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1.发明公开
公开(公告)号：EP2376544A1
公开(公告)日：2011-10-19
申请号：EP09799022.0
申请日：2009-12-10
发明人： ROBERT, Pierre , THUILLIEZ, Julien
摘要： The invention relates to a method for preparing a functionalised diene elastomer, in particular a functionalised polybutadiene with a high cis-1,4 chaining rate having both a high Mooney viscosity and a low polydispersity index. The method of the invention comprises reacting a catalytic system with at least one conjugated diene monomer to be polymerised, and adding a functionalising agent to the elastomer thus obtained, said catalytic system including at least: optionally, a preformation conjugated diene; a salt of one or more rare earth metals; an inert hydrocarbon solvent; and alkylation agent; and a halogen donor with the exception of alkylaluminium sesquihalides; and the incorporation of at least one Lewis base: (i) either, before said reaction, in the catalytic system during the synthesis thereof, (ii) or, during said reaction, in said polymerising medium including said catalytic system and said monomer(s) to be polymerised.
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2.发明授权
公开(公告)号：EP1893681B1
公开(公告)日：2009-09-16
申请号：EP06742878.9
申请日：2006-05-11
发明人： ARAUJO DA SILVA, José, Carlos , BINDE, Nathalie , ROBERT, Pierre , STERIN, Sébastien , VEYLAND, Anne
CPC分类号： C08K5/54 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C2015/0614 , C08K3/36 , C08K5/5455 , C08L21/00
摘要： The invention concerns a tyre and a rubber composition for tyre or semi-finished product for tyre, based on at least one isoprene elastomer (for example, natural rubber), an inorganic filler as reinforcing filler (for example, silica), a coupling system binding said reinforcing inorganic filler and the isoprene elastomer, said coupling system comprising in combination: a monofunctional covering agent (for example, a polyorganosiloxane oil) capable of binding to the functional sites of the inorganic filler surface; and as coupling agent, an organosilicium compound (for example, an organosilane or an organosiloxane) at least bifunctional graftable on the elastomer by means of a functional azo-dicarbonyl (-CO-N=N-CO-) group.
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公开(公告)号：EP1915422A1
公开(公告)日：2008-04-30
申请号：EP06776284.9
申请日：2006-07-18
CPC分类号： B60C1/0016 , C08K5/0016 , C08L21/00 , C08L2666/04 , C08L2666/06
摘要： The invention relates to a plasticizing system that can be used for plasticizing a diene rubber composition, characterized in that it is based on an MES or TDAE oil and on a terpene/vinyl aromatic copolymer resin, in particular, limonene and styrene copolymer. The rubber composition exhibits an improved resistance to wear and to cuts, said composition being based on at leas tone diene elastomer, a reinforcing filler, a cross-linking system and a plasticizing system comprising between 5 and 35 pce of an MES or TDAE oil and between 5 and 35 pce of a terpene/vinyl aromatic copolymer resin (pce = parts by weight per 100 parts of elastomers). The invention also relates to a method for preparing a composition of the aforementioned type, to the use of this composition for producing a finished article or semi-finished product for use in a tire or a tire/motor vehicle connecting system, particularly a tire tread.
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4.发明公开PROCÉDÉ DE PRÉPARATION D'UN COPOLYMÈRE DIÉNIQUE À BLOC POLYÉTHER, COMPOSITION DE CAOUTCHOUC RENFORCÉE ET PNEUMATIQUE 有权用于生产共轭二烯共聚物与聚醚，增强KAUTSCHUKZUSAMMENESETZUNG和轮胎
公开(公告)号：EP2173808A1
公开(公告)日：2010-04-14
申请号：EP08761241.2
申请日：2008-06-19
CPC分类号： C08L53/02 , B60C1/0016 , C08C19/44 , C08G81/025
摘要： The invention relates to a process for preparing, in one step, a diene block copolymer, of which at least one of these blocks is constituted of a polyether for which the number-average molecular weight is essentially from 100 to 5000 g/mol, and at least another of these blocks is constituted of a diene elastomer. The process according to the invention allows a high degree of grafting of the polyether to the polymer chains. The present invention also relates to a reinforced rubber composition, especially intended for manufacturing tyres, comprising such a block copolymer that is intended to interact with the reinforcing filler. A rubber composition according to the invention has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
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5.发明公开
公开(公告)号：EP1451246A1
公开(公告)日：2004-09-01
申请号：EP02803791.9
申请日：2002-11-25
发明人： ROBERT, Pierre , MATHIEU, Samuel
CPC分类号： C08C19/30 , B60C1/0016 , C08K3/013 , Y02T10/862 , C08L13/00
摘要： The invention concerns a rubber composition useful for forming a tyre running tread, said composition being based on at least: a reinforcing inorganic filler; a diene elastomer having a molar percentage of units derived from conjugate dienes higher than 30 % which is prepared in emulsion and which includes carboxylic acid functions along its chain; a binding agent between said reinforcing inorganic filler and said elastomer consisting of a polysulphur alkoxysilane. Said composition is such that said elastomer is obtainable by carrying out: in an emulsifying solution, free radical copolymerisation of at least a conjugate diene monomer with a precursor comonomer which is hydrolysable or oxidizable in carboxylic acid, to obtain an intermediate diene elastomer comprising functions precursor of said acid along its chain; then hydrolysis or oxidation of said precursor functions to obtain said elastomer comprising carboxylic acid functions along its chain.
