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1.发明公开
公开(公告)号：EP2975040A1
公开(公告)日：2016-01-20
申请号：EP14765633.4
申请日：2014-03-14
发明人： KOBAYASHI, Osamu , NIIKURA, Naoko , INOUE, Tomoko , MIZUTA, Satoshi , TAKATSUNA, Reiko , HIRAI, Kenji , SHIROUZU, Kentaro , OBATA, Miyoo
IPC分类号： C07D487/04 , A01N43/90 , A01P13/02 , C07D498/04
CPC分类号： C07D498/04 , A01N43/90 , A01N47/06 , C07D487/04
摘要： Provided are a polycyclic pyrazolinone derivative indicated by general formula (1) (in the formula, R 1 , X 1 , X 2 , X 3 , and Y indicate the definitions provided in the Specification) and a herbicide comprising same as effective component thereof.
摘要翻译： 提供通式（1）表示的多环吡唑啉酮衍生物（式中，R 1，X 1，X 2，X 3，Y表示本说明书中提供的定义），和含有与其有效成分相同的除草剂。
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2.发明授权
公开(公告)号：EP1854788B8
公开(公告)日：2012-12-26
申请号：EP06714409.7
申请日：2006-02-23
IPC分类号： C07D231/14
CPC分类号： C07D231/14
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3.发明授权PROCESS FOR THE PREPARATION OF 3-(SUBSTITUTED PHENYL)-5-ALKYLIDENE-1,3-OXAZOLIDINE-2,4-DIONE DERIVATIVES 失效用于制备3-（取代苯基）-5-亚烷基-1,3-恶唑烷-2,4-二酮衍生物
公开(公告)号：EP0812834B1
公开(公告)日：2001-06-20
申请号：EP96903234.1
申请日：1996-02-26
发明人： HIRAI, Kenji , MASUDA, Katsuyuki , YANO, Tomoyuki , OHNO, Ryuta , MATUKAWA, Tomoko , IMAI, Kiyomi , OKANO, Natsuko , YOSHII, Tomoko , MOURI, Takehito
IPC分类号： C07D263/44 , C07C67/31 , C07C69/708 , B01J27/128 , B01J27/138 , B01J31/04 , B01J31/18 , C07B61/00
CPC分类号： C07D263/44 , C07C67/31 , C07C69/708
摘要： An industrial process for efficiently preparing a 3-(substituted phenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione derivative having a potent herbicidal activity without using phosgene or the like. More precisely, a process for preparing a 3-(substituted phenyl)-5-alkylidene-1,3-oxazolidine-2,3-dione derivative of general formula (III) by reacting an N-(substituted phenyl)carbamate of general formula (I) with a 2-hydroxy-3-alkenoate of general formula (II) or a 3-alkoxy-2-hydroxyalkanoate of general formula (IV), wherein Ar is substituted phenyl; R1 is C1-C6 alkyl; R?2 and R3¿ are each independently hydrogen or C¿1?-C12 alkyl; and R?4 and R5¿ are each independently C¿1?-C6 alkyl.
