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公开(公告)号：EP0144477B1
公开(公告)日：1987-03-18
申请号：EP83307576.5
申请日：1983-12-13
CPC分类号： C07C69/618 , C07C67/08 , C07C69/54 , C07C69/78
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2.发明公开Piperidine derivatives, their production, and polymers photostabilized thereby 失效Piperidinderivate，ihre Herstellung und photostabilisierte Polymere。
公开(公告)号：EP0141502A2
公开(公告)日：1985-05-15
申请号：EP84306002.1
申请日：1984-08-31
IPC分类号： C07D491/22 , C08K5/34
CPC分类号： C07D491/22 , C08K5/3435
摘要： The invention provides a piperidine derivative represented by the formula (I)
wherein R 2 and R 3 represent hydrogen atoms or taken tooether form
and each R is selected from a hydrogen atom and C 1 -C 3 alkyl groups. These compounds are effective photostabilizers for high polymers even when used in combination with sulfur- containing antioxidants.摘要翻译： 本发明提供由式（I）...
表示的哌啶衍生物，其中R 2和R 3表示氢原子或一起形成...，且每个R选自氢原子和 C1-C3烷基。 这些化合物即使与含硫抗氧化剂组合使用也是高聚合物的有效光稳定剂。 -
3.发明公开
公开(公告)号：EP0144477A1
公开(公告)日：1985-06-19
申请号：EP83307576.5
申请日：1983-12-13
CPC分类号： C07C69/618 , C07C67/08 , C07C69/54 , C07C69/78
摘要： A method for producing a bisphenol derivative represented by the formula (I),
wherein R represents an alkyl group having 1 to 3 carbon atoms, an alkenyl group having 2 to 4 carbon atoms, or a phenyl or 2-phenylethenyl group, and each R' is selected from alkyl groups of 1 to 4 carbon atoms, characterised in that carboxylic acid represented by the formula (II),
wherein R is as defined above, is reacted with bisphenol represented by the formula (III),
wherein each R' is as defined above, using halogenating agent in the presence of dehydrohalogenating agent. By the present invention, bisphenol derivatives represented by the formula (I) can be produced commercially in one step and in good yields from carboxylic acids without handling a strongly irritative acid halide.摘要翻译： 一种由式（I）表示的双酚衍生物的方法，其中R表示碳原子数1〜3的烷基，碳原子数2〜4的烯基或苯基或2-苯基乙烯基， 并且每个R min选自1至4个碳原子的烷基，其特征在于由式（II）表示的羧酸R 1〜OH（II）其中R如上所定义，与双酚代表的 式（III），
其中每个R min'如上定义，在脱卤化氢剂的存在下使用卤化剂。 通过本发明，由式（I）表示的双酚衍生物可以在一步中以商品形式从羧酸得到，而不用强烈刺激性的酰卤处理。 -
4.发明公开
公开(公告)号：EP0078142A2
公开(公告)日：1983-05-04
申请号：EP82305548.8
申请日：1982-10-19
IPC分类号： C07D487/04 , C08K5/34
CPC分类号： C07D487/04 , C08K5/3445
摘要： An acetylene carbamide derivative is of the general formula (I):
wherein each A is
wherein R 1 is hydrogen or C 1-4 alkyl, and X is A or hydrogen.
Five tetrakis and five tris specific compounds are named. The derivatives can be produced from an acetylene carbamide
by reaction with a p-hydroxybenzyl alcohol, a dialkyldithiocarbamate, or formaldehyde and a phenol.
The derivatives (1) are useful in an amount of 0.001 to 10% by weight as stabilizers against deterioration by light or oxygen of organic substances such as polymers, rubbers and petroleum products. They may be used together with a sulfur or phosphorus-containing antioxidant or a hindered amine light stabilizer.-
5.发明授权Piperidine derivatives, their production, and polymers photostabilized thereby 失效哌啶衍生物，它们的生产和聚合物可以使用它们
公开(公告)号：EP0141502B1
公开(公告)日：1989-01-25
申请号：EP84306002.1
申请日：1984-08-31
IPC分类号： C07D491/22 , C08K5/34
CPC分类号： C07D491/22 , C08K5/3435
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6.发明授权
公开(公告)号：EP0078142B1
公开(公告)日：1986-03-05
申请号：EP82305548.8
申请日：1982-10-19
IPC分类号： C07D487/04 , C08K5/34
CPC分类号： C07D487/04 , C08K5/3445
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7.发明公开Piperidine derivatives, their production, and polymers photostabilized thereby 失效哌啶衍生物，它们的生产和聚合物可以使用它
公开(公告)号：EP0141502A3
公开(公告)日：1986-02-26
申请号：EP84306002
申请日：1984-08-31
IPC分类号： C07D491/22 , C08K05/34 , C07D319/00 , C07D221/00
CPC分类号： C07D491/22 , C08K5/3435
摘要： The invention provides a piperidine derivative represented by the formula (I)
wherein R 2 and R 3 represent hydrogen atoms or taken tooether form
and each R is selected from a hydrogen atom and C 1 -C 3 alkyl groups. These compounds are effective photostabilizers for high polymers even when used in combination with sulfur- containing antioxidants.-
8.发明公开
公开(公告)号：EP0078142A3
公开(公告)日：1983-07-06
申请号：EP82305548
申请日：1982-10-19
IPC分类号： C07D487/04 , C08K05/34 , C07D235/00
CPC分类号： C07D487/04 , C08K5/3445
摘要： An acetylene carbamide derivative is of the general formula (I):
wherein each A is
wherein R 1 is hydrogen or C 1-4 alkyl, and X is A or hydrogen. Five tetrakis and five tris specific compounds are named. The derivatives can be produced from an acetylene carbamide
by reaction with a p-hydroxybenzyl alcohol, a dialkyldithiocarbamate, or formaldehyde and a phenol. The derivatives (1) are useful in an amount of 0.001 to 10% by weight as stabilizers against deterioration by light or oxygen of organic substances such as polymers, rubbers and petroleum products. They may be used together with a sulfur or phosphorus-containing antioxidant or a hindered amine light stabilizer.
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