摘要:
Disclosed are fluorobenzene derivatives, which are important intermediates for producing herbicidal oxazolidinedione derivatives, and methods of producing them. The fluorobenzene derivatives include compounds of formula (11):
where X is a halogen atom, R³ is a nitro, amino or isocyanato group or R¹OCONH, and R¹ is an alkyl or phenyl group. Via the intermediates of the invention, oxazolidinedione derivatives can be produced with high yield.
摘要:
An oxazolidinedione compound represented by the formula (I): wherein R 1 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, a cycloalkyl group having 3 to 5 carbon atoms, an alkenyl group having 3 to 5 carbon atoms, an alkynyl group having 3 to 5 carbon atoms or an alkoxycarbonyl group having 1 or 2 carbon atoms in the alkyl moiety thereof, R 2 represents an alkyl group having 3 to 5 carbon atoms or a cycloalkyl group having 3 to 5 carbon atoms, and X represents a chlorine atom or a fluorine atom; a process for preparing the same; and a herbicidal composition comprising the oxazolidinedione compound as an active component are disclosed. The above oxazolidinedione compounds exhibit a high selectivity for useful crop plants and a strong herbicidal activity with respect to various noxious weeds.
摘要:
A process is disclosed for preparing 2-chloro-4-fluorophenol which comprises chlorinating 4-fluorophenol with a chlorinating agent in the presence of water. The process according to the present invention has advantages in that the chlorination can be carried out using inexpensive reagents without requiring the use of particular apparatus and under mild conditions, and the desired product can be obtained in good yields and with high selectivity. 2-Chloro-4-fluorophenol obtained in the present invention is useful as a starting material for producing various pharmaceutical agents and agricultural agents.
摘要:
New L-phenylalanine dehydrogenases produced by a microorganism belonging to the genus Bacillus , new microorganisms capable of L-phenylalanine dehydrogenase and belonging to the genus Bacillus , a process for production of L-phenylalanine dehydrogenase using the microorganisms, and processes for production of L-amino acids using the enzymes or the microorganisms.
摘要:
New L-phenylalanine dehydrogenases produced by a microorganism belonging to the genus Sporosarcina or Bacillus, new microorganisms capable of L-phenylalanine dehydrogenase and belonging to the genus Sporosarcina or Bacillus, a process for production of L-phenylalanine dehydrogenase using the microorganisms, and processes for production of L-amino acids using the enzymes or the microorganisms.