PROCESS AND PLANT FOR PRODUCING HYDROGEN USING HYDROGEN BROMIDE ELECTROLYSIS

    公开(公告)号:EP4311867A1

    公开(公告)日:2024-01-31

    申请号:EP22186624.7

    申请日:2022-07-25

    摘要: A process for producing hydrogen comprises the following steps:
    a) providing a starting mixture containing bromine, water and a sulfur containing compound,
    b) reacting the starting mixture provided in step a) so as to produce a reaction mixture effluent comprising sulfuric acid and hydrogen bromide,
    c) separating the reaction mixture effluent obtained in step b) into one or more hydrogen bromide enriched compositions and into one or more sulfuric acid enriched compositions, wherein at least one hydrogen bromide enriched composition contains at most 1,000 ppm of sulfuric acid,
    d) subjecting at least a portion of the at least one hydrogen bromide enriched composition containing at most 1,000 ppm of sulfuric acid obtained in step c) to an electrolysis so as to obtain hydrogen and a bromine containing composition, and
    e) recycling at least a portion of the bromine containing composition obtained in step d) back to step a).

    A PROCESS FOR REMOVING SULFUR CONTAINING COMPOUNDS FROM GAS CONTAINING AT LEAST ONE SULFUR CONTAINING COMPOUND

    公开(公告)号:EP4311807A1

    公开(公告)日:2024-01-31

    申请号:EP22186635.3

    申请日:2022-07-25

    摘要: A process for removing at least a sulfur containing compound from gas containing at least one sulfur containing compound, wherein the process comprises the following steps:
    a) contacting a gas stream containing at least one sulfur containing compound with a stream containing bromine and water so as to obtain a starting stream,
    b) reacting the starting stream provided in step a) so as to produce a reaction mixture effluent comprising sulfuric acid and hydrogen bromide,
    c) separating the reaction mixture effluent obtained in step b) into one or more hydrogen bromide enriched compositions and into one or more sulfuric acid enriched compositions,
    d) subjecting at least a portion of the at least one hydrogen bromide enriched composition obtained in step c) to a treatment, in which at least a portion of the hydrogen bromide enriched composition is converted to bromine,
    e) recycling at least a portion of the bromine containing composition obtained in step d) back to step a), and
    f) withdrawing gas, which is depleted in the at least one sulfur containing compound.