摘要:
A high power lithium-ion secondary battery having an increased capacity and capable of maintaining high discharge voltage and repeating charging/discharging high current. A lithium-ion secondary battery having; an electrode group formed by laminating or winding a negative electrode layer and a positive electrode layer so as to interpose a separator made of synthetic resin, the negative electrode layer containing a material capable of intercalating/deintercalating lithium-ion, and a positive electrode layer including a lithium-containing metallic oxide; and a non-aqueous electrolyte containing lithium salt, where the electrode group is immersed. The positive electrode material unit contains a fluorinated lithium-containing metallic oxide as a main material, and the separator possesses a hydrophilic group. Further, the positive electrode material preferably contains a main material including LiNi x Co y Mn z O 2 , where 0.4 ≤ x ≤ 1,0≤ y ≤ 0.2, 0 ≤ z 0.2, x + y + z = 1.
摘要翻译:一种高功率锂离子二次电池,其具有增加的容量并且能够保持高放电电压并且重复充电/放电高电流。 一种锂离子二次电池,具有: 通过层叠或卷绕负极层和正极层形成的电极组,以便插入由合成树脂制成的隔板,所述负极层含有能够嵌入/脱嵌锂离子的材料,以及包括 含锂金属氧化物; 和含有锂盐的非水电解质,浸渍电极组。 正极材料单元包含含氟的含锂金属氧化物作为主要材料,并且隔膜具有亲水基团。 此外,正极材料优选含有包括LiNi x Co y Mn z O 2的主要材料,其中0.4‰x‰1.0‰y‰0.2,0‰z 0.2,x + y + z = 1。
摘要:
A separator of the present invention for a nonaqueous electrolyte secondary battery is obtained by fluorinating a polyolefin based resin. A contact angle of the separator with a nonaqueous solvent electrolyte is 40° or less a shutdown temperature of the separator is 170°C or less. Further, a multilayered separator of the present invention for a nonaqueous electrolyte secondary battery includes a plurality of layers, at least one of which is the foregoing separator for a nonaqueous electrolyte secondary battery. These separators for nonaqueous electrolyte secondary battery have both a favorable electrolyte-retaining characteristic and a suitable shutdown performance.
摘要:
Provided is positive electrode material for a highly safe lithium-ion secondary battery that can charge and discharge a large current while having long service life. Disclosed are composite particles comprising: particles of lithium-containing phosphate; and carbon coating comprising at least one carbon material selected from the group consisting of (i) fibrous carbon material, (ii) chain-like carbon material, and (iii) carbon material produced by linking together fibrous carbon material and chain-like carbon material, wherein each particle is coated with the carbon coating. The fibrous carbon material is preferably a carbon nanotube with an average fiber size of 5 to 200 nm. The chain-like carbon material is preferably carbon black produced by linking, like a chain, primary particles with an average particle size of 10 to 100 nm. The lithium-containing phosphate is preferably LiFePO 4 , LiMnPO 4 , LiMn X Fe (1-X) PO 4 , LiCoPO 4 , or Li 3 V 2 (PO 4 ) 3 .
摘要:
The present invention provides a method for producing a lithium secondary battery in which peeling of an active substance can be prevented and the generation of metal powder canbe prevented when a power collection foil is processed at an electrode production step. The method for producing the lithium secondary battery includes an electrode-producing step of producing a positive electrode and a negative electrode; a step of forming a group of electrodes by layering the positive electrode and the negative electrode on each other through a separator, or winding the positive electrode and the negative electrode through a separator; and a step of immersing the group of the electrodes in an electrolyte. The electrode-producing step has a boring step of forming a plurality of through-holes penetrating a power collection foil and having projected parts projected from at least a rear surface of the power collection foil and a mixed agent-forming step of forming a mixed agent layer on the power collection foil through which the through-holes have been formed. After the boring step finishes, the mixed agent-forming step is successively performed without winding the power collection foil through which the through-holes have been formed.
摘要:
The present invention provides an electrode material, for a lithium battery, which is capable of achieving a high-energy density and a high output and continuing its properties for many years, a method of producing the electrode material, and the lithium battery. The electrode material for use in positive and negative electrodes of a lithium battery is formed as a complex by combining a carbon-based conductive material and an electrode active material with each other. The carbon-based conductive material of the electrode material is subjected to hydrophilic treatment by using a gas containing fluorine gas. The electrode material is formed as the complex by calcining a mixture of the carbon-based conductive material subjected to the hydrophilic treatment and the electrode active material in the presence of fluororesin.
摘要:
There is provided a method for producing an electrode material for a lithium-ion secondary battery. The method comprises the following steps: (a) mixing components of a basic ingredient or active substance of electrode material and a conductive carbon material to obtain a conductive carbon material-composited material; (b) mixing the conductive carbon material-composited material and a surface layer-forming material; an (c) burning the mixture obtained at step (b) to obtain the electrode material. Also, there is provided a lithium-ion secondary battery comprising an electrode which comprises the material according to the invention.
摘要:
The present invention provides a negative-electrode material for a lithium secondary battery which has a very low resistance, allows the lithium secondary battery to be charged and discharged (high output) at a high current and have a high capacity, and achieve a cycle life to such an extent that the lithium secondary battery can be mounted on a vehicle. The electrode material is composed of (a) at least one active substance (4) selected from among a metal oxide containing metal therein and an alloy material each of which is coated with a carbon material and has a graphene phase or an amorphous phase (8) on at least a surface thereof, (b) a graphite-based carbon material (5) having the graphene phase or the amorphous phase on at least a surface thereof; and (c) carbon material (6) other than the graphite-based carbon material and having the graphene phase or the amorphous phase on at least a surface thereof. The active substance (4), the graphite-based carbon material (5), and the carbon material (6) other than the graphite-based carbon material fuse the graphene phase or the amorphous phase (8a, 8b) thereof together and bond them to each other to form a composite active substance (7) including composed of the active substance including one active substance selected from among the metal oxide containing the metal and the alloy material
摘要:
The present invention provides positive and negative electrodes, for a lithium secondary battery, allowing a battery to be quickly and fully charged in a very short period of time, for example, within one minute and allowing the battery to be used for vehicles at low temperatures. An organic electrolytic solution is permeated into an electrode group formed by winding positive and negative electrodes or by laminating the positive and negative electrodes one upon another with a separator being interposed therebetween to repeatingly occlude and release lithium ions. The positive electrode active substance and the negative electrode active substance have at least one phase selected from among a graphene phase and an amorphous phase as a surface layer thereof. An activated carbon layer is formed on a surface of the positive electrode active substance and that of the negative electrode active substance. An activated carbon layer having a specific surface area not less than 1000m 2 /g is formed on a surface of the positive electrode active substance and that of the negative electrode active substance.