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    ALKYLENE EPOXIDATION WITH MESOPOROUS CATALYSTS
    5.
    发明公开
    ALKYLENE EPOXIDATION WITH MESOPOROUS CATALYSTS 审中-公开
    ALKYLENEPOXIDIERUNG与介孔材料

    公开(公告)号：EP2866931A2

    公开(公告)日：2015-05-06

    申请号：EP13810441.9

    申请日：2013-06-27

    申请人： University Of Kansas

    发明人： SUBRAMANIAM, Bala ,  RAMANATHAN, Anand ,  GHANTA, Madhav ,  YAN,Wenjuan

    IPC分类号： B01J23/30

    CPC分类号： C07D301/19 ,  C07D301/12

    摘要： A process for epoxidizing an olefin comprising contacting an olefin with an oxidant in the presence of an insoluble oxidation catalyst in a solvent system comprising an organic water-miscible solvent to form an alkylene oxide. The insoluble oxidation catalyst comprises a metal, preferably selected from the group consisting of tungsten, cerium, and niobium. The metal is directly incorporated within a solid mesoporous silicate support, such as one selected from the group consisting of KIT-5, KIT-6, and TUD-1.

    PROCESS FOR PREPARING DIVINYLARENE DIOXIDES
    6.
    发明公开
    PROCESS FOR PREPARING DIVINYLARENE DIOXIDES 有权
    制备二烯丙基二氧化物的方法

    公开(公告)号：EP2516409A1

    公开(公告)日：2012-10-31

    申请号：EP10798907.1

    申请日：2010-12-17

    申请人： Dow Global Technologies LLC

    发明人： RIPPLINGER, Eric, B. ,  JEAN, David ,  BUROW, David, L. ,  PHAM, Khiet, T. ,  GULYAS, Gyongyi ,  HOOK, Bruce, D.

    IPC分类号： C07D301/19 ,  C07D301/12

    CPC分类号： C08G59/22 ,  C07D301/12 ,  C07D301/19 ,  C08G59/027

    摘要： A process for preparing a divinylarene dioxide including reacting (a) at least one divinylarene; (b) at least one peroxycarboximidic acid; (c) at least one solvent; and (d) at least one basic compound, under conditions to form a reaction mixture containing a divinylarene dioxide product; and then separating the divinylarene dioxide product from the other reaction mixture components to obtain a purified divinylarene dioxide product.

    摘要翻译： 一种制备二乙烯基芳烃二氧化物的方法，包括使（a）至少一种二乙烯基芳烃反应; （b）至少一种过氧羧酰亚胺酸; （c）至少一种溶剂; 和（d）至少一种碱性化合物，在形成含有二乙烯基芳烃二氧化物产物的反应混合物的条件下进行; 然后将二乙烯基芳烃二氧化物产物与其他反应混合物组分分离以获得纯化的二乙烯基芳烃二氧化物产物。

    METHOD FOR PRODUCING PROPYLENE OXIDE
    9.
    发明公开
    METHOD FOR PRODUCING PROPYLENE OXIDE 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON PROPYLENOXID

    公开(公告)号：EP1837334A1

    公开(公告)日：2007-09-26

    申请号：EP06700853.2

    申请日：2006-01-12

    申请人： Sumitomo Chemical Company, Limited

    发明人： TSUJI, Junpei ,  ITOU, Yoshiaki ,  SHINOHARA, Koji

    IPC分类号： C07D301/14 ,  C07D301/32 ,  C07D303/04 ,  C07B61/00

    CPC分类号： C07D301/19

    摘要： A method for continuously producing propylene oxide, which comprises supplying an organic peroxide and propylene to an epoxidation reactor in which a solid catalyst for epoxidation is packed, thereby subjecting them to an epoxidation reaction, the method having a propylene pre-treatment step described below:
    propylene pre-treatment step; a step of treating at least a part of propylene supplied to the epoxidation reactor, which comprises removing an oxygen-containing organic compound contained in propylene.

    摘要翻译： 一种连续生产环氧丙烷的方法，其包括将有机过氧化物和丙烯供给到其中填充用于环氧化的固体催化剂的环氧化反应器，由此进行环氧化反应，所述方法具有以下丙烯预处理步骤： 丙烯预处理步骤; 处理提供给环氧化反应器的丙烯的至少一部分的步骤，其包括除去丙烯中所含的含氧有机化合物。

    PROCESS
    10.
    发明公开
    PROCESS 有权
    程序

    公开(公告)号：EP1786796A1

    公开(公告)日：2007-05-23

    申请号：EP05784523.2

    申请日：2005-09-02

    申请人： Shell Internationale Research Maatschappij B.V.

    发明人： NISBET, Timothy Michael ,  SNODGRASS, Kevin Michael

    IPC分类号： C07D301/32 ,  C07D301/14

    CPC分类号： C07D301/19 ,  C07C1/24 ,  C07C29/132 ,  C07C15/46 ,  C07C33/22

    摘要： Process of manufacturing propylene oxide and styrene which process comprises: (i) contacting propene with a mixture of ethylbenzene hydroperoxide and ethylbenzene in the presence of catalyst to obtain propylene oxide and 1-phenylethanol, (ii) separating propylene oxide from the reaction mixture obtained in step (i) , (iii) subjecting the mixture obtained in step (ii) to distillation to obtain a top stream containing ethylbenzene and a bottom stream containing 1-phenylethanol, (iv) subjecting the bottom stream containing 1-phenylethanol obtained in step (iii) to a further distillation to obtain a top stream containing purified 1-phenylethanol and a bottom stream containing heavy by¬ products, (v) contacting the top stream containing 1- phenylethanol obtained in step (iv) with a dehydration catalyst to obtain styrene and water, (vi) subjecting the reaction mixture obtained in step (v) to distillation to obtain a top stream containing styrene and water and a bottom stream containing unconverted 1-phenylethanol, 2-phenylethanol, methylphenylketone and by-products, (vii) subjecting the bottom stream containing unconverted 1-phenylethanol, 2-phenylethanol, methylphenylketone and further by-products obtained in step (vi) to distillation to obtain a top stream containing methylphenylketone and a bottom stream containing 2-phenylethanol and heavy by-products, and (viii) recycling to step (iv) the bottom stream containing 2-phenylethanol and heavy by-products obtained in step (vii) , wherein the bottom stream obtained in step (vii) is introduced into the distillation of step (iv) below the point at which the bottom stream containing 1-phenylethanol obtained in step (iii) is introduced.