A PROCESS FOR THE REMOVAL OF METAL CONTAMINANTS FROM FLUIDS
    1.
    发明公开
    A PROCESS FOR THE REMOVAL OF METAL CONTAMINANTS FROM FLUIDS 审中-公开
    VERFAHREN ZUR ENTFERNUNG VON METALLISCHEN VERUNREINIGUNGEN AUSFLÜSSIGKEITEN

    公开(公告)号:EP3010637A4

    公开(公告)日:2017-02-22

    申请号:EP14812933

    申请日:2014-06-17

    申请人: RELIANCE IND LTD

    IPC分类号: B01J20/08 B01D53/58

    摘要: The present disclosure provides a process for removing metal contaminants from a contaminated fluid stream comprising the step of contacting said fluid stream with macroporous alpha alumina to obtain a fluid stream containing less than 50 ppm of metal. The fluid stream can be selected from the group consisting of a stream of mineral acid(s) and a stream of alkylene(s); and the metal contaminant can be at least one of elemental metals and metal oxides. The process further comprises a step of obtaining spent macroporous alpha alumina and regenerating active macroporous alpha alumina therefrom by washing said spent macroporous alpha alumina with at least one purified stream selected from the group consisting of a stream of mineral acid(s) and a stream of alkylene(s).

    摘要翻译: 本公开提供了从污染流体物流中除去金属污染物的方法,包括使所述流体物流与大孔α氧化铝接触以获得含有少于50ppm金属的流体物流的步骤。 流体物流可以选自无机酸流和亚烷基物流; 并且金属污染物可以是元素金属和金属氧化物中的至少一种。 该方法还包括通过用至少一种纯化流洗涤所述用过的大孔α氧化铝,从而获得用过的大孔α氧化铝并再生活性大孔α氧化铝的步骤,所述净化流选自无机酸流和 亚烷基(一个或多个)。

    REMOVAL OF BROMINE FROM GASEOUS HYDROGEN BROMIDE
    3.
    发明公开
    REMOVAL OF BROMINE FROM GASEOUS HYDROGEN BROMIDE 审中-公开
    溴的从气态溴化氢去除

    公开(公告)号:EP2855350A1

    公开(公告)日:2015-04-08

    申请号:EP13727761.2

    申请日:2013-05-24

    IPC分类号: C01B7/09 C07C17/093

    摘要: Processes of and systems for removing free bromine from gaseous anhydrous HBr contaminated with free bromine are described. In one type of process the gaseous contaminated HBr is fed into countercurrent contact with at least one liquid alkylaromatic hydrocarbon within a packed section of a column while maintaining the packed section under free radical bromination conditions so that one or more than one liquid a-bromoalkylaromatic compound is produced along with one mole of gaseous HBr per mole of a-bromoalkylaromatic compound produced. In another type of process the gaseous anhydrous HBr is fed into countercurrent contact through at least two scrubbers so that the gaseous anhydrous HBr is scrubbed substantially free of bromine by passage through these at least two scrubbers, each of which contains a different specified type of scrubbing liquid. In one embodiment the liquid alkylaromatic hydrocarbon comprises 1,2-diphenylethane.

    A PROCESS FOR PURIFYING HBr IN HYDROCARBONS
    10.
    发明公开
    A PROCESS FOR PURIFYING HBr IN HYDROCARBONS 审中-公开
    VERFAHREN ZUR AUFREINIGUNG VON HBR在KOHLENWASSERSTOFFEN

    公开(公告)号:EP2147908A1

    公开(公告)日:2010-01-27

    申请号:EP08733968.5

    申请日:2008-04-14

    摘要: The present invention provides a method for separating HBr from HBr-containing hydrocarbons (alkenes, aromatics and/or alkanes) to purify the hydrocarbons. Reacting a silica supported metal oxide solid material (MO x /SiO 2 , MO x =MgO, CoO, Co 2 O 3 , CuO and mixture thereof) with HBr in HBr-containing hydrocarbons, so as to ensure that the concentration of HBr is reduced to below 1.87×10 -16 , and then oxidizing the solid material which reacted with HBr in oxygen or air to regenerate MO x /SiO 2 , meanwhile Br 2 is recycled. Therefore, the purpose of continuous purification of hydrocarbons can be achieved.

    摘要翻译: 本发明提供了将HBr与含HBr的烃(烯烃,芳烃和/或烷烃)分离以净化烃的方法。 在含HBr的烃中与HBr反应二氧化硅负载的金属氧化物固体材料(MO x / SiO 2,MO x = MgO,CoO,Co 2 O 3,CuO及其混合物),以确保HBr的浓度为 降低至1.87×10 -16以下,然后氧化与氧气或空气中的HBr反应的固体物质再生MO x / SiO 2,同时将Br 2回收利用。 因此,可以实现连续净化烃的目的。