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公开(公告)号：EP0871985A1
公开(公告)日：1998-10-21
申请号：EP97905559.0
申请日：1997-01-02
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Joshi, Vijay , Vermeulen, Lori Ann , Tang, Xiaozhang , Suponeva, Elena , Byrd, Houston
发明人： THOMPSON, Mark, E. , SNOVER, Jonathan, Lee , JOSHI, Vijay , VERMEULEN, Lori, Ann , TANG, Xiaozhang , SUPONEVA, Elena , BYRD, Houston
IPC分类号： B82B1 , B01J23 , B01J31 , B01J35 , C01B3 , C01B15 , C07F9 , C08F8 , C08F30 , C25B1 , H01G9 , H01L51 , H01M6 , H01M14 , C08F230
CPC分类号： H01M14/005 , B01J23/40 , B01J31/0259 , B01J31/1691 , B01J31/1845 , B01J31/185 , B01J35/0013 , B01J35/004 , B01J2231/643 , B01J2231/645 , B01J2531/48 , B82Y10/00 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/44 , C08F30/02 , C08F30/04 , C08F230/02 , C08F230/04 , C25B1/003 , H01G9/20 , H01L51/0075 , H01L51/0595 , H01L51/42 , Y02E10/549 , Y02E60/364 , Y02E60/368 , Y02P20/134 , Y02P20/135
摘要： Multi-layered compositions having a plurality of pillared metal complexes disposed on a supporting substrate (2), the pillars comprising divalent electron acceptor moieties (12) with a phosphonate or arsenate (14) at each end. Each layer of parallel pillars is separated by a layer of a group (IVA), (IVB), (IIIA) or (IIIB) metal or a lanthanide (18). The compositions can further comprise particles of at least one group VIII metal at zero valence entrapped within each layer of the complex (16). The complexes can also incorporate 'stalactites' and 'stalagmites' of capped arsonato or phosphonato ligands interspersed with the pillars providing a series of interstices about each electron accepting group. The supporting substrate can be comprised of an organic polymer template. The complexes are useful for the conversion and storage of solar energy, for the production of photocurrents, and as catalyst for reduction reactions, for example, the production of hydrogen peroxide from oxygen and hydrogen gases, the production of H2 gas from water, and the reduction of ketones to form alcohols.
摘要翻译： 具有多个设置在支撑衬底（2）上的柱状金属络合物的多层组合物，所述柱包含二价电子受体部分（12），每个末端具有膦酸盐或砷酸盐（14）。 每层平行柱由（IVA），（IVB），（IIIA）或（IIIB）金属或镧系元素（18）层分隔开。 该组合物可以进一步包含截留在配合物（16）的每个层内的至少一种零价Ⅷ族金属的颗粒。 这些配合物还可以结合散布在支柱上的加盖的配体或膦酸盐配体的“钟乳石”和“石笋”，为每个受电子基团提供一系列空隙。 支撑基底可以由有机聚合物模板组成。 这些配合物可用于太阳能的转化和储存，用于生产光电流，以及用作还原反应的催化剂，例如从氧气和氢气中生产过氧化氢，从水中生产H2气体和 还原酮形成醇。
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公开(公告)号：EP0871985B1
公开(公告)日：2009-08-19
申请号：EP97905559.7
申请日：1997-01-02
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Joshi, Vijay , Vermeulen, Lori Ann , Tang, Xiaozhang , Suponeva, Elena , Byrd, Houston
发明人： THOMPSON, Mark, E. , SNOVER, Jonathan, Lee , JOSHI, Vijay , VERMEULEN, Lori, Ann , TANG, Xiaozhang , SUPONEVA, Elena , BYRD, Houston
CPC分类号： H01M14/005 , B01J23/40 , B01J31/0259 , B01J31/1691 , B01J31/1845 , B01J31/185 , B01J35/0013 , B01J35/004 , B01J2231/643 , B01J2231/645 , B01J2531/48 , B82Y10/00 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/44 , C08F30/02 , C08F30/04 , C08F230/02 , C08F230/04 , C25B1/003 , H01G9/20 , H01L51/0075 , H01L51/0595 , H01L51/42 , Y02E10/549 , Y02E60/364 , Y02E60/368 , Y02P20/134 , Y02P20/135
摘要： Multi-layered compositions having a plurality of pillared metal complexes disposed on a supporting substrate (2), the pillars comprising divalent electron acceptor moieties (12) with a phosphonate or arsenate (14) at each end. Each layer of parallel pillars is separated by a layer of a group (IVA), (IVB), (IIIA) or (IIIB) metal or a lanthanide (18). The compositions can further comprise particles of at least one group VIII metal at zero valence entrapped within each layer of the complex (16). The complexes can also incorporate 'stalactites' and 'stalagmites' of capped arsonato or phosphonato ligands interspersed with the pillars providing a series of interstices about each electron accepting group. The supporting substrate can be comprised of an organic polymer template. The complexes are useful for the conversion and storage of solar energy, for the production of photocurrents, and as catalyst for reduction reactions, for example, the production of hydrogen peroxide from oxygen and hydrogen gases, the production of H2 gas from water, and the reduction of ketones to form alcohols.
