摘要:
A process for producing cumene which comprises subjecting cumyl alcohol to hydrogenolysis or dehydration and then to hydrogenation, characterized in that a palladium catalyst is used as a catalyst for the hydrogenolysis or hydrogenation and that hydrogen having a carbon monoxide concentration of 0.1 to 10 vol.% is used.
摘要:
A method for producing α-methylstyrene wherein α-methylstyrene is formed from cumyl alcohol through dehydration in the presence of an active alumina, characterized in that a raw reaction material containing cumyl alcohol contains an organic acid in a concentration of 10 to 1000 wt ppm.
摘要:
A process for producing propylene oxide, characterized by reacting propylene with hydrogen peroxide in the presence of a crystalline titanosilicate catalyst having a pore structure not smaller than the 12-oxygen-membered ring using as a medium an organic solvent capable of being separated from water to obtain a reaction mixture containing propylene oxide, and separating the reaction mixture into two liquids, i.e., an aqueous layer and an oil layer containing the organic solvent, to cause the propylene oxide to separate from the water and come into the oil layer.
摘要:
A process for the preparation of propylene oxide which comprises the following steps, wherein alcohols having two or three carbon atoms, cyclohexanol and/or isopropylcyclohexane formed as by-products are removed from the system at one or more stages either during the steps or between the steps: oxidation step of preparing cumene hydroperoxide by oxidizing cumene, epoxidation step of reacting the cumene hydroperoxide obtained in the oxidation step with propylene to form propylene oxide and cumyl alcohol, and hydrogenolysis step of preparing cumene by hydrogenolysis of the cumyl alcohol obtained in the epoxidation step and recycling the cumene to the oxidation step as the material.
摘要:
A method for producing propylene oxide, characterized in that it comprises reacting propylene with hydrogen peroxide in the presence of an organic solvent and a crystalline titanosilicate catalyst that has an MWW structure containing Ti having been incorporated during crystallization.
摘要:
A method for producing propylene oxide, characterized in that it comprises reacting a peroxide and propylene in the presence of a titanosilicate catalyst which has the X-ray diffraction pattern described below and is represented by the formula: xTiO2·(1-x)SiO2 [wherein x represents a value of 0.0001 to 0.1], X-ray diffraction pattern (interplanar spacing of lattice d/Å) 13.2 ± 0.6 12.3 ± 0.3 11.0 ± 0.3 9.0 ± 0.3 6.8 ± 0.3 3.9 ± 0.2 3.5 ± 0.1 3.4 ± 0.1
摘要:
A process for producing cumene, which comprises supplying cumyl alcohol and hydrogen to a dehydration catalyst to obtain a mixture containing alpha -methyl styrene and water produced and hydrogen, and supplying the mixture to a hydrogenation catalyst.
摘要:
A method for the purification of propylene oxide, characterized by distilling contaminated propylene oxide in the presence of a hydrocarbon having 5 or fewer carbon atoms. According to this method, impurities (particularly, oxygenic impurities) present in a solution of propylene oxide to be purified can be removed extremely efficiently.