摘要:
An object of the present invention is to provide a novel sulfur-based positive-electrode active material which can largely improve cyclability of a lithium-ion secondary battery, a positive electrode comprising the positive-electrode active material and a lithium-ion secondary battery comprising the positive electrode. The sulfur-based positive-electrode active material is one comprising: a carbon skeleton derived from a polymer composed of a monomer unit having at least one hetero atom-containing moiety, the hetero atom being O, and sulfur incorporated into the carbon skeleton as the carbon skeleton is formed from the polymer by heat treatment.
摘要:
Disclosed is a lithium ion secondary battery, in which a vinyl alcohol polymer or a derivative thereof is arranged inside the battery in an amount of 0.3 mg or more per 1 mAh of battery capacity in terms of a vinyl alcohol unit moiety content. The lithium ion secondary battery can decrease the battery voltage under high-temperature conditions, and cannot be recharged after being exposed to high-temperature conditions.
摘要:
An object of the present invention is to provide a novel sulfur-based positive-electrode active material which can largely improve cyclability of a lithium-ion secondary battery, a positive electrode comprising the positive-electrode active material and a lithium-ion secondary battery comprising the positive electrode. The sulfur-based positive-electrode active material is one comprising: a carbon skeleton derived from a polymer composed of a monomer unit having at least one hetero atom-containing moiety, and sulfur incorporated into the carbon skeleton as the carbon skeleton is formed from the polymer by heat treatment.
摘要:
The invention addresses the problem of providing a polyimide precursor, a polyimide precursor solution, and a mixture slurry, each capable of more firmly binding active material particles to a current collecting body. The polyimide precursor solution according to the invention contains a tetracarboxylic acid ester compound, a diamine compound having an anionic group, and a solvent. The solvent dissolves the tetracarboxylic acid ester compound and the diamine compound. As the tetracarboxylic acid ester compound, a 3,3',4,4'-benzophenonetetracarboxylic acid diester is particularly preferred. Examples of the "diamine compound having an anionic group" include 3,4-diaminobenzoic acid, 3,5-diaminobenzoic acid, and m-phenylenediamine-4-sulfonic acid. Further, the mixture slurry according to the invention contains active material particles in the polyimide precursor solution.
摘要:
A binder for a positive electrode of a lithium ion secondary battery according to the present invention includes a copolymer of vinyl alcohol and an alkali metal-neutralized product of ethylene-unsaturated carboxylic acid.
摘要:
Disclosed is a nickel positive electrode for a fiber battery having a long life duration, and also being enabling a high output and high capacity to be attained. For this purpose, the nickel positive electrode for a fiber battery is obtained by coating a carbon fiber with nickel, then causing a cathodic polarization in a nickel nitrate bath using the nickel-coated carbon fiber as a cathode, and then immersing the precipitate, which was deposited on the surface of the carbon fiber by the cathodic polarization, in an aqueous caustic alkali solution.