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1.发明公开
公开(公告)号：EP0659847A1
公开(公告)日：1995-06-28
申请号：EP94120598.1
申请日：1994-12-23
发明人： Tsuboi, Makoto , Yuki, Shuhei , Kakimizu, Akiko , Arai, Kenji , Mizutani, Masato
CPC分类号： A01N43/80 , C09D5/1625
摘要： There are disclosed a controlling agent and an antifouling composition against harmful aquatic organisms, which include a particular N-phenylisothiazolone derivative of the formula:
wherein X¹ and X² are the same or different and are independently hydrogen, chlorine or bromine; and R is haloalkoxy. Also disclosed is a method for preventing or inhibiting the adhesion of harmful aquatic organisms to water-exposed articles, which includes applying the antifouling composition to the water-exposed articles.摘要翻译： 有圆盘游离缺失的控制剂和防污组合物对有害水生物，其中包括下式的一个特别是N- phenylisothiazolone衍生物：
worin X <1>和X <2>是相同的或不同的并且是unabhängig氢， 氯或溴; 且R为卤代烷氧基。 所以圆盘游离缺失是用于防止或抑制有害水生生物体暴露于水的物品，其包括将所述防垢组合物的暴露于水的物品的密合性的方法。 -
2.发明公开
公开(公告)号：EP0644243A2
公开(公告)日：1995-03-22
申请号：EP94114600.3
申请日：1994-09-16
IPC分类号： C09D5/14
CPC分类号： C09D5/1625 , A01N43/80 , C08K5/47
摘要： There are disclosed a controlling agent and an antifouling composition against harmful aquatic organisms, which include a particular N-phenylbenzoisothiazolone derivative of the formula:
wherein R's are the same or different and are independently halogen, alkyl or alkoxy; n is an integer of 0 to 5; X's are the same or different and are independently halogen, nitro, alkyl or alkoxy; and m is an integer of 0 to 4; with the proviso that when the R's are all alkyl or all alkoxy, n is an integer of 1 to 3, and when all of the R's are different, n is an integer of 2 or 3. Also disclosed is a method for preventing or inhibiting the adhesion of harmful aquatic organisms to water-exposed articles, which includes applying the antifouling composition to the water-exposed articles.摘要翻译： 有盘的游离缺失对有害水生物，其中包括下式的一个特别是N- phenylbenzoisothiazolone衍生物的控制剂和防污组合物：worin的r是相同的或不同的，并且是卤素unabhängig
，烷基或烷氧基; n为0〜5的整数; X可相同或不同，是卤素unabhängig，硝基，烷基或烷氧基; 且m是0〜4的整数; 其条件没有当将R的都是烷基或全部烷氧基，n为1〜3的整数，并且当所有的R的是不同的，n是或的整数2 3。因此游离缺失盘是用于防止的方法或抑制 的有害水生生物体粘附于水中物体，其包括将所述防垢组合物的暴露于水的物品。 -
3.发明授权
公开(公告)号：EP0659847B1
公开(公告)日：1998-03-18
申请号：EP94120598.1
申请日：1994-12-23
发明人： Tsuboi, Makoto , Yuki, Shuhei , Kakimizu, Akiko , Arai, Kenji , Mizutani, Masato
CPC分类号： A01N43/80 , C09D5/1625
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4.发明公开
公开(公告)号：EP0644243A3
公开(公告)日：1996-01-10
申请号：EP94114600.3
申请日：1994-09-16
IPC分类号： C09D5/14
CPC分类号： C09D5/1625 , A01N43/80 , C08K5/47
摘要： There are disclosed a controlling agent and an antifouling composition against harmful aquatic organisms, which include a particular N-phenylbenzoisothiazolone derivative of the formula:
wherein R's are the same or different and are independently halogen, alkyl or alkoxy; n is an integer of 0 to 5; X's are the same or different and are independently halogen, nitro, alkyl or alkoxy; and m is an integer of 0 to 4; with the proviso that when the R's are all alkyl or all alkoxy, n is an integer of 1 to 3, and when all of the R's are different, n is an integer of 2 or 3. Also disclosed is a method for preventing or inhibiting the adhesion of harmful aquatic organisms to water-exposed articles, which includes applying the antifouling composition to the water-exposed articles.-
5.发明授权
公开(公告)号：EP0644243B1
公开(公告)日：1999-01-27
申请号：EP94114600.3
申请日：1994-09-16
IPC分类号： C09D5/14
CPC分类号： C09D5/1625 , A01N43/80 , C08K5/47
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6.发明公开
公开(公告)号：EP1342756A1
公开(公告)日：2003-09-10
申请号：EP03251373.1
申请日：2003-03-06
发明人： Oya, Masaaki, , Nakamura, Naoya , Tsuboi, Makoto
IPC分类号： C09D5/16
CPC分类号： C09D5/1656 , C08K5/09 , C09D5/1668 , C09D143/00
摘要： An antifouling coating composition comprising:
(A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester,
