摘要:
A porous carbon that has an extremely high specific surface area while being crystalline, and a method of manufacturing the porous carbon are provided. A porous carbon has mesopores 4 and a carbonaceous wall 3 constituting an outer wall of the mesopores 4, wherein the carbonaceous wall 3 has a portion forming a layered structure. The porous carbon is fabricated by mixing a polyamic acid resin 1 as a carbon precursor with magnesium oxide 2 as template particles; heat-treating the mixture in a nitrogen atmosphere at 1000°C for 1 hour to cause the polyamic acid resin to undergo heat decomposition; washing the resultant sample with a sulfuric acid solution at a concentration of 1 mol/L to dissolve MgO away; and heat-treating the noncrystalline porous carbon in a nitrogen atmosphere at 2500°C.
摘要:
A purification method for a carbon material containing carbon nanotubes is provided, which satisfies the following requirements: The method should prevent carbon nanotubes from being damaged, broken or flocculated; the method should be capable of removing the catalyst metal and carbon components other than the carbon nanotubes; and the method should be applicable to not only multi-walled carbon nanotubes but also single-walled carbon nanotubes which will undergo significant structural changes when heated to 1400°C or higher temperatures. The method is characterized by including a carbon material preparation process for preparing a carbon material containing carbon nanotubes by an arc discharge method, using an anode made of a material containing at least carbon and a catalyst metal; and a halogen treatment process for bringing the carbon material into contact with a gas containing a halogen and/or halogen compound.
摘要:
An object is to provide a graphite-copper composite electrode material that is capable of reducing electrode wear to a practically usable level and to provide an electrical discharge machining electrode using the material. A graphite-copper composite electrode material includes a substrate comprising a graphite material and having pores, and copper impregnated in the pores of the substrate, the electrode material having an electrical resistivity of 2.5 µΩm or less, preferably 1.5 µΩm or less, more preferably 1.0 µΩm or less. It is desirable that the substrate comprising the graphite material have an anisotropy ratio of 1.2 or less. It is desirable that an impregnation rate ϕ of the copper in the electrode material is 13% or greater. It is desirable that the substrate comprising the graphite material have a bulk density of from 1.40 Mg/m 3 to 1.85 Mg/m 3 .
摘要翻译:本发明的目的是提供一种石墨 - 铜复合电极材料,其能够将电极磨损降低到实际可用的水平,并提供使用该材料的放电加工电极。 石墨 - 铜复合电极材料包括含有石墨材料并具有孔隙的基底和浸渍在基底孔中的铜,该电极材料的电阻率为2.5微米或更小,优选为1.5微米或更小 ,更优选为1.0μm以下。 希望包含石墨材料的基板的各向异性比为1.2以下。 希望电极材料中铜的浸渍率为13%以上。 希望包含石墨材料的基材的堆积密度为1.40Mg / m 3至1.85Mg / m 3。
摘要:
There is obtained a carbon material for lithium-ion secondary battery negative electrode, a low-crystalline carbon impregnated carbon material for lithium-ion secondary battery negative electrode, a negative electrode plate, and a lithium-ion secondary battery, each of which realizes a first charge/discharge cycle with less gas generation and provides a rapid charge/discharge. The carbon material is obtained by: blending and kneading a carbonaceous aggregate with a binder to form a composition; press molding the composition into an article; carbonizing the press molded article; graphitizing