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公开(公告)号：EP3023401A1
公开(公告)日：2016-05-25
申请号：EP14194053.6
申请日：2014-11-20
IPC分类号： C07C1/22 , C07C15/085 , B01J23/72
CPC分类号： C07C1/22 , C07C2521/08 , C07C2523/72 , C07C2523/78 , C07D301/19 , Y02P20/52 , C07C15/085
摘要： A method for the hydrogenolysis of a phenyl alcohol to eliminate a hydroxyl group therefrom, the method comprising contacting a feed comprising the phenyl alcohol and a hydrogenating agent with a heterogeneous catalyst comprising copper and silica at a reaction temperature of less than 140 °C, wherein the catalyst comprises copper (calculated as CuO) in an amount in the range of from 71 to 90 % by weight of the catalyst. A process for the preparation of an alkylene oxide is also disclosed.
摘要翻译： 一种苯酚氢解以从其中除去羟基的方法，所述方法包括使包含苯基醇和氢化剂的进料与包含铜和二氧化硅的非均相催化剂在小于140℃的反应温度下接触，其中 该催化剂包含占催化剂重量的71-90％的铜（以CuO计算）。 还公开了制备烯化氧的方法。
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2.发明公开Improvements relating to hydrogenolysis of phenyl alcohols 审中-公开氢氧化铍苯基醇（Verbesserungen bei der Hydrogenolyse von Phenylalkoholen）
公开(公告)号：EP3023402A1
公开(公告)日：2016-05-25
申请号：EP14194055.1
申请日：2014-11-20
IPC分类号： C07C1/22 , C07C15/085 , B01J23/72
CPC分类号： C07C1/22 , C07C29/132 , C07C2521/06 , C07C2523/72 , C07D301/19 , Y02P20/52 , C07C15/085 , C07C33/20
摘要： A method for the hydrogenolysis of a phenyl alcohol to eliminate a hydroxyl group therefrom, the method comprising contacting a feed comprising the phenyl alcohol and a hydrogenating agent with a heterogeneous catalyst comprising copper and zirconium at a reaction temperature of less than 135 °C and wherein the amount of copper (calculated as CuO) is in the range of from 10 to 80 % by weight of the catalyst and the amount of zirconium (calculated as ZrO 2 ) is in the range of from 20 to 90 % by weight of the catalyst. A process for the preparation of an alkylene oxide is also disclosed.
摘要翻译： 一种苯乙醇氢解以除去羟基的方法，该方法包括在小于135℃的反应温度下使包含苯醇和氢化剂的进料与包含铜和锆的多相催化剂接触，其中 铜的量（以CuO计算）在催化剂的10〜80重量％的范围内，锆的量（按ZrO 2计算）在催化剂的20〜90重量％的范围内 。 还公开了一种制备环氧烷烃的方法。
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公开(公告)号：EP1692086A1
公开(公告)日：2006-08-23
申请号：EP04804660.1
申请日：2004-12-02
IPC分类号： C07C1/24
摘要： A process for preparing styrene by contacting a gaseous feed which contains 1-phenylethanol and at least 0.1 %wt of phenol and/or ethylphenol with a heterogeneous dehydration catalyst in the presence of at least 0.40 %wt of benzylalcohol and at a molar ratio of benzylalcohol to total amount of phenol and ethylphenol of at least 0.8.
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公开(公告)号：EP2279163B1
公开(公告)日：2014-05-21
申请号：EP09742069.9
申请日：2009-05-05
CPC分类号： C07C68/065 , C07C69/96
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公开(公告)号：EP2279163A1
公开(公告)日：2011-02-02
申请号：EP09742069.9
申请日：2009-05-05
CPC分类号： C07C68/065 , C07C69/96
摘要： The invention relates to a process for the preparation of an alkanediol and a dialkyl carbonate comprising: (a) reacting an alkylene carbonate and an alkanol at a temperature of from 10 to 200 °C, at a pressure of from 5x10
4 to 5x10
6 N/m
2 and in the absence of a transesterification catalyst, to obtain a mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate; (b) contacting the mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate with a transesterification catalyst at a temperature of from 10 to 200 °C and at a pressure of from 5xl0
4 to 5xl0
6 N/m
2 , to obtain a mixture comprising the alkanediol and the dialkyl carbonate; and (c) recovering the alkanediol and the dialkyl carbonate from the mixture comprising the alkanediol and the dialkyl carbonate.
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