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1.发明公开
公开(公告)号：EP0403252A3
公开(公告)日：1991-08-28
申请号：EP90306441.8
申请日：1990-06-13
IPC分类号： C07D303/32 , C07D303/48 , C07D407/10 , C07D409/10 , C07D333/22 , C07D307/46 , C07C49/794 , C07C49/80 , C07C49/84
CPC分类号： C07D407/10 , C07C45/74 , C07C49/796 , C07C49/798 , C07C49/813 , C07C49/84 , C07C201/12 , C07D303/32 , C07D303/48 , C07D409/10 , C07C205/45
摘要： A process for preparing epoxy ketones of the formula III
by reacting unsaturated ketones of the formula II
with a poly-(amino acid), an oxidant and a base in a mixture of water and a non-aromatic non-chlorinated hydrocarbon solvent.
Compounds of the formula II can be further treated with a peracid to yield epoxy esters of the formula IV.
Certain compounds of the formulae II, III or IV are new.-
2.发明公开Process for preparation of epoxy esters and intermediates prepared thereby 失效Verfahren zur Herstellung von Epoxyestern und dadurch erhaltene Zwischenprodukte。
公开(公告)号：EP0403252A2
公开(公告)日：1990-12-19
申请号：EP90306441.8
申请日：1990-06-13
IPC分类号： C07D303/32 , C07D303/48 , C07D407/10 , C07D409/10 , C07D333/22 , C07D307/46 , C07C49/794 , C07C49/80 , C07C49/84
CPC分类号： C07D407/10 , C07C45/74 , C07C49/796 , C07C49/798 , C07C49/813 , C07C49/84 , C07C201/12 , C07D303/32 , C07D303/48 , C07D409/10 , C07C205/45
摘要： A process for preparing epoxy ketones of the formula III
by reacting unsaturated ketones of the formula II
with a poly-(amino acid), an oxidant and a base in a mixture of water and a non-aromatic non-chlorinated hydrocarbon solvent.
Compounds of the formula II can be further treated with a peracid to yield epoxy esters of the formula IV.
Certain compounds of the formulae II, III or IV are new.摘要翻译： 通过使式II
的不饱和酮与聚（氨基酸），氧化剂和碱在水和非芳族非离子表面活性剂的混合物中反应制备式III 的环氧酮的方法， 氯化烃溶剂。 可以用过酸进一步处理式II的化合物，得到式IV的环氧酯。 某些化合物Ⅱ，Ⅲ或Ⅳ是新的。 Ë
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