ELECTRODE MATERIAL FOR LITHIUM-ION SECONDARY BATTERY AND METHOD FOR MANUFACTURING SAME
    7.
    发明公开
    ELECTRODE MATERIAL FOR LITHIUM-ION SECONDARY BATTERY AND METHOD FOR MANUFACTURING SAME 审中-公开
    用于锂离子二次电池的电极材料及其制造方法

    公开(公告)号:EP3226332A1

    公开(公告)日:2017-10-04

    申请号:EP16191612.7

    申请日:2016-09-29

    IPC分类号: H01M4/58 C01B25/37 H01M4/36

    摘要: An electrode material for a lithium-ion secondary battery of the present invention includes particles which are made of LiFe x Mn 1-w-x-y-z Mg y Ca z A w PO 4 , have an orthorhombic crystal structure, and have a space group of Pmna, in which a mis-fit value [(1-(b2×c2)/(b1×c1))×100] of a bc plane which is computed from lattice constants b1 and c1 of the LiFe x Mn 1-w-x-y-z Mg y Ca z A w PO 4 and lattice constants b2 and c2 of Fe x Mn 1-w-x-y-z Mg y Ca z A w PO 4 obtained by deintercalating Li from LiFe x Mn 1-w-x-y-z Mg y Ca z A w PO 4 by means of an oxidation treatment using nitrosonium tetrafluoroborate in acetonitrile is 1.32% or more and 1.85% or less.

    摘要翻译: 本发明的锂离子二次电池用电极材料包含由LiFexMn1-wxy-zMgyCazAwPO4构成的粒子,具有正交晶系结构,且具有Pmna的空间群,其中,失配值[(1 根据LiFexMn1-wxy-zMgyCazAwPO4的晶格常数b1和c1以及由FexMn1-wxy-zMgyCazAwPO4得到的晶格常数b2和c2计算出的bc平面的[(b2×c2)/(b1×c1))×100] 通过使用四氟硼酸亚硝鎓在乙腈中的氧化处理从LiFexMn1-wxy-zMgyCazAwPO4中脱嵌Li为1.32%以上且1.85%以下。

    ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY, ELECTRODE FOR LITHIUM ION SECONDARY BATTERY, AND LITHIUM ION SECONDARY BATTERY

    公开(公告)号:EP3534439A1

    公开(公告)日:2019-09-04

    申请号:EP18197086.4

    申请日:2018-09-27

    摘要: [Task] To provide an electrode material for a lithium ion secondary battery satisfying both electron conductivity and lithium diffusivity, an electrode in which the electrode material for a lithium ion secondary battery is used, and a lithium ion secondary battery in which the electrode is used.
    [Means for Resolution] An electrode material for a lithium ion secondary battery including a carbonaceous coated electrode active material having primary particles of an electrode active material, secondary particles that are aggregates of the primary particles, and a carbonaceous film that coats the primary particles of the electrode active material and the secondary particles that are the aggregates of the primary particles, in which a ratio A/B of an average primary particle diameter A (nm) that is estimated from a specific surface area of the carbonaceous coated electrode active material obtained by a BET method to a crystallite diameter B (nm) of the electrode active material is 1 or more and 2.5 or less.