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3.发明公开ELECTRON ACCEPTOR COMPOSITIONS ON POLYMER TEMPLATES AND CATALYTIC PRODUCTION OF HYDROGEN PEROXIDE 失效电子受体组合物在聚合物模板和催化剂生产过氧化氢
公开(公告)号：EP0846082A2
公开(公告)日：1998-06-10
申请号：EP95944612.0
申请日：1995-12-27
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Joshi, Vijay , Vermeulen, Lori Ann , Tang, Xiaozhang
发明人： THOMPSON, Mark, E. , SNOVER, Jonathan, Lee , JOSHI, Vijay , VERMEULEN, Lori, Ann , TANG, Xiaozhang
IPC分类号： C07F7 , B01J23 , B01J29 , B01J31 , B01J35 , B01J37 , C01B3 , C01B15 , C07C2 , C07F9 , C08F8 , C08F30 , B01J21 , C08F230
CPC分类号： C08F30/04 , B01J21/08 , B01J23/40 , B01J23/42 , B01J31/1658 , B01J31/1691 , B01J31/185 , B01J31/189 , B01J35/0013 , B01J35/004 , B01J35/006 , B01J37/0209 , B01J37/30 , B01J2231/62 , B01J2231/645 , B01J2231/70 , B01J2531/48 , B01J2531/824 , B01J2531/828 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/02 , C08F8/40 , C08F8/44 , C08F30/02 , C08F230/02 , C08F230/04 , Y02E60/364 , Y02P20/134 , Y10T292/702 , Y10T428/31504 , Y10T428/31678 , C08F26/06
摘要： Multi-layered compositions having a plurality of pillared metal complexes disposed on a supporting substrate, the pillars comprising divalent electron acceptor moieties with a phosphonate or arsenate at each end. Each layer of parallel pillars is separated by a layer of a group (IVA), (IVB), (IIIA) or (IIIB) metal or a lanthanide. The compositions can further comprise particles of at least one Group VIII metal at zero valence entrapped within each layer of the complex. The complexes can also incorporate 'stalactites' and 'stalagmites' of capped arsonato or phosphonato ligands interspersed with the pillars providing a series of interstices about each electron accepting group. The supporting substrate can be comprised of an organic polymer template. The complexes are useful for the conversion and storage of solar energy and as catalysts for reduction reactions, for example, the production of hydrogen peroxide from oxygen and hydrogen gases, the production of H2 gas from water, and the reduction of ketones to form alcohols.
