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公开(公告)号：EP3233273A1
公开(公告)日：2017-10-25
申请号：EP15870587.1
申请日：2015-11-18
CPC分类号： B01J29/85 , B01J29/90 , B01J35/002 , C01B37/08 , C01B39/54 , C07C1/26 , C07C11/04 , C07C11/06 , C07C2529/85 , Y02P20/52 , Y02P20/584 , C07C11/08
摘要： Disclosed is a catalyst capable of producing an olefin from an alkyl halide, the catalyst comprising a silicoaluminophosphate (SAPO) having a chabazite zeolite structure with the following chemical composition (SixAlyPz)O2, where x, y, and z represent the mole fractions of silicon, aluminum, and phosphorus, respectively, present as tetrahedral oxides, x is 0.01 to 0.30 and the sum of x+y+z is 1, and where the catalyst comprises silicon tetrahedral oxides that are connected with three or less aluminum tetrahedral oxide as shown by 29Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy peak(s) with peak(s) maxima between −93 ppm and −115 ppm.
摘要翻译： 公开了能够由烷基卤生产烯烃的催化剂，所述催化剂包含具有以下化学组成（Si x Al y P z）O 2的菱沸石沸石结构的硅铝磷酸盐（SAPO），其中x，y和z表示 以四面体氧化物形式存在的硅，铝和磷的摩尔分数，x为0.01至0.30，且x + y + z之和为1，并且其中催化剂包含与三个或更少的铝连接的硅四面体氧化物 四面体氧化物，如29 Si魔角旋转（MAS）核磁共振（NMR）光谱峰所示，峰的最大值在-93ppm和-115ppm之间。
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2.发明公开STABLE SILICOALUMINOPHOSPHATE CATALYSTS FOR CONVERSION OF ALKYL HALIDES TO OLEFINS 审中-公开将烷基卤化物转化为烯烃的稳定的硅铝磷酸盐催化剂
公开(公告)号：EP3024806A1
公开(公告)日：2016-06-01
申请号：EP15829730.9
申请日：2015-07-28
CPC分类号： B01J29/85 , B01J7/00 , B01J35/002 , B01J35/023 , B01J35/1061 , B01J2229/37 , C01B39/54 , C07C1/26 , C07C2529/85 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Disclosed is a method for converting an alkyl halide to an olefin. The method includes contacting a silicoaluminophosphate (SAPO) catalyst with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product that includes C2 to C4 olefins. The SAPO catalyst has bimodal acidity designated as weak acid sites and strong acid sites. The weak acid concentration is less than 0.55 mmol/g-cat and the total acid concentration is less than 1.5 mmol/g-cat.
摘要翻译： 公开了一种将卤代烷转化为烯烃的方法。 该方法包括在足以生产包括C 2 -C 4烯烃的烯烃产物的反应条件下使硅铝磷酸盐（SAPO）催化剂与包含烷基卤的进料接触。 SAPO催化剂具有双峰酸度，称为弱酸位和强酸位。 弱酸浓度小于0.55 mmol / g-cat，总酸浓度小于1.5 mmol / g-cat。
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3.发明公开STABLE CATALYST FOR CONVERSION OF ALKYL HALIDE TO OLEFINS 审中-公开维生素KATALYSATOR ZUR UMWANDLUNG VON ALKYLHALID在OLEFINE
公开(公告)号：EP3140036A1
公开(公告)日：2017-03-15
申请号：EP15815523.4
申请日：2015-06-30
发明人： GHOSH, Ashim Kumar , KULKARNI, Neeta , MIER, Mike
CPC分类号： C07C1/30 , B01J29/85 , B01J35/002 , B01J35/1019 , B01J37/28 , B01J2229/186 , C07C1/26 , C07C2529/85 , Y02P20/52 , C07C11/02 , C07C11/04 , C07C11/06
摘要： Disclosed are stable catalysts, and methods for their use, that are capable of producing an olefin from an alkyl halide. The catalysts include a phosphorus-treated silicoalummophosphate (SAPO) having a structure of X/SAPO or X/Z-SAPO, where X includes a non-framework phosphorus and Z is one or more elements from Groups 2A, 3A, IVB, VIB, VIIB, VIII, IB of the Periodic Table, or compounds thereof comprised in the SAPO framework.
摘要翻译： 公开了能够从烷基卤生产烯烃的稳定的催化剂及其使用方法。 催化剂包括具有X / SAPO或X / Z-SAPO结构的磷处理的磷硅酸钠（SAPO），其中X包括非骨架磷，Z是来自2A，3A，IVB，VIB， VIIB，VIII，IB，或包含在SAPO框架中的化合物。
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4.发明公开
公开(公告)号：EP3016739A1
公开(公告)日：2016-05-11
申请号：EP15818645.2
申请日：2015-06-29
发明人： GHOSH, Ashim Kumar , MIER, Mike
CPC分类号： B01J29/40 , B01J29/90 , C01B39/38 , C07C1/26 , C07C2529/40 , C08F10/00 , Y02P20/52 , Y02P20/584 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Disclosed is a method for converting an alkyl halide to an olefin. The method can include contacting a zeolite catalyst comprising HZSM-5 having a silica to alumina (SAR) ratio of at least 30 with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product comprising C2 to C4 olefins, wherein the selectivity of the C2 to C4 olefins is at least 85% at 20% alkyl halide conversion.
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