THERMALLY CONDUCTIVE SILICONE COMPOSITION AND CURED OBJECT OBTAINED THEREFROM

    公开(公告)号:EP4349916A1

    公开(公告)日:2024-04-10

    申请号:EP22816078.4

    申请日:2022-05-31

    发明人: TSUKADA, Junichi

    摘要: Provided is a thermally conductive silicone composition capable of being turned into a cured product that is superior in heat dissipation property and is able to suppress corrosion of metal wirings. The thermally conductive silicone composition contains:
    (A) an organopolysiloxane having at least 2 silicon atom-bonded alkenyl groups per molecule, and having a kinetic viscosity of 10 to 100,000 mm 2 /s at 25°C;
    (B) an organohydrogenpolysiloxane having, per molecule, at least 2 hydrogen atoms that are directly bonded to silicon atoms;
    (C) a thermally conductive filler having a thermal conductivity of not lower than 10 W/m·K;
    (D) a dimethylpolysiloxane with one molecular chain end being blocked by a trialkoxy group;
    (E) a platinum group metal-based curing catalyst;
    (F) benzotriazole and/or a benzotriazole derivative; and
    (G) an aliphatic unsaturated bond-free organopolysiloxane.

    THERMALLY CONDUCTIVE SILICONE RESIN COMPOSITION

    公开(公告)号:EP4082970A1

    公开(公告)日:2022-11-02

    申请号:EP20908282.5

    申请日:2020-12-08

    摘要: One of the objects of the present invention is to provide a thermally conductive silicone resin composition which has good thermal conductivity, a light weight (namely, a light weight per unit volume), and good reliability in high humidity, and a molded body thereof. The present invention provides a thermally conductive silicone resin composition comprising the following components (A) to (E):
    (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in an amount of 100 parts by mass,
    (B) an organohydrogen polysiloxane having at least two hydrogen atoms each bonded to a silicon atom in an amount such that the ratio of the number of the hydrogen atoms bonded to a silicon atom relative to the number of the alkenyl group in component (A) is 0.1 to 2,
    (C) a thermally conductive filler in an amount of 2500 to 6000 parts by mass,
    (D) a catalytic amount of an addition-reaction catalyst, and
    (E) an addition-reaction controlling agent in an amount of 0.01 to 1 parts by mass,
    wherein the thermally conductive filler (C) comprises magnesium oxide having a specific surface area of 0.4 m 2 /g or less in an amount of 20 to 50 wt %, and aluminum hydroxide in an amount of 10 to 30 wt%, relative to the total weight of component (C).

    THERMALLY CONDUCTIVE SILICONE COMPOSITION AND CURED PRODUCT THEREOF

    公开(公告)号:EP3872135A1

    公开(公告)日:2021-09-01

    申请号:EP19876590.1

    申请日:2019-08-05

    摘要: This invention is a thermal conductive silicone composition containing: (A) 100 parts by mass of an organopolysiloxane having at least two alkenyl groups per molecule; (B) an organohydrogenpolysiloxane having at least two hydrogen atoms directly bonded to silicon atoms in such an amount that the number of moles of hydrogen atoms directly bonded to silicon atoms is 0.1 to 5.0 times the number of moles of alkenyl groups derived from the component (A); (C) 2,800 to 4,000 parts by mass of a heat conductive filler including 50 mass% or more of a mixture of 25 to 35 mass% of aluminum hydroxide having an average particle size of 0.1 µm or more and less than 40 µm and 65 to 75 mass% of aluminum hydroxide having an average particle size of 40 µm or more and 100 µm or less; and (D) a platinum group metal-based curing catalyst having a mass-based platinum group metal element content of 0.1 to 1,000 ppm relative to the component (A). This provides a thermal conductive silicone composition and a cured product thereof which result in a thermal conductive silicone cured product having both thermal conduction and light weight.