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1.发明授权METAL (III) COMPLEXES CONTAINING, NON-AROMATIC, ANIONIC, DIENYL GROUPS AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 失效不是芳族的，阴离子二烯基含金属（III）配合物和含ADDITIONSPOLYMERIZATIONSKATALYSATOREN
公开(公告)号：EP0781287B1
公开(公告)日：2002-01-02
申请号：EP95925522.5
申请日：1995-07-06
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00
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公开(公告)号：EP0863919A1
公开(公告)日：1998-09-16
申请号：EP96936975.0
申请日：1996-10-25
发明人： CARNAHAN, Edmund, M. , CARNEY, Michael, J. , NEITHAMER, David, R. , NICKIAS, Peter, N. , SHIH, Keng-Yu , SPENCER, Lee
CPC分类号： C08F10/00 , C08F4/025 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65908 , C08F2500/03 , C08F2500/01 , C08F210/08 , C08F2500/18 , C08F210/14 , C08F2500/07 , C08F2500/04
摘要： A support for use in preparing supported catalysts for addition polymerizations comprising the reaction product of: (A) an inorganic oxide material comprising reactive surface hydroxyl groups, at least some of said hydroxyl groups optionally having been functionalized and converted to a reactive silane moiety corresponding to the formula: -OSiR2H, wherein R, independently each occurrence, is hydrogen, C1-20 hydrocarbyl, or C1-20 hydrocarbyloxy, said inorganic oxide or functionalized derivative thereof comprising less than 1.0 mmol of reactive surface hydroxyl functionality per gram; and (B) an activator compound comprising: b1) a cation which is capable of reacting with a transition metal compound to form a catalytically active transition metal complex, and b2) a compatible anion containing at least one substituent able to react with the inorganic oxide, with residual hydroxyl functionality of the inorganic oxide, or with the reactive silane moiety, thereby covalently bonding the compatible anion to the support; catalysts formed therefrom, process of manufacture and the method of use.
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3.发明授权
公开(公告)号：EP0781299B1
公开(公告)日：1998-09-09
申请号：EP95928056.1
申请日：1995-07-06
CPC分类号： C25B3/02 , C07F5/027 , C07F7/0809 , C07F7/082 , C07F17/00 , C08F4/65908 , C08F4/6592 , C08F10/00
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公开(公告)号：EP1228109A1
公开(公告)日：2002-08-07
申请号：EP00952585.8
申请日：2000-08-07
发明人： CAMPBELL, Richard, E., Jr. , DEVORE, David, D. , JACOBSEN, Grant B. , LAPOINTE, Robert, E. , NEITHAMER, David, R.
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/025 , C08F4/65908 , C08F2500/18 , C08F2500/24 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F210/08
摘要： A composition useful as an addition polymerization catalyst comprising: (a) an inert support; (b) a Group 3-10 or Lanthanide metal complex; and (c) an activator compound capable of causing the metal complex B to form an active polymerization catalyst, said compound corresponding to the formula (I): (A*+a)b(Z*J*j)-cd, wherein A* is a cation of charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a x b is equal to c x d.
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公开(公告)号：EP1000093B1
公开(公告)日：2001-12-12
申请号：EP98935502.9
申请日：1998-06-29
发明人： CARNAHAN, Edmund, M. , JACOBSEN, Grant, B. , KLOSIN, Jerzy , NICKIAS, Peter, N. , SCHWARTZ, David, J. , NEITHAMER, David, R.
IPC分类号： C08F4/643 , C08F10/00 , C07F5/02 , C08F110/00 , C08F210/00
CPC分类号： C07F5/066 , C07F5/00 , C07F5/027 , C08F4/65916 , C08F4/65922 , C08F10/00 , C08F4/65908
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公开(公告)号：EP0889911A1
公开(公告)日：1999-01-13
申请号：EP97909048.0
申请日：1997-03-20
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61916 , C08F4/6192 , C08F4/65908
摘要： Boratabenzene cocatalysts, especially novel pentafluorophenyl boratabenzenes, are useful cocatalysts or activators with metallocenes. They are less expensive than prior art activators, are soluble and offer more irreversible reactions. Compositions comprise at least one metallocene catalyst and at least one dihydroboratabenzene or anion thereof. Processes include polymerizations with metallocenes in the presence of boratabenzene cocatalyst and activation process including bulk electrolysis techniques.
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7.发明授权
公开(公告)号：EP0640090B1
公开(公告)日：1998-09-02
申请号：EP93912135.6
申请日：1993-04-07
CPC分类号： C07F17/00 , C07F7/28 , C08F4/65908 , C08F4/6592 , C08F10/00 , Y10S526/943
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公开(公告)号：EP0863919B1
公开(公告)日：2000-11-15
申请号：EP96936975.0
申请日：1996-10-25
发明人： CARNAHAN, Edmund, M. , CARNEY, Michael, J. , NEITHAMER, David, R. , NICKIAS, Peter, N. , SHIH, Keng-Yu , SPENCER, Lee
CPC分类号： C08F10/00 , C08F4/025 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65908 , C08F2500/03 , C08F2500/01 , C08F210/08 , C08F2500/18 , C08F210/14 , C08F2500/07 , C08F2500/04
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公开(公告)号：EP0793679A1
公开(公告)日：1997-09-10
申请号：EP95927164.0
申请日：1995-07-14
CPC分类号： C08F110/02 , C08F4/54
摘要： Ethylene is homopolymerized in the presence of a catalyst consisting essentially of a Group 3 metal complex, preferably a scandium complex, having a bridged ligand structure. Optionally polymer blends are prepared by combining the process with another polymerization process, either in series or in parallel.
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10.发明公开METAL (III) COMPLEXES CONTAINING, NON-AROMATIC, ANIONIC, DIENYL GROUPS AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 失效不是芳族的，阴离子二烯基含金属（III）配合物和含ADDITIONSPOLYMERIZATIONSKATALYSATOREN
公开(公告)号：EP0781287A1
公开(公告)日：1997-07-02
申请号：EP95925522.0
申请日：1995-07-06
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00
摘要： Novel group 4, group 3 or lanthanide metal complexes wherein the metal is in the +3 formal oxidation state containing a cyclic or non-cyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
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