(B) a carboxylic acid,
(C) a bivalent or trivalent metal compound, and
(D) a dehydrating agent.摘要翻译： 一种防污涂料组合物，包括：（A）一种甲硅烷基酯共聚物包含选自聚合性不饱和羧酸硅烷基酯的结构单元，（B）羧酸，（C）的二价或三价金属化合物，和（D）一种脱水剂 ，
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7.发明授权(Poly)oxyalkylene block silyl ester copolymer, antifouling coating composition, antifouling coating formed from antifouling coating composition, antifouling method using antifouling coating composition and hull or underwater structure covered with antifouling coating 有权（聚）oxyalkylenesilylester嵌段共聚物，防污涂料组合物，防污涂料下涂有防污涂料的水制成防污涂料组合物，使用的防污涂料组合物的防污方法，以及包络线或结构的
公开(公告)号：EP1201700B1
公开(公告)日：2003-05-14
申请号：EP01308986.7
申请日：2001-10-23
IPC分类号： C08G81/02 , C08G65/336 , C09D153/00 , C09D171/02 , C08L71/02 , C09D5/16
CPC分类号： C08L71/02 , C08F293/005 , C08G65/336 , C08G81/025 , C08L53/00 , C09D5/1668 , C09D153/00 , Y10S525/926 , Y10T428/31663 , C08L2666/02 , C08L2666/04
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公开(公告)号：EP1724310B1
公开(公告)日：2018-10-31
申请号：EP06017540.3
申请日：2003-03-06
发明人： Oya, Masaaki , Nakamura, Naoya , Tsuboi, Makoto
IPC分类号： C09D5/16 , C09D143/00 , C08K5/09
CPC分类号： C09D5/1656 , C08K5/09 , C09D5/1668 , C09D143/00
摘要： An antifouling coating composition comprising: (A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester, (B) a carboxylic acid, (C) a bivalent or trivalent metal compound, and (D) a dehydrating agent.
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9.发明授权
公开(公告)号：EP1342756B2
公开(公告)日：2015-06-24
申请号：EP03251373.1
申请日：2003-03-06
发明人： Oya, Masaaki, , Nakamura, Naoya , Tsuboi, Makoto
IPC分类号： C09D143/00 , C08K5/09 , C09D5/16
CPC分类号： C09D5/1656 , C08K5/09 , C09D5/1668 , C09D143/00
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10.发明公开Silyl (meth)acrylate copolymers, processes for preparing the same, antifouling paint compositions containing the silyl (meth)acrylate copolymers, antifouling coating films formed from the antifouling paint compositions, antifouling methods using the antifouling paint compositions, and hulls or underwater structures coated with the antifouling coating films 有权甲硅烷基的共聚物，（甲基）丙烯酸酯，它们的制备方法，防污含有这些共聚物中，防污油漆组合物的防污涂层薄膜，它们的使用方法油漆组合物，以及涂覆的船体或水下结构
公开(公告)号：EP1016681A2
公开(公告)日：2000-07-05
申请号：EP99310578.2
申请日：1999-12-24
发明人： Tsuboi, Makoto , Yoshikawa, Eiichi , Arimura, Hidetaka , Hamazu, Fumio , Nakamura, Naoya , Hikiji, Yasuto , Oya, Masaaki , Hiyoshi, Satoshi , Kozono, Yukio
CPC分类号： C09D5/1668 , C08F230/08
摘要： A silyl (meth)acrylate copolymer which comprises (a) silyl (meth)acrylate constituent units of formula (I), or (III)
-CH 2 -CR(COOSiR 11 R 12 R 13 ) (III)
wherein R 1 to R 4 and R to R 13 are as defined herein, (b) acrylic unsaturated monomer constituent units of formula (II) or silyl (meth)acrylate constituent units of formula (IV)
-CH 2 -CR(COOSiR 14 R 15 R 16 ) (IV)
wherein R, R 5 , Z and R 14 to R 16 are as defined herein and (c) unsaturated monomer constituent units other than the constituent units (a) and (b), providing that when (a) is a component of formula (I), (b) is a compound of formula (II); when (a) is a compound of formula (III), (b) is a compound of formula (IV); and the total amount of the constituent units (a), (b) and (c) is 100 % by weight;
and which has a weight-average molecular weight, as measured by GPC, of not more than 200,000.摘要翻译： 其包括（a）甲硅烷基（甲基）甲硅烷基（甲基）丙烯酸酯共聚物丙烯酸酯（I），或（III）
-CH2-CR（COOSiR <11> - [R <12> - [R <13>）式的组成单元 worin - [R <1>至R <4>和R至R <13>是如所定义，（b）式的丙烯酸类不饱和单体构成单元（II）或甲硅烷基（甲基）式的丙烯酸酯构成单元（IV） -CH2-CR（COOSiR <14> - [R <15> - [R <16>）worin R，R <5>，Z和R <14>至R <16>是如在和（c）不饱和单体构成单元定义 比的构成单元（a）和（b）提供没有当（a）为式（I）的组分，（b）是下式的化合物的其它（II）; 当（a）为式（III）的化合物，（b）是下式的化合物（IV）; 和的结构单元的总量（a）中，（b）和（c）是按重量计100％; 并且其具有的重均分子量，通过GPC测得的不超过200,000，。
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