公开(公告)号：EP2595225A1

公开(公告)日：2013-05-22

申请号：EP11806580.4

申请日：2011-06-13

申请人： Showa Denko K.K.

发明人： IMAI, Takuya ,  WAKIZAKA, Yasuaki ,  OTA, Kenichiro

IPC分类号： H01M4/88 ,  B01J27/24 ,  H01M4/90 ,  H01M8/10

CPC分类号： B01J27/24 ,  H01M4/88 ,  H01M4/90 ,  H01M4/9016 ,  H01M2008/1095

摘要： To provide a method for producing a fuel cell catalyst containing a metal oxycarbonitride having durability that is superior to that of conventional fuel cell catalysts. A method for producing a fuel cell catalyst comprising a metal oxycarbonitride, the method comprising: a step of producing a metal oxycarbonitride by heating a metal carbonitride in an inert gas containing oxygen gas; and a step of bringing the metal oxycarbonitride into contact with an acidic solution.

摘要翻译： 一种用于制造燃料电池用催化剂包含具有耐久性的金属碳氮氧化物确实提供的方法优于常规的那样的燃料电池催化剂。 一种用于制造燃料电池催化剂，其包含金属碳氮氧化物的方法，该方法包括：通过在惰性气体中加热金属碳氮化物在含有氧气制造金属碳氮氧化物的工序; 并且使金属与在酸性溶液接触碳氮氧化物的工序。

公开(公告)号：EP2535971B1

公开(公告)日：2018-10-24

申请号：EP11742236.0

申请日：2011-02-09

申请人： Showa Denko K.K.

发明人： LEE, Kunchan ,  KONTA, Ryoko ,  HORIKITA, Masaki ,  YU, Chunfu ,  WAKIZAKA, Yasuaki ,  OTA, Kenichiro ,  MONDEN, Ryuji ,  ICHIOKA, Kazunori ,  SATO, Takashi ,  IMAI, Takuya

IPC分类号： H01M8/1004 ,  H01M4/90 ,  C01B21/082

CPC分类号： H01M4/9016 ,  C01B21/0828 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/8896 ,  H01M8/1004 ,  Y02E60/521

摘要： Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100°C to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

公开(公告)号：EP2518806A1

公开(公告)日：2012-10-31

申请号：EP10839224.2

申请日：2010-12-13

申请人： Showa Denko K.K.

发明人： IMAI, Takuya ,  WAKIZAKA, Yasuaki ,  SHISHIKURA, Toshikazu ,  HORIKITA, Masaki ,  OTA, Kenichiro

IPC分类号： H01M4/86 ,  H01M4/90 ,  H01M8/10

CPC分类号： H01M4/8828 ,  H01M4/8663 ,  H01M4/8673 ,  H01M4/9016 ,  H01M2008/1095

摘要： There is provided an ink for forming a fuel cell catalyst layer that is capable of efficiently forming a high-performance fuel cell catalyst layer inexpensively. The ink for forming a fuel cell catalyst layer of the present invention comprises a fuel cell catalyst, an electron conductive material, a proton conductive material and a solvent, wherein the fuel cell catalyst comprises a metal-containing oxycarbonitride that contains niobium and/or titanium; the mass ratio [(A)/(B)] of the content (A) of the fuel cell catalyst to the content (B) of the electron conductive material is 1 to 6; and the mass ratio [(D)/(C)] of the content (D) of the proton conductive material to the total content (C) of the fuel cell catalyst and the electron conductive material is 0.2 to 0.6.

摘要翻译： 提供了一种用于形成能够廉价有效地形成高性能燃料电池催化剂层的燃料电池催化剂层的油墨。 用于形成本发明燃料电池催化剂层的油墨包括燃料电池催化剂，电子传导材料，质子传导材料和溶剂，其中燃料电池催化剂包括含有铌和/或钛的含金属碳氮氧化物 ; 燃料电池催化剂的含量（A）与电子导电材料的含量（B）的质量比[（A）/（B）]为1〜6; 并且质子传导材料的含量（D）与燃料电池催化剂和电子导电材料的总含量（C）的质量比[（D）/（C）]为0.2〜0.6。

公开(公告)号：EP2595225B1

公开(公告)日：2019-06-12

申请号：EP11806580.4

申请日：2011-06-13

申请人： Showa Denko K.K.

发明人： IMAI, Takuya ,  WAKIZAKA, Yasuaki ,  OTA, Kenichiro

IPC分类号： H01M4/90 ,  H01M4/88 ,  H01M8/1018

公开(公告)号：EP2428268B1

公开(公告)日：2017-03-01

申请号：EP10769718.7

申请日：2010-04-27

申请人： Showa Denko K.K.

发明人： WAKIZAKA, Yasuaki ,  IMAI, Takuya ,  SHISHIKURA, Toshikazu ,  MONDEN, Ryuji ,  OTA, Kenichiro

IPC分类号： B01J27/24 ,  H01M4/90 ,  H01M8/1018

CPC分类号： H01M4/9016 ,  B01J27/24 ,  H01M2008/1095 ,  Y02E60/50

公开(公告)号：EP2518806B1

公开(公告)日：2015-08-19

申请号：EP10839224.2

申请日：2010-12-13

申请人： Showa Denko K.K.

