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    Metallo-organic polymers for gas separation and purification
    3.
    发明公开
    Metallo-organic polymers for gas separation and purification 无效
    Metallorganische Polymere zur Gastrennung und Reinigung

    公开(公告)号：EP1070538A2

    公开(公告)日：2001-01-24

    申请号：EP00306105.8

    申请日：2000-07-18

    申请人： THE BOC GROUP, INC.

    发明人： Wang, Qing Min ,  Shen, Dongmin ,  Bülow, Martin ,  Lau, Miu Ling ,  Fitch, Frank R. ,  Deng, Shuguang

    IPC分类号： B01J20/00 ,  B01J20/26 ,  B01D53/04 ,  B01D53/047

    CPC分类号： B01D53/02 ,  B01D2253/202 ,  B01D2253/204 ,  B01D2257/402 ,  B01D2257/504 ,  B01D2257/702 ,  B01J20/226 ,  B01J20/26 ,  C08G79/00 ,  Y02C10/08 ,  Y02C20/10 ,  Y02P20/152 ,  Y02P20/153 ,  Y10S95/90

    摘要： The present invention provides for methods and compositions for gas separation and purification utilizing a metallo-organic polymer adsorbent in processes for separating carbon dioxide, water, nitrogen oxides and hydrocarbons from gas streams. The metallo-organic polymer adsorbent composition has the formula:

            [R(L) n ] m M n ,

    wherein R represents an organic spacer selected from the group consisting of an organic cyclic or acyclic compound; L represents a ligation group substituted on the organic spacer selected from the group consisting of carboxylate group, -C(=O)O - ; dithiocarboxylate group, -C(=S)S - ; and β-diketonate group,
    -C(=O)C(R')=C(-O - )-, wherein R' = H, or an aliphatic or aromatic group; M represents a transition metal or a rare earth metal m is the oxidation state of the transition or rare earth metal; and n is the number of the ligation group substituted on the organic spacer.

    摘要翻译： 本发明提供了在气流中分离二氧化碳，水，氮氧化物和烃的方法中利用金属有机聚合物吸附剂进行气体分离和净化的方法和组合物。 金属有机聚合物吸附剂组合物具有下式：R（L）nmMn，其中R表示选自有机环状或非环状化合物的有机间隔物; L表示在选自羧酸酯基，-C（= O）O - 的有机间隔基上取代的连接基团。 二硫代羧酸酯基，-C（= S）S - 和β-二酮基团，-C（= O）C（R'）= C（-O - ） - ，其中R'= H，或脂族或芳族基团; M表示过渡金属或稀土金属，m是过渡金属或稀土金属的氧化态; n是在有机间隔物上取代的连接基团的数目。

    Zeolites and their use in the separation of nitrogen from other gases
    5.
    发明公开
    Zeolites and their use in the separation of nitrogen from other gases 失效
    沸石和它们在氮气从其它气体中分离利用

    公开(公告)号：EP0758561A1

    公开(公告)日：1997-02-19

    申请号：EP96305870.6

    申请日：1996-08-09

    申请人： THE BOC GROUP, INC.

    发明人： Ojo, Adeola F. ,  Fitch, Frank R. ,  Bülow, Martin

    IPC分类号： B01J20/18

    CPC分类号： B01D53/02 ,  B01D53/04 ,  B01D53/047 ,  B01D2253/108 ,  B01D2256/10 ,  B01D2257/102 ,  B01J20/18 ,  Y10S95/902

    摘要： Chabazite, offretite, erionite, levyne, mordenite, gmelinite, zeolite A, zeolite T, EMC-2, ZSM-3, ZSM-18, ZK-5, zeolite L, and beta zeolite whose exchangeable cations are composed, on an equivalents basis, of 95 to 50% lithium ions, 4 to 50% of one or more of aluminium, cerium, lanthanum and mixed lanthanides and 0 to 15% of other ions are prepared by ion-exchanging the base zeolite with water-soluble trivalent ion salts and with water soluble lithium salts. The zeolites preferentially adsorb nitrogen from gas mixtures.

    摘要翻译： 菱沸石，菱钾沸石，毛沸石，插晶菱沸石，丝光沸石，钠菱沸石，A沸石，沸石T，EMC-2，ZSM-3，ZSM-18，ZK-5，沸石L和β沸石是谁的可交换阳离子被组成到当量计 ，95％至50％的锂离子，4至50的一个或多个铝，铈，镧和混合镧系元素和其他离子的0至15％的％的通过离子交换与水溶性三价离子盐的碱沸石制备 和与水溶性锂盐。 沸石优先吸附从气体混合物中的氮。

    Mechanism for oscillating a sample holder within a sample vessel
    7.
    发明公开
    Mechanism for oscillating a sample holder within a sample vessel 失效
    一种用于一个容器内振荡样品架

    公开(公告)号：EP0703442A3

    公开(公告)日：1997-01-02

    申请号：EP95305743.7

    申请日：1995-08-17

    申请人： THE BOC GROUP, INC.

