摘要:
A method for producing an ammonium tungstate aqueous solution includes the steps of: adding sulfuric acid to a solution containing tungstate ions; bringing the solution having the sulfuric acid added therein, into contact with an anion exchange resin; and bringing the anion exchange resin into contact with an aqueous solution containing ammonium ions.
摘要:
There are provided a cemented carbide high in thermal diffusivity and excellent in wear resistance, and a cutting tool including a base material formed of this cemented carbide. The cemented carbide is a WC based cemented carbide in which a hard phase mainly constituted of WC grains is bound by a binder phase mainly constituted of Co, and is used for a cutting tool. The binder phase is substantially constituted of Co, or Co and Ni. A total content of Co and Ni is not less than 4.5 mass % and not more than 15 mass %. In this cemented carbide, the WC grains have an average diameter of not less than 0.4 µm and not more than 4 µm. Assuming that the average diameter of the WC grain is represented by x (µm), the cemented carbide has a thermal diffusivity X (cm 2 /sec) satisfying X > 0.055x + 0.238. The cemented carbide can further contain one or more elements selected from Cr, Ta, Nb, Zr, and Ti at not less than 0.05 mass % and not more than 5 mass % in total.
摘要:
A joined product according to the present invention is a joined product including a cemented carbide sintered compact serving as a first material (1) to be joined and a cBN sintered compact or a diamond sintered compact serving as a second material (3) to be joined. The first material (1) to be joined and the second material (3) to be joined are joined by a joining material (2) that forms a liquid phase at a temperature exceeding 800°C and lower than 1000°C and that is placed between the first material (1) to be joined and the second material (3) to be joined. The first material (1) to be joined and the second material (3) to be joined are joined by resistance heating and pressing at a pressure of 0.1 to 200 MPa.
摘要:
An issue to be addressed by the present invention lies in providing a heat-resistant tungsten alloy provided for a plastic working tool and satisfying both a physical property such as proof stress and hardness corresponding to a workpiece having a high melting point and practicability more than conventional. The present heat-resistant tungsten alloy has a first phase containing W as a major component, a second phase having a carbonitride of at least one element of Ti, Zr and Hf and containing the carbonitride as a major component when W is removed, and a third phase having a carbide of at least one element of group 5A elements in the periodic table and containing the carbide as a major component when W is removed, the heat-resistant tungsten alloy having a Vickers hardness of 550 Hv or more at a room temperature, a displacement of 1 mm or more when leading to fracture, as determined in a three point bending test at 1200°C, and a 0.2% proof stress of 900 MPa or more, as determined in the three point bending test at 1200°C.
摘要:
Provided is a Mo-Si-B-based alloy for a heat-resistant alloy that satisfies, more than conventional, physical properties such as proof stress and hardness adapted to an increase in the melting point of a welding object. A Mo-Si-B-based alloy powder of this invention is such that the full width at half maximum of (600) of Mo 5 SiB 2 in X-ray diffraction peak data is 0.08 degrees or more and 0.7 degrees or less.
摘要:
Provided is a heat-resistant alloy that satisfies physical properties such as proof stress and hardness adapted to an increase in the melting point of a welding object compared to conventional alloys. A heat-resistant alloy of this invention includes a first phase, as a main component, containing a Mo or W metal phase, a second phase containing a Mo-Si-B-based alloy, and a third phase containing titanium carbonitride, wherein the balance is inevitable compounds and inevitable impurities.
摘要:
A coated hard alloy excellent in wearing resistance, chipping resistance, welding resistance, and coating adhesion. The coated hard alloy has on the surface thereof an inner layer, an intermediate layer, and an outer layer. The inner layer comprises a layer of at least one member selected among the carbides, nitrides, borides, and oxides of elements in Groups IVa, Va, and VIa of the Periodic Table and solid solutions of these. The intermediate layer comprises a layer of at least one member selected among aluminum oxide, zirconium oxide, and solid solutions of these. The outer layer comprises a titanium carbonitride layer having a columnar structure. The coated hard alloy has a section in which the maximum roughness of the surface of the intermediate layer, Amax, and that of the surface of the titanium carbonitride layer having a columnar structure in the outer layer, Bmax, satisfy the relationship 1: (Bmax/Amax)
摘要:
A cemented carbide comprising WC grains (1) and at least one compound (3) which is selected among carbides, nitrides and carbonitrides of Group IVa, Va and VIa elements, and solid solutions of them and is present in at least part of the WC grains. The compound (3) is selected among carbides, nitrides and carbonitrides of Ti, Zr, Hf and W, and solid solutions of them, and the mean particle diameter thereof is less than 0.3 νm.