摘要:
The invention relates to particulate lithium metal composite materials having a layer containing phosphorous and a method for producing said phosphorous-coated lithium metal products, characterized in that melted, droplet-shaped lithium metal is reacted in a hydrocarbon solvent with a phosphorous source that contains the phosphorous in the oxidation stage 3, and use thereof for the pre-lithiation of electrode materials and the production of battery anodes.
摘要:
This invention relates generally to electrode materials, electrochemical cells employing such materials, and methods of synthesizing such materials. The electrode materials have a crystal structure with a high ratio of Li to metal M, which is found to improve capacity by enabling the transfer of a greater amount of lithium per metal, and which is also found to improve stability by retaining a sufficient amount of lithium after charging. Furthermore, synthesis techniques are presented which result in improved charge and discharge capacities and reduced particle sizes of the electrode materials.
摘要:
An object of the present invention is to provide a highly efficient electrical storage device that uses a fiber positive electrode and a fiber negative electrode and in which lithium ion is used as an intercalating species, and to provide a method of fabricating the electrical storage device. The electrical storage device according to the present invention includes: a fiber positive electrode including an electrically conductive fiber, the fiber having a surface on which a positive electrode active material coating is formed, the positive electrode active material coating containing a transition metal oxide represented by a chemical formula 1 which is (Li 1-x A x ) a M b X c O d ; a fiber negative electrode including an electrically conductive fiber, the fiber having a surface on which a negative electrode active material coating is formed; a separator; and an electrolyte (in the chemical formula 1, A is at least one kind of alkali metal selected from the group consisting of Na, K, Rb, and Cs; M is at least one kind of transition metal selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Ru, Pd, Ag, Ta, W, Ce, Pr, Sm, Eu, and Pb; X is at least one kind of typical elements selected from the group consisting of B, Al, Si, P, S, Ga, and Ge; and 0
摘要:
The present invention relates to primary and secondary electrochemical energy storage systems. More particularly, the present invention relates to such systems as battery cells, especially battery cells utilizing metal fluorides with the presence of phosphates or fluorophosphates, which use materials that take up and release ions as a means of storing and supplying electrical energy.
摘要:
A cathode material for a lithium-ion secondary battery of the present invention is active material particles including central particles represented by General Formula Li x A y D z PO 4 (0.9
摘要:
The present invention relates to a method for manufacturing of a porous electrode material, wherein the porous electrode material comprises transition metal phosphide on a porous structure comprising transition metal. The method comprises contacting elemental phosphorous and a porous structure comprising transition metal, and heating, in an inert atmosphere, the contacted elemental phosphorous and the porous structure comprising transition metal to a temperature in the temperature range of 300 to 1100°C, thereby reacting at least a part of the phosphorous and at least a part of the transition metal under formation of transition metal phosphide on the surface of the porous structure, thereby forming the porous electrode material. The present invention further relates to a porous electrode material obtainable by the method.
摘要:
It is an object to provide a laminated-structure battery that is capable of suppressing output unevenness of the single cells on the inner side and the outer side and improving durability. In a battery that has at least a cathode, an anode, and an electrolyte layer and that has a laminated structure prepared by laminating at least three layers of single battery layers each prepared by opposing the cathode and the anode to each other with an interposal of the electrolyte layer, a laminated-structure battery being characterized by that, in a direction of lamination of respective single battery layers, a center portion is higher than an end portion in terms of at least one of a ratio of a cathode charge capacity to an anode charge capacity (charge A/C ratio) and a ratio of a cathode discharge capacity to an anode discharge capacity (discharge A/C ratio).