摘要翻译： 多层组合物，其具有设置在支撑基材上的多个柱状金属络合物，所述柱包含二价电子受体部分，每个末端具有膦酸盐或砷酸盐。 平行柱的每一层由组（IVA），（IVB），（IIIA）或（IIIB）金属或镧系元素的层分隔开。 该组合物可以进一步包含截留在络合物的每一层内的至少一种零价的第VIII族金属的颗粒。 这些配合物还可以结合散布在支柱上的加盖的配体或膦酸盐配体的“钟乳石”和“石笋”，为每个受电子基团提供一系列空隙。 支撑基底可以由有机聚合物模板组成。 这些配合物可用于太阳能的转化和储存以及用作还原反应的催化剂，例如从氧气和氢气中生产过氧化氢，从水中生产H2气，以及还原酮形成醇。
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4.发明授权ELECTRON ACCEPTOR COMPOSITIONS ON POLYMER TEMPLATES AND CATALYTIC PRODUCTION OF HYDROGEN PEROXIDE 失效ELEKTRONENAKZEPTORZUSAMMENSETZUNGEN ON聚合物基质气的催化生产
公开(公告)号：EP0846082B1
公开(公告)日：2003-10-08
申请号：EP95944612.1
申请日：1995-12-27
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Joshi, Vijay , Vermeulen, Lori Ann , Tang, Xiaozhang
发明人： THOMPSON, Mark, E. , SNOVER, Jonathan, Lee , JOSHI, Vijay , VERMEULEN, Lori, Ann , TANG, Xiaozhang
CPC分类号： C08F30/04 , B01J21/08 , B01J23/40 , B01J23/42 , B01J31/1658 , B01J31/1691 , B01J31/185 , B01J31/189 , B01J35/0013 , B01J35/004 , B01J35/006 , B01J37/0209 , B01J37/30 , B01J2231/62 , B01J2231/645 , B01J2231/70 , B01J2531/48 , B01J2531/824 , B01J2531/828 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/02 , C08F8/40 , C08F8/44 , C08F30/02 , C08F230/02 , C08F230/04 , Y02E60/364 , Y02P20/134 , Y10T292/702 , Y10T428/31504 , Y10T428/31678 , C08F26/06
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公开(公告)号：EP0713492B1
公开(公告)日：2001-07-18
申请号：EP94925164.9
申请日：1994-08-09
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Vermeulen, Lori Ann
CPC分类号： C08F30/04 , B01J21/08 , B01J23/42 , B01J31/1691 , B01J31/185 , B01J35/0013 , B01J37/0209 , B01J2231/645 , B01J2531/48 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/44 , C08F30/02 , C08F230/02 , C08F230/04 , Y02E60/364 , Y02P20/134 , Y10T428/31504
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公开(公告)号：EP0713492A1
公开(公告)日：1996-05-29
申请号：EP94925164.0
申请日：1994-08-09
申请人： THE TRUSTEES OF PRINCETON UNIVERSITY , Thompson, Mark E. , Snover, Jonathan Lee , Vermeulen, Lori Ann
IPC分类号： C07F7 , B01J23 , B01J29 , B01J31 , B01J35 , B01J37 , C01B3 , C01B15 , C07C2 , C07F9 , C08F8 , C08F30 , B01J21 , C08F230
CPC分类号： C08F30/04 , B01J21/08 , B01J23/42 , B01J31/1691 , B01J31/185 , B01J35/0013 , B01J37/0209 , B01J2231/645 , B01J2531/48 , C01B3/042 , C01B15/029 , C07F9/581 , C08F8/44 , C08F30/02 , C08F230/02 , C08F230/04 , Y02E60/364 , Y02P20/134 , Y10T428/31504
摘要： Stable electron acceptor compositions are composed of a plurality of pillared metal complexes disposed on a supporting substrate. At least one Group VIII metal at zero valence is entrapped within this matrix. The complexes comprise from one to about 100 units of the formula: -(Y1O3-Z-Y2O3)Me?1-, Y1 and Y2¿ being phosphorus or arsenic; Z being a divalent group which reversibly forms a stable reduced form and contains two conjugated cationic centers having a negative E°¿red? value; and Me?1¿ being a trivalent or tetravalent metal of Group III, IVA, or IVB having an atomic number of a least 21 or a lanthanide. The units are bound to the substrate through a divalent linking group. Counter anions balance the charge of Z. The compositions can be used in the decomposition of water to yield hydrogen gas, the sensing of oxygen, and as catalysts.
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