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1.发明公开Hydrogenation catalyst composition and hydrogenation method thereof 有权Hydrierungskatalysatorzusammensetzung und Hydrierungsverfahrendafür
公开(公告)号：EP2316862A1
公开(公告)日：2011-05-04
申请号：EP10165616.3
申请日：2010-06-11
申请人： TSRC Corporation
CPC分类号： C08C19/02
摘要： A hydrogenation catalyst composition for hydrogenating a polymer of conjugated diene is provided. The polymer of conjugated diene is a homopolymer of conjugated diene or a copolymer of conjugated diene and vinyl aromatics. The hydrogenation catalyst composition includes: (a) a titanium compound, (b) a compound of formula (II),
where R 5 is C 1 -C 12 alkyl, alkenyl, amine, ether, ketone or ester groups, R 3 and R 6 are C 1 -C 12 alkyl or alkenyl groups, R 4 and R 7 are C 1 ∼C 12 alkyl, alkenyl, amine, ether, ketone or ester groups, n and m are integrals, 1≦ n≦ 3, 1≦ m≦ 3, and (c) alkyl aluminum.摘要翻译： 提供用于氢化共轭二烯的聚合物的氢化催化剂组合物。 共轭二烯的聚合物是共轭二烯的均聚物或共轭二烯和乙烯基芳烃的共聚物。 氢化催化剂组合物包括：（a）钛化合物，（b）式（II）化合物，其中R 5是C 1 -C 12烷基，烯基，胺，醚，酮或酯基，R 3和R 6是C 1 -C 12烷基或烯基，R 4和R 7是C 1 -C 12烷基，烯基，胺，醚，酮或酯基，n和m是整数，1‰| n‰| 3,1 ‰| m‰| 3，（c）烷基铝。
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2.发明公开Coupled polymers and manufacturing method thereof 有权Gekoppelte Polymere und Herstellungsverfahrendafür
公开(公告)号：EP2272878A1
公开(公告)日：2011-01-12
申请号：EP10163369.1
申请日：2010-05-20
申请人： TSRC Corporation
CPC分类号： C08C19/02 , C08C19/44 , C08F36/04 , C08F236/10 , C08F297/023 , C08L15/00 , C08F4/48
摘要： A coupled copolymer is provided. The coupled copolymer is coupled by reacting a silane coupling agent with a copolymer, where the copolymer is polymerized by a conjugated diene monomer and a vinyl aromatics monomer, and the silane coupling agent has an alkenyl group and a alkoxy group, and has a chemical Formula (I) as follows:
where R 1 and R 4 are alkyl groups; R 3 is a group having an alkenyl group; R 5 is one of an alkyl and an alkenyl groups; q is one of "1" and "0"; when q = 0, then k = j = 0, 1≦ n≦ 3, 0≦ m≦ 2, m+n = 3, and R 2 is alkoxy group; and when q = 1, then k+j = 3, R 2 is -(CH 2 ) r , r = 1-6 and m+n = 3.摘要翻译： 提供了一种偶联共聚物。 通过使硅烷偶联剂与共聚物反应而使共轭共聚物通过共轭二烯单体和乙烯基芳香族单体聚合而偶联，硅烷偶联剂具有烯基和烷氧基，并具有化学式 （I）如下：其中R 1和R 4是烷基; R 3为具有烯基的基团; R 5是烷基和链烯基之一; q是“1”和“0”之一; 当q = 0时，k = j = 0，1‰| n‰| 3，0‰| m‰| 2，m + n = 3，R 2为烷氧基; 当q = 1时，则k + j = 3，R 2为 - （CH 2）r，r = 1-6，m + n = 3。
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公开(公告)号：EP2316862B1
公开(公告)日：2013-12-25
申请号：EP10165616.3
申请日：2010-06-11
申请人： TSRC Corporation
CPC分类号： C08C19/02
摘要： A hydrogenation catalyst composition for hydrogenating a polymer of conjugated diene is provided. The polymer of conjugated diene is a homopolymer of conjugated diene or a copolymer of conjugated diene and vinyl aromatics. The hydrogenation catalyst composition includes: (a) a titanium compound, (b) a compound of formula (II), where R 5 is C 1 -C 12 alkyl, alkenyl, amine, ether, ketone or ester groups, R 3 and R 6 are C 1 -C 12 alkyl or alkenyl groups, R 4 and R 7 are C 1 ˆ¼C 12 alkyl, alkenyl, amine, ether, ketone or ester groups, n and m are integrals, 1‰¦ n‰¦ 3, 1‰¦ m‰¦ 3, and (c) alkyl aluminum.
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公开(公告)号：EP2272878B1
公开(公告)日：2013-12-18
申请号：EP10163369.1
申请日：2010-05-20
申请人： TSRC Corporation
CPC分类号： C08C19/02 , C08C19/44 , C08F36/04 , C08F236/10 , C08F297/023 , C08L15/00 , C08F4/48
摘要： A coupled copolymer is provided. The coupled copolymer is coupled by reacting a silane coupling agent with a copolymer, where the copolymer is polymerized by a conjugated diene monomer and a vinyl aromatics monomer, and the silane coupling agent has an alkenyl group and a alkoxy group, and has a chemical Formula (I) as follows: where R 1 and R 4 are alkyl groups; R 3 is a group having an alkenyl group; R 5 is one of an alkyl and an alkenyl groups; q is one of "1" and "0"; when q = 0, then k = j = 0, 1‰¦ n‰¦ 3, 0‰¦ m‰¦ 2, m+n = 3, and R 2 is alkoxy group; and when q = 1, then k+j = 3, R 2 is -(CH 2 ) r , r = 1-6 and m+n = 3.
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