EP13779317.0
申请日：2013-09-26
申请人： Roquette Frères
IPC分类号： C07D307/46 , C07D307/68
CPC分类号： C07D307/68 , C07D307/46
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4.发明授权PROCEDE DE SYNTHESE DE 2,5-DI(HYDROXYMETHYL)FURANE ET DE 2,5-DI(HYDROXYMETHYL)TETRAHYDROFURANE PAR HYDROGENATION SELECTIVE DE FURANE-2,5-DIALDEHYDE 有权合成VERFAHRENFÜR2,5-DI（羟甲基）呋喃2,5-二（羟甲基）四氢呋喃选择选择性水杨酸呋喃-2,5-二氯乙烯
公开(公告)号：EP2900648B1
公开(公告)日：2017-05-17
申请号：EP13779316.2
申请日：2013-09-26
申请人： Roquette Frères
IPC分类号： C07D307/12 , C07D307/40
CPC分类号： C07D307/42 , C07D307/12 , C07D307/40
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