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4.发明公开TETRAHYDROPHTHALAMIDE DERIVATIVE, INTERMEDIATE FOR PRODUCING THE SAME, PRODUCTION OF BOTH, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT 失效四氢邻苯衍生物，它们的工艺进行生产的两个中间产品以及诸如含成分除草剂。
公开(公告)号：EP0635485A1
公开(公告)日：1995-01-25
申请号：EP93906823.5
申请日：1993-03-25
发明人： HIRAI, Kenji , MATSUKAWA, Tomoko , YANO, Tomoyuki , EJIRI, Emiko , AIZAWA, Kiyomi , SHIKAKURA, Koichi , YOSHII, Tomoko , UGAI, Sadayuki , YAMADA, Osamu , KISHI, Shigeki
IPC分类号： C07C233/60 , C07D211/16 , C07D211/58 , C07D213/40 , C07D277/06 , C07D295/18 , C07D307/52 , C07D307/88 , A01N37/30 , A01N43/12 , C07C233/62 , C07C233/63 , C07D307/90
CPC分类号： C07D213/40 , A01N37/30 , A01N37/32 , A01N37/46 , A01N43/08 , A01N43/12 , A01N43/40 , A01N43/78 , A01N47/16 , C07C217/88 , C07C233/60 , C07C233/62 , C07C233/63 , C07C2601/02 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/42 , C07C2603/62 , C07C2603/66 , C07D211/58 , C07D277/04 , C07D295/185 , C07D307/52 , C07D307/90
摘要： A 3,4,5,6-tetrahydrophthalamide derivative and a 3,4,5,6-tetrahydroisophthalimide derivative, both having an excellent efficay as the active ingredient of a herbicide, and an industrial process for efficiently producing these higher-performance, herbicidally active compounds. A tetrahydrophthalamide derivative represented by general formula (I) is produced by the reaction of a tetrahydrophthalimide derivative, prepared by the reaction of a halogenated 5-cycloalkyloxyaniline derivative with 3,4,5,6-tetrahydrophthalic anhydride, or of the tetrahydroisophthalimide derivative of the invention with various amines. These tetrahydrophthalamide and tetrahydroisophthalimide derivatives have an excellent herbicidal effect in the treatment of lowland and upland soils and foliage treatment. The tetrahydroisophthalimide derivative is useful also as an intermediate for producing the tetrahydrophthalamide derivative and the like.
摘要翻译： 甲3,4,5,6- tetrahydrophthalamide衍生物和3,4,5,6- tetrahydroisophthalimide衍生物，两者都具有优异的efficay作为除草剂的活性成分，并且对工业过程高效地制造论文较高性能，除草 活性化合物。 由通式（I）表示的衍生物tetrahydrophthalamide由四氢邻苯二甲衍生物的反应产生，通过卤化5- cycloalkyloxyaniline衍生物的反应用3,4,5,6-四氢邻苯二甲酸酐制备的，或tetrahydroisophthalimide的衍生物的 本发明的具有各种cardamines。 这些tetrahydrophthalamide和tetrahydroisophthalimide衍生物在低地和高地土壤和叶面处理的处理具有优异的除草效果。 所述tetrahydroisophthalimide衍生物以中间体用于制备tetrahydrophthalamide衍生物等是有用的。
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5.发明公开PYRAZOLE DERIVATIVE, INTERMEDIATE THEREFOR, PROCESSES FOR PRODUCING THESE, AND HERBICIDE CONTAINING THESE AS ACTIVE INGREDIENT 有权吡唑衍生物，它们的中间体，及其制造方法除草剂有他们作为活性成分
公开(公告)号：EP1362852A1
公开(公告)日：2003-11-19
申请号：EP02712451.0
申请日：2002-02-19
发明人： HIRAI, Kenji , UCHIDA, Atsushi , WATANABE, Atsuko , ABE, Taeko , UEDA, Takuya , ITO, Hiroshi
IPC分类号： C07D231/20 , C07D401/12 , C07D405/12 , C07D409/12 , C07D413/12 , A01N47/38
CPC分类号： A01N47/38 , C07D231/20
摘要： The present invention provides a pyrazole derivative of the general formula (1),
which has an excellent efficacy as an active component for a herbicide, an intermediate for the production thereof, processes for the production thereof, and a herbicide containing the derivative as an active ingredient.摘要翻译： 本发明提供通式（1）
具有优异的功效，以用于除草剂中间体用于生产它们的活性组分，其生产工艺的吡唑衍生物和除草剂含有该衍生物 作为活性成分。 -
6.发明授权HETEROCYCLE-SUBSTITUTED BENZENE DERIVATIVE, PRODUCTION THEREOF, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT 失效杂环取代的苯衍生物，其经营及除草剂WHICH此作为活性成分
公开(公告)号：EP0493606B1
