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1.发明公开AN ON-LINE GAS CHROMATOGRAPHY SYSTEM AND THE USE THEREOF FOR ANALYZING CATALYTIC REACTIONS 审中-公开在线气相色谱系统及其用于分析催化反应的用途
公开(公告)号：EP3254099A1
公开(公告)日：2017-12-13
申请号：EP16704704.2
申请日：2016-02-04
CPC分类号： G01N30/32 , B01J8/001 , B01J8/025 , B01J8/0278 , B01J8/067 , B01J19/2455 , B01J2208/00061 , B01J2208/00407 , B01J2208/00548 , B01J2208/00628 , B01J2208/027 , B01J2219/00033 , G01N30/68 , G01N2030/025 , G05D16/04
摘要： An on-line gas chromatography system for a fixed-bed continuous flow reactor and a method for on-line gas analysis of a catalytic reaction using the gas chromatography system. A reactor flow loop, a gas chromatogram, and a hydrostatic regulator are present in the gas chromatography system, wherein the reactor flow loop contains a fixed-bed reactor, a purge gas source, a feed gas source, and a by-pass line for reaction calibration.
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2.发明公开ENHANCED PERFORMANCE OF THE DEHYDROGENATION BY THE REDUCTION OF COKE FORMATION USING PRE-ACTIVATED CO2 审中-公开预活化CO2减少焦炭形成对脱氢的促进作用
公开(公告)号：EP3160924A1
公开(公告)日：2017-05-03
申请号：EP15725425.1
申请日：2015-05-05
CPC分类号： C07C5/333 , B01J19/088 , B01J23/72 , B01J2219/00123 , B01J2219/0805 , B01J2219/0871 , B01J2219/0894 , C07C5/3332 , C07C2521/04 , C07C2521/06 , C07C2523/26 , C21C5/28 , H05H1/2406 , H05H2245/1215 , C07C11/09
摘要： The present disclosure addresses the deficiencies described above by providing systems and methods for enhancing the efficiency and yield of alkene production. The methods and systems provide for the use of activated CO
2 in a dehydrogenation reactor along with an alkane stream. Through the use of the methods and systems of the invention, catalyst deactivation by coke deposition is reduced and the selectivity and efficiency of the dehydrogenation reaction is improved.摘要翻译： 本公开通过提供用于提高烯烃生产的效率和产量的系统和方法来解决上述缺陷。 该方法和系统提供了在脱氢反应器中使用活性CO 2以及烷烃流。 通过使用本发明的方法和系统，减少了由焦炭沉积引起的催化剂失活，并且提高了脱氢反应的选择性和效率。
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公开(公告)号：EP3240770B1
公开(公告)日：2019-02-13
申请号：EP15823818.8
申请日：2015-12-29
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4.发明公开
公开(公告)号：EP3224227A1
公开(公告)日：2017-10-04
申请号：EP15810770.6
申请日：2015-11-25
CPC分类号： C07C5/3332 , B01J23/26 , B01J23/92 , B01J38/04 , C07C2523/26 , C09K5/16 , Y02P20/146 , Y02P20/584 , C07C11/02 , C07C11/09
摘要： A process of catalytically dehydrogenating an alkane to an alkene, using Cr2O3 as a catalyst, where the catalyst is reduced concurrently with the dehydrogenation by using CO as a reducing gas. In reducing the catalyst with CO, CO2 is produced, which may be reacted with H2 produced by the dehydrogenation, to form CO and H2O by the reverse water-gas shift reaction. A Cu O heat-releasing material may be included with the catalyst in the reactor. The CO reducing gas reduces CuO to form Cu and CO2, releasing heat. The CO2 produced by reducing the Cu O may also be reacted with H2 produced by the dehydrogenation, to form CO and H2O by the reverse water-gas shift reaction.
摘要翻译： 使用Cr 2 O 3作为催化剂将烷烃催化脱氢为烯烃的方法，其中通过使用CO作为还原气体将催化剂与脱氢同时还原。 在用CO还原催化剂时，产生CO 2，其可以与脱氢产生的H 2反应，通过逆向水煤气变换反应形成CO和H 2 O. 催化剂可以包括CuO放热材料在反应器中。 CO还原气体减少CuO形成Cu和CO2，释放热量。 通过还原CuO产生的CO2也可以与脱氢产生的H2反应，通过逆向水煤气变换反应形成CO和H2O。
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公开(公告)号：EP3551599A1
公开(公告)日：2019-10-16
申请号：EP17818629.2
申请日：2017-12-04
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6.发明公开A CATALYTIC REACTION ANALYSIS DUAL REACTOR SYSTEM AND A CALIBRATION METHOD FOR CORRECTING NON-CATALYTIC EFFECTS USING THE DUAL REACTOR SYSTEM 审中-公开双反应器系统催化反应分析双反应器系统及校正非催化效应的标定方法
公开(公告)号：EP3253481A1
公开(公告)日：2017-12-13
申请号：EP16705996.3
申请日：2016-02-01
CPC分类号： B01J8/001 , B01J8/025 , B01J8/0278 , B01J8/0285 , B01J8/067 , B01J19/0013 , B01J19/0046 , B01J19/2445 , B01J2208/00061 , B01J2208/0007 , B01J2208/00407 , B01J2208/00504 , B01J2208/00628 , B01J2208/021 , B01J2219/00157 , B01J2219/00286 , B01J2219/00306 , B01J2219/00391 , B01J2219/00418 , B01J2219/00495 , B01J2219/00585 , B01J2219/00707 , B01J2219/00747 , C10G11/10 , C10G29/00 , G01N31/10
摘要： A catalytic reaction analysis dual reactor system and a method for measuring the catalytic activity of a catalyst by correcting for non-catalytic effects with the catalytic reaction analysis dual reactor system. The dual reactor system contains a first reactor comprising a first catalyst on a first catalyst support, and a second reactor comprising a second catalyst support, wherein the particle size and amount of the first catalyst and the second catalyst support are substantially the same, and the effect of the catalyst is isolated by correcting the result obtained from the first reactor containing the catalyst with the result obtained from the second reactor containing the catalyst support.
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公开(公告)号：EP3240770A1
公开(公告)日：2017-11-08
申请号：EP15823818.8
申请日：2015-12-29
CPC分类号： C07C5/3332 , C07C11/02 , C07C11/09 , C07C2521/04 , C07C2521/06 , C07C2523/26 , Y02P20/146 , Y02P20/584
摘要： A process of catalytically dehydrogenating an alkane to an alkene, using Cr2O3 as a catalyst, where the catalyst is oxidized to CrO3 during the dehydrogenation, and is regenerated by using CO as a reducing gas. In regenerating the catalyst with CO, CO2 is produced, which may be fed to a dehydrogenation reactor with the alkane and reacted with H2 produced by the dehydrogenation, to form CO and H2O by the reverse water-gas shift reaction.
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