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    Process for production of sec-butylbenzene
    3.
    发明公开
    Process for production of sec-butylbenzene 失效
    Verfahren zur Herstellung von sec.-Butylbenzol。

    公开(公告)号：EP0395360A1

    公开(公告)日：1990-10-31

    申请号：EP90304403.0

    申请日：1990-04-24

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Tamura, Mitsuhisa ,  Yamauchi, Kazuhiro ,  Higashio, Yasuhiko ,  Takahashi, Kazuteru

    IPC分类号： C07C15/02 ,  C07C2/68

    CPC分类号： C07C2/70 ,  C07C2527/11 ,  C07C2527/126 ,  C07C2531/02 ,  C07C15/02

    摘要： Benzene and n -butene (1-, cis - and/or trans -) are reacted at a temperature of 20 to 70°C in the presence of a complex catalyst which is a homogeneous liquid of aluminum chloride, hydrogen chloride and an aromatic hydro­carbon, in amount of 0.3 to 5 wt% of the AlCl₃ to the benzene (prepared by stirring for ⅓ - 3 hours); the reaction mixture is separated into fractions containing mainly the desired product sec -butylbenzene with not more than 1% of by-product isobutylbenzene; heavy materials; and (which are recycled) benzene, and dibutyl- and tributylbenzenes.
    The catalyst can be separated, recovered and recycled.
    The reaction can be continuous or batchwise.
    The product sec -butylbenzene can be utilised for production of phenol.

    摘要翻译： 苯和正丁烯（1-，顺 - 和/或反 - ）在20至70℃的温度下在络合催化剂存在下反应，该络合催化剂是氯化铝，氯化氢和芳族烃的均匀液体 ，相对于苯的AlCl 3为0.3〜5重量％（搅拌1/3〜3小时）。 将反应混合物分离成主要含有所需产物仲丁基苯和不超过1％副产物异丁苯的级分; 重材料; 和（其是再循环的）苯，以及二丁基 - 和三丁基苯。 催化剂可以分离，回收和再循环。 反应可以是连续的或分批的。 产物仲丁基苯可用于生产苯酚。

    A method for producing compounds having a double bond at the terminal
    4.
    发明公开
    A method for producing compounds having a double bond at the terminal 失效
    Verfahren zur Herstellung von Verbindungen mitendständigerDoppelbindung。

    公开(公告)号：EP0150832A2

    公开(公告)日：1985-08-07

    申请号：EP85100784.9

    申请日：1985-01-25

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Araki, Masashi ,  Takahashi, Kazuteru ,  Hibi, Takuo

    IPC分类号： C07C1/24 ,  C07C11/02 ,  C07C13/19

    CPC分类号： C07C1/24 ,  C07C2521/06

    摘要： A method for producing a compound having a double bond at the terminal which comprises dehydrating a compound represented by the formula (I),
    wherein R is a C 3 - C 20 hydrocarbon group which may have one or more double bonds, by contacting with zirconium oxide as a catalyst. According to the method described above, terminal olefins which are useful as a material for heat-resistant polymers, a comonomer for polyolefins, a raw material for detergents, etc. are provided at low costs and with safety.

    摘要翻译： 一种制备末端具有双键的化合物的方法，该方法包括使由式（I）表示的化合物R 1 - （CH 3）（I）脱水，其中R是可以具有一个或多个 通过与氧化锆作为催化剂接触来进行双键。 根据上述方法，以低成本和安全的方式提供可用作耐热聚合物材料的末端烯烃，聚烯烃共聚单体，洗涤剂原料等。

    Catalytic process for production of sec-butylbenzene
    9.
    发明公开
    Catalytic process for production of sec-butylbenzene 失效
    Katalytisches Verfahren zur Herstellung von sec-Butylbenzol。

    公开(公告)号：EP0475687A1

    公开(公告)日：1992-03-18

    申请号：EP91308151.9

    申请日：1991-09-05

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Takahashi, Kazuteru ,  Higashio, Yasuhiko

    IPC分类号： C07C15/02 ,  C07C2/68

    CPC分类号： C07C2/68 ,  C07C2527/126 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/02

    摘要： Benzene (1 mole) and n -butene (0.2 to 1.2 mole) are mixed together with a liquid catalyst comprising 0.5 mole HCl and 2 moles of an aromatic hydrocarbon having 1 mole of AlCl₃ bonded thereto, and reacted at a temperature of 80-150°C for a time T of 0.01 - 0.7 hour, and at a catalyst concentration of not more than 0.9 wt%, usually 0.01 - 0.9 wt%,and the concentration C satisfying the formula: 40 > [C x T x 2 (K-20)/10 ]>20
    The reaction can be batchwise or continuous. The sec -butylbenzene product is separated and recovered; by-product di- and tri- sec -butylbenzene may be transalkylated or recycled; unreacted benzene may be recycled; the spent catalyst can be recovered and recycled.
    By-product isobutylbenzene is kept to no more than 1 wt%.
    The sec -butylbenzene is useful in the production of phenol, e.g. by oxidation.

    摘要翻译： 将苯（1摩尔）和正丁烯（0.2-1.2摩尔）与包含0.5摩尔HCl和2摩尔与其结合的1摩尔AlCl 3的芳族烃的液体催化剂混合在一起，并在80-150℃的温度下反应 ℃，时间T为0.01〜0.7小时，催化剂浓度为0.9重量％以下，通常为0.01〜0.9重量％，浓度C满足下式：反应可以是间歇或连续的 。 分离和回收仲丁基苯产物; 副产物二 - 和三仲丁基苯可以是烷基转移或再循环; 未反应的苯可以再循环; 废催化剂可以回收和再循环。 副产物异丁苯保持不超过1重量％。 仲丁基苯可用于生产苯酚，例如 通过氧化。