    发明人： Bülow, Martin ,  Micke, André

    IPC分类号： G01N7/02

    CPC分类号： G01N7/02

    摘要： A mechanism used in connection with determining a time resolved interaction between a target substance, for instance, an adsorbent and at least one agent, for instance, an adsorbate capable of interacting with the target substance. In accordance with the method the target substance and agent(s) are introduced into a sample vessel. At the same time, the target substance is oscillated within the sample vessel without changing the volume of the sample vessel. A concentration of one or more components associated with the time resolved interaction as a function of time is measured by measuring chamber pressure and simultaneously performing a mass spectroscopical analysis of chamber content at discrete time intervals. The target substance is oscillated by a mechanical movement which oscillates a sample holder configured to hold the target substance. The movement has a finger-like member, preferably formed by welded steel bellows and a curved member rotating within the finger-like member so that motion of the finger-like member does not change chamber volume and therefore effect the pressure measurements that are to be made in accordance with the method.

    Oxygen sorbent compositions and methods of using same
    10.
    发明公开
    Oxygen sorbent compositions and methods of using same 审中-公开
    氧吸着剂组合物及其使用方法

    公开(公告)号：EP1547972A3

    公开(公告)日：2005-08-03

    申请号：EP04258017.5

    申请日：2004-12-21

    申请人： THE BOC GROUP, INC.

    发明人： Bülow, Martin ,  Böer, Jürgen ,  Burckhardt, Wolfgang ,  Guth, Hans Ulrich ,  Ullmann, Helmut ,  Vashook, Vladimir V.

    IPC分类号： C01B3/38 ,  C01B13/02 ,  B01D53/04 ,  B01D53/047 ,  C04B35/01 ,  C04B35/26 ,  C04B35/45

    CPC分类号： C04B35/01 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D2251/40 ,  B01D2253/106 ,  B01D2253/1124 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/3425 ,  B01D2257/104 ,  B01D2259/40086 ,  C01B3/382 ,  C01B13/0255 ,  C01B2203/0244 ,  C01B2203/0844 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/82 ,  C01B2210/0046 ,  C04B35/2683 ,  C04B35/4508 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3225 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3281 ,  C04B2235/408 ,  C04B2235/768

    摘要： A crystalline ceramic oxide of the general formula (1), (2), (3), (4), (5), (6), (7), (8), (9), or (10):A x B y O 3-δ ,A x A' x' B y B' y' O 3-δ , andA x A' x' A'' x'' B y B' y' B'' y'' O 3-δ ,A 2 BO 4-δ A 2 B 2 O 5-δ AO(ABO 3-δ ) n AM 2 Cu 3 O 7-δ Bi 4 V 2(1-x) Me 2x O 11-3x ,A'B'O 3 where B' is W or Mo;A 2 B 2 O 7-δ , and combinations thereof, wherein: A is a cation of atoms having atomic numbers ranging from 57-71, inclusive, a cation of yttrium, cations of Groups 1 and 2 atoms, and combination thereof; B is a cation of a d-block transition metal; A' is a cation of Na or Li; M is a metal cation selected from cations of Group 2 atoms; Me is a metal cation of Cu, Bi, and Co atoms; x ranges from 0.01 to 1.00; and δ ranges from 0.05 to 0.30 are useful as sorbents of oxygen and catalysts of the reaction between a hydrocarbon and oxygen to form carbon monoxide and hydrogen. The compounds (1) - (10) may also function as active supports for binary metal oxides to enhance the oxygen sorption/desorption capacity of the composites. One group of composite materials comprise components (A) and (B), wherein component (A) is selected from compounds of general formulas (1) through (10), inclusive, and combinations thereof, and component (B) comprises a metal selected from rhodium (Rh), platinum (Pt), palladium (Pd), nickel (Ni) and silver (Ag), and combinations and alloys of these metals.

    摘要翻译： （1），（2），（3），（4），（5），（6），（7），（8），（9）或（10）的晶体陶瓷氧化物：AxByO 3 -A，AxA'x'ByB'y'O3-δ和AxA'x'A''x''ByB'y'B''y''O3-δ，A2BO4-δA2B2O5-δAO（ABO3-δ）nAM2Cu3O7 -δBi4 V 2（1-x）Me 2 xO 11-3x，A'B'O 3其中B'为W或Mo; A 2 B 2 O 7-δ及其组合，其中：A为原子数为57-71的原子 ，钇的阳离子，1族和2族原子的阳离子，以及它们的组合; B是d嵌段过渡金属的阳离子; A'是Na或Li的阳离子; M是选自第2族原子的阳离子的金属阳离子; Me是Cu，Bi和Co原子的金属阳离子; x在0.01至1.00的范围内; 和δ的范围为0.05至0.30可用作氧的吸收剂和烃与氧之间反应形成一氧化碳和氢的催化剂。 化合物（1） - （10）也可以用作二元金属氧化物的活性载体以增强复合材料的氧气吸附/解吸能力。 一组复合材料包含组分（A）和（B），其中组分（A）选自通式（1）至（10）的化合物及其组合，并且组分（B） 从铑（Rh），铂（Pt），钯（Pd），镍（Ni）和银（Ag）以及这些金属的组合和合金。