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6.发明授权COMPOSITION DE CAOUTCHOUC POUR PNEUMATIQUE COMPORTANT UN SYSTEME DE COUPLAGE ORGANOSILICIQUE 有权轮胎橡胶两者合并的比率含有有机硅公民教育体系
公开(公告)号：EP1893683B1
公开(公告)日：2010-08-18
申请号：EP06753568.2
申请日：2006-05-11
发明人： ARAUJO DA SILVA, José, Carlos , VEYLAND, Anne , STERIN, Sébastien , ROBERT, Pierre , BINDE, Nathalie
CPC分类号： C08K5/5465 , C08K5/5455 , C08L21/00 , Y10S152/905 , Y10T156/1357 , C08L2666/44
摘要： The invention concerns a tyre and a rubber composition for tyre based on at least one isoprene elastomer (for example, natural rubber), one inorganic filler as reinforcing filler (for example, silica), a coupling system binding said reinforcing inorganic filler and the isoprene elastomer, said coupling system comprising in combination: as first coupling agent, a sulphurated silane compound; as second coupling agent, one at least bifunctional organosilicium compound (for example an organosilane or an organosiloxane) capable of being grafted on the elastomer by means of an azo-dicarbonyl functional (-CO-N=N-CO-) group.
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7.发明公开PROCÉDÉ DE PRÉPARATION D'UN COPOLYMÈRE DIÉNIQUE À BLOC POLYÉTHER, COPOLYMÈRE DIÉNIQUE À BLOC POLYÉTHER, COMPOSITION DE CAOUTCHOUC RENFORCÉE ET PNEUMATIQUE 有权PROCESS用于产生具有与聚醚的聚醚嵌段共轭二烯共聚物的二烯共聚物，补强橡胶组合物和轮胎
公开(公告)号：EP2173789A1
公开(公告)日：2010-04-14
申请号：EP08761237.0
申请日：2008-06-19
IPC分类号： C08G81/02 , C08G65/336 , C08L53/02 , B60C1/00
CPC分类号： C08F297/02 , B60C1/0016 , C08C19/44 , C08F297/04 , C08F297/044 , C08G65/336 , C08G65/337 , C08G81/025 , C08K3/013 , C08L53/00 , C08L53/005 , C08L53/02 , C08L53/025 , C08L71/02 , C08L2205/05 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L15/00
摘要： A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
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公开(公告)号：EP1204702B1
公开(公告)日：2012-04-25
申请号：EP01936381.1
申请日：2001-05-21
CPC分类号： C08L9/06 , B60C1/0016 , C08C19/26 , C08K3/013 , C08K3/36 , C08L19/006 , Y02T10/862 , C08L13/00 , C08L2666/08
摘要： The invention concerns a crosslinkable or crosslinked rubber composition having improved hysteretic properties when crosslinked useful for producing a tyre running tread, a method for preparing such a crosslinkable composition, such a running tread and a tyre exhibiting reduced rolling resistance. The inventive rubber composition is based on an elastomer matrix comprising at least a diene elastomer including a carboxylic acid function at one or at each of its two chain ends, and a reinforcing filler including an inorganic reinforcing filler, and is such that said diene elastomer has a mole weight higher than 80000 g/mol and it is present in major amount in said elastomer matrix.
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9.发明公开COMPOSITION DE CAOUTCHOUC POUR PNEUMATIQUE COMPORTANT UN SYSTEME DE COUPLAGE ORGANOSILICIQUE 有权轮胎橡胶两者合并的比率含有有机硅公民教育体系
公开(公告)号：EP1893683A1
公开(公告)日：2008-03-05
申请号：EP06753568.2
申请日：2006-05-11
发明人： ARAUJO DA SILVA, José, Carlos , VEYLAND, Anne , STERIN, Sébastien , ROBERT, Pierre , BINDE, Nathalie
CPC分类号： C08K5/5465 , C08K5/5455 , C08L21/00 , Y10S152/905 , Y10T156/1357 , C08L2666/44
摘要： The invention concerns a tyre and a rubber composition for tyre based on at least one isoprene elastomer (for example, natural rubber), one inorganic filler as reinforcing filler (for example, silica), a coupling system binding said reinforcing inorganic filler and the isoprene elastomer, said coupling system comprising in combination: as first coupling agent, a sulphurated silane compound; as second coupling agent, one at least bifunctional organosilicium compound (for example an organosilane or an organosiloxane) capable of being grafted on the elastomer by means of an azo-dicarbonyl functional (-CO-N=N-CO-) group.
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10.发明公开
公开(公告)号：EP1893681A1
公开(公告)日：2008-03-05
申请号：EP06742878.9
申请日：2006-05-11
发明人： ARAUJO DA SILVA, José, Carlos , BINDE, Nathalie , ROBERT, Pierre , STERIN, Sébastien , VEYLAND, Anne
CPC分类号： C08K5/54 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C2015/0614 , C08K3/36 , C08K5/5455 , C08L21/00
摘要： The invention concerns a tyre and a rubber composition for tyre or semi-finished product for tyre, based on at least one isoprene elastomer (for example, natural rubber), an inorganic filler as reinforcing filler (for example, silica), a coupling system binding said reinforcing inorganic filler and the isoprene elastomer, said coupling system comprising in combination: a monofunctional covering agent (for example, a polyorganosiloxane oil) capable of binding to the functional sites of the inorganic filler surface; and as coupling agent, an organosilicium compound (for example, an organosilane or an organosiloxane) at least bifunctional graftable on the elastomer by means of a functional azo-dicarbonyl (-CO-N=N-CO-) group.
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