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    SUPPORTABLE BISCYCLOPENTADIENYL METAL COMPLEXES
    5.
    发明公开
    SUPPORTABLE BISCYCLOPENTADIENYL METAL COMPLEXES 失效
    可支撑的双环戊二烯金属配合物

    公开(公告)号：EP0858462A1

    公开(公告)日：1998-08-19

    申请号：EP96935872.0

    申请日：1996-09-20

    申请人： THE DOW CHEMICAL COMPANY

    发明人： NICKIAS, Peter, N. ,  SPENCER, Lee

    IPC分类号： C07F17 ,  C08F10 ,  C08F4

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/61927

    摘要： Metal complexes corresponding to formula (I), wherein L independently each occurrence is a delocalized, π-bonded group that is bound to M, containing up to 50 non-hydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C1-20 hydrocarbyl, and C1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C1-20 hydrocarbyloxy, and m is an integer from 1 to 3; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X' independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxyl, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X' groups together form a divalent hydrocarbadiyl or neutral hydrocarbon group; n is a number from 0 to 3; and p is an integer from 0 to 2.

    摘要翻译： 对应于式（I）的金属络合物，其中L各自独立地为与M结合的离域的π-键合基团，其含有至多50个非氢原子; M是元素周期表第3,4族或镧系元素的金属; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E每次出现时独立地为碳，硅或锗，R每次出现时独立地选自C1 -20烃基和C 1-20烃氧基，条件是在至少一次出现时R为C 1-20烃氧基，且m为1-3的整数; X'是具有至多20个非氢原子的中性路易斯碱配体; X'独立地为选自具有至多20个非氢原子的氢化物，卤素，烃基，甲硅烷基，甲锗烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和氨基烃基的一价阴离子部分，或两个X' 基团一起形成二价烃基或中性烃基; n是从0到3的数字; 并且p是0至2的整数。

    ZWITTERIONIC CATALYST ACTIVATOR
    10.
    发明公开
    ZWITTERIONIC CATALYST ACTIVATOR 失效
    ZWITERIONISCHER催化剂活化剂

    公开(公告)号：EP1000093A1

    公开(公告)日：2000-05-17

    申请号：EP98935502.9

    申请日：1998-06-29

    申请人： THE DOW CHEMICAL COMPANY

    发明人： CARNAHAN, Edmund, M. ,  JACOBSEN, Grant, B. ,  KLOSIN, Jerzy ,  NICKIAS, Peter, N. ,  SCHWARTZ, David, J. ,  NEITHAMER, David, R.

    IPC分类号： C08F4/643 ,  C08F10/00 ,  C07F5/02 ,  C08F110/00 ,  C08F210/00

    CPC分类号： C07F5/066 ,  C07F5/00 ,  C07F5/027 ,  C08F4/65916 ,  C08F4/65922 ,  C08F10/00 ,  C08F4/65908

    摘要： A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a zwitterionic compound corresponding to the formula (I) or (II), wherein: L+ is a protonated derivative of an element of Group 15 of the Periodic Table of the Elements, additionally bearing two hydrocarbyl substituents of from 1 to 50 carbons each, or a positively charged derivative of an element of Group 14 of the Periodic Table of the Elements, said Group 14 element being substituted with three hydrocarbyl substituents of from 1 to 50 carbons each; R1 is a divalent linking group of from 1 to 40 non-hydrogen atoms; R2 independently each occurrence is a ligand group of from 1 to 50 nonhydrogen atoms with the proviso that in a sufficient number of occurrences to balance charge in the compound. R?2 is L+-R1-; R4¿ is a bridging hydride or halide group or a divalent linking group of from 1 to 40 non-hydrogen atoms; M1 is boron, aluminum or gallium; Arf independently each occurrence is a monovalent, fluorinated organic group containing from 6 to 100 non-hydrogen atoms; Y is a Group 15 element; and Z is a Group 14 element.