公开(公告)日：2000-10-18
申请号：EP91912325.7
申请日：1991-07-16
发明人： HIRAI, Kenji , YAMASHITA, Mitsuo , TATENO, Tomoko , EJIRI, Emiko , HARASAWA, Kikuko , ONJI, Yuichi , UGAI, Sadayuki , NAGATO, Shoin
IPC分类号： C07D209/48 , A01N43/38
CPC分类号： C07D209/48 , A01N37/32 , A01N43/56 , C07C69/96 , C07C205/43 , C07C217/88 , C07C219/34 , C07C271/28 , C07C2601/08 , C07C2601/14 , C07D231/56
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7.发明授权TETRAHYDROPHTHALAMIDE DERIVATIVE, INTERMEDIATE FOR PRODUCING THE SAME, PRODUCTION OF BOTH, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT 失效四氢邻苯衍生物，它们的工艺进行生产的两个中间产品以及诸如含成分除草剂
公开(公告)号：EP0635485B1
公开(公告)日：1997-06-11
申请号：EP93906823.5
申请日：1993-03-25
发明人： HIRAI, Kenji , MATSUKAWA, Tomoko , YANO, Tomoyuki , EJIRI, Emiko , AIZAWA, Kiyomi , SHIKAKURA, Koichi , YOSHII, Tomoko , UGAI, Sadayuki , YAMADA, Osamu , KISHI, Shigeki
IPC分类号： C07C233/60 , C07D211/16 , C07D211/58 , C07D213/40 , C07D277/06 , C07D295/18 , C07D307/52 , C07D307/88 , A01N37/30 , A01N43/12 , C07C233/62 , C07C233/63 , C07D307/90
CPC分类号： C07D213/40 , A01N37/30 , A01N37/32 , A01N37/46 , A01N43/08 , A01N43/12 , A01N43/40 , A01N43/78 , A01N47/16 , C07C217/88 , C07C233/60 , C07C233/62 , C07C233/63 , C07C2601/02 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/42 , C07C2603/62 , C07C2603/66 , C07D211/58 , C07D277/04 , C07D295/185 , C07D307/52 , C07D307/90
摘要： A 3,4,5,6-tetrahydrophthalamide derivative and a 3,4,5,6-tetrahydroisophthalimide derivative, both having an excellent efficay as the active ingredient of a herbicide, and an industrial process for efficiently producing these higher-performance, herbicidally active compounds. A tetrahydrophthalamide derivative represented by general formula (I) is produced by the reaction of a tetrahydrophthalimide derivative, prepared by the reaction of a halogenated 5-cycloalkyloxyaniline derivative with 3,4,5,6-tetrahydrophthalic anhydride, or of the tetrahydroisophthalimide derivative of the invention with various amines. These tetrahydrophthalamide and tetrahydroisophthalimide derivatives have an excellent herbicidal effect in the treatment of lowland and upland soils and foliage treatment. The tetrahydroisophthalimide derivative is useful also as an intermediate for producing the tetrahydrophthalamide derivative and the like.
摘要翻译： 甲3,4,5,6- tetrahydrophthalamide衍生物和3,4,5,6- tetrahydroisophthalimide衍生物，两者都具有优异的efficay作为除草剂的活性成分，并且对工业过程高效地制造论文较高性能，除草 活性化合物。 由通式（I）表示的衍生物tetrahydrophthalamide由四氢邻苯二甲衍生物的反应产生，通过卤化5- cycloalkyloxyaniline衍生物的反应用3,4,5,6-四氢邻苯二甲酸酐制备的，或tetrahydroisophthalimide的衍生物的 本发明的具有各种cardamines。 这些tetrahydrophthalamide和tetrahydroisophthalimide衍生物在低地和高地土壤和叶面处理的处理具有优异的除草效果。 所述tetrahydroisophthalimide衍生物以中间体用于制备tetrahydrophthalamide衍生物等是有用的。
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8.发明授权PYRAZOLE DERIVATIVE, INTERMEDIATE THEREFOR, PROCESSES FOR PRODUCING THESE, AND HERBICIDE CONTAINING THESE AS ACTIVE INGREDIENT 有权吡唑衍生物，它们的中间体，及其制造方法除草剂有他们作为活性成分
公开(公告)号：EP1362852B1
公开(公告)日：2011-04-06
申请号：EP02712451.0
申请日：2002-02-19
发明人： HIRAI, Kenji , UCHIDA, Atsushi , WATANABE, Atsuko , ABE, Taeko c/o Sun Verl Machida 607 , UEDA, Takuya , SAKURAI, Hiroshi
IPC分类号： C07D231/20 , C07D401/12 , C07D405/12 , C07D409/12 , C07D413/12 , A01N47/38
CPC分类号： A01N47/38 , C07D231/20
摘要： A pyrazole derivative represented by the following general formula (1). (1) It is highly effective when used as the active ingredient of a herbicide.