发明人： IMAI, Takuya ,  WAKIZAKA, Yasuaki ,  SHISHIKURA, Toshikazu ,  HORIKITA, Masaki ,  OTA, Kenichiro

IPC分类号： H01M4/86 ,  H01M4/90 ,  H01M8/10 ,  H01M4/88

CPC分类号： H01M4/8828 ,  H01M4/8663 ,  H01M4/8673 ,  H01M4/9016 ,  H01M2008/1095

公开(公告)号：EP2535971A1

公开(公告)日：2012-12-19

申请号：EP11742236.0

申请日：2011-02-09

申请人： Showa Denko K.K.

发明人： LEE, Kunchan ,  KONTA, Ryoko ,  HORIKITA, Masaki ,  YU, Chunfu ,  WAKIZAKA, Yasuaki ,  OTA, Kenichiro ,  MONDEN, Ryuji ,  ICHIOKA, Kazunori ,  SATO, Takashi ,  IMAI, Takuya

IPC分类号： H01M4/88 ,  B01J27/24 ,  B01J37/04 ,  B01J37/08 ,  C01B21/076 ,  C01B21/082 ,  H01M4/90 ,  H01M8/10

CPC分类号： H01M4/9016 ,  C01B21/0828 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/8896 ,  H01M8/1004 ,  Y02E60/521

摘要： Provided is a process for producing a fuel cell electrode catalyst having high catalytic activity which uses a transition metal, e.g., titanium, which process comprises thermal treatment at relatively low temperature, i.e., not including thermal treatment at high temperature (calcining) step. The process for producing a fuel cell electrode catalyst comprises a step (1) of mixing at least a transition metal-containing compound, a nitrogen-containing organic compound and a solvent to provide a catalyst precursor solution; a step (2) of removing the solvent from the catalyst precursor solution; and a step (3) of thermally treating a solid residue obtained in the step (2) at a temperature of 500 to 1100°C to provide an electrode catalyst; wherein the transition metal-containing compound is partly or wholly a compound comprising at least one transition metal element (M1) selected from the group 4 and 5 elements of the periodic table as a transition metal element.

摘要翻译： 本发明提供一种用于制造燃料电池用电极催化剂具有高的催化活性使用的过渡金属，E. G.，钛，其在相对低的温度包括过程的热处理，即，不包括在高温（煅烧）步骤热处理的过程。 用于制造燃料电池用电极催化剂的制造方法至少包括含过渡金属的化合物，含氮的有机化合物和溶剂以提供催化剂前体溶液进行混合的工序（1）; 除去由催化剂前体溶液中的溶剂的工序（2）; 和步骤（3）的热处理在500〜1100℃的温度下进行步骤（2），以提供催化剂到电极得到固体残余物; worin所述含过渡金属的化合物是部分或全部包含选自4和周期表的第5种族元素作为过渡金属元素中选择的至少一种过渡金属元素（M1）的化合物。

公开(公告)号：EP2428268A1

公开(公告)日：2012-03-14

申请号：EP10769718.7

申请日：2010-04-27

申请人： Showa Denko K.K.

发明人： WAKIZAKA, Yasuaki ,  IMAI, Takuya ,  SHISHIKURA, Toshikazu ,  MONDEN, Ryuji ,  OTA, Kenichiro

IPC分类号： B01J27/24 ,  H01M4/88 ,  H01M4/90 ,  H01M8/10

CPC分类号： H01M4/9016 ,  B01J27/24 ,  H01M2008/1095 ,  Y02E60/50

摘要： The invention provides catalysts that are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability. The catalyst includes a metal element M, carbon, nitrogen and oxygen, wherein the catalyst shows peaks at 1340 cm -1 to 1365 cm -1 and at 1580 cm -1 to 1610 cm -1 as analyzed by Raman spectroscopy and the metal element M is one selected from titanium, iron, niobium, zirconium and tantalum. The catalysts of the invention are stable and are not corroded in acidic electrolytes or at high potential, have high oxygen reducing ability and are inexpensive compared to platinum. Fuel cells having the catalysts are therefore relatively inexpensive and have high performance.

摘要翻译： 本发明提供了在酸性电解质或高电位下不被腐蚀并且具有优异的耐久性和高氧还原能力的催化剂。 该催化剂包括金属元素M，碳，氮和氧，其中该催化剂在通过拉曼光谱法分析时在1340cm-1至1365cm-1和1580cm-1至1610cm-1处显示峰，金属元素M 是选自钛，铁，铌，锆和钽中的一种。 本发明的催化剂稳定并且不会在酸性电解质中或在高电位下被腐蚀，具有高的氧还原能力并且与铂相比便宜。 具有催化剂的燃料电池因此相对便宜且具有高性能。