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9.发明公开4-IMINOOXAZOLIDIN-2-ONE DERIVATIVE, PROCESS FOR PRODUCING THE SAME, AND HERBICIDE CONTAINING THE SAME AS ACTIVE INGREDIENT 失效4- IMINOOXAZOLIDIN -2-酮衍生物，用于生产和YOU作为活性成分的除草剂含
公开(公告)号：EP0722939A1
公开(公告)日：1996-07-24
申请号：EP94929018.3
申请日：1994-10-07
发明人： HIRAI, Kenji , MATSUKAWA, Tomoko , YANO, Tomoyuki , MASUDA, Katsuyuki , YOSHII, Tomoko , MOURI, Takehito , UGAI, Sadayuki , YAMADA, Osamu
IPC分类号： C07D263/48 , A01N43/76
CPC分类号： C07D263/48 , A01N43/76
摘要： The invention relates to 4-imino-oxazolidine-2-one derivatives represented by the general formula (1):
and a process for producing said compounds by reacting aryl isocyanates of the general formula (2):
with methacrolein cyanohydrin in the presence of a base, as well as a herbicide containing said compounds as an active ingredient; it also relates to a process for producing oxazolidinedione derivatives useful as herbicides by hydrolyzing said compounds.摘要翻译： 本发明涉及4-亚氨基恶唑烷-2-酮衍生物由通式（1）表示：
以及用于通过使通式（2）的芳基异氰酸酯生产所述化合物的方法： 用异丁烯醛 在碱，以及除草化合物的存在氰醇含有所述作为活性成分; 因此，它涉及一种生产作为通过水解所述化合物的除草剂有用恶唑烷二酮衍生物的方法。 -
10.发明公开HYDANTOIN DERIVATIVES, PROCESS FOR PRODUCING THE SAME AND HERBICIDES COMPRISING THE SAME AS ACTIVE INGREDIENTS 失效乙内酰脲衍生物，其制造方法相同，作为活性成分的除草剂含
公开(公告)号：EP0801068A1
公开(公告)日：1997-10-15
申请号：EP95941888.0
申请日：1995-12-26
发明人： HIRAI, Kenji , YANO, Tomoyuki , OKANO, Natuko , UGAI, Sadayuki , YAMADA, Osamu
IPC分类号： C07D471/04 , A01N43/90
CPC分类号： C07D471/04 , A01N43/90
摘要： This invention provides with novel hydantoin derivatives, processes for preparing them, and herbicides containing said derivatives as active ingredient.
The hydantoin derivative of this invention represented by the general formula (1):
is produced by reacting an arylisocyanate derivative or an arylisothiocyanate derivative represented by the general formula (2):
with a dehydropipecolic acid derivative represented by the general formula (3):摘要翻译： 本发明新颖的乙内酰脲衍生物提供，制备它们的方法，和除草剂含有所述衍生物作为活性成分。 由通式（1）代表的本发明的乙内酰脲衍生物：
是通过使至芳基的异氰酸酯衍生物或在由通式arylisothiocyanate衍生物制备（2）： 与由一般代表一个脱氢酸衍生物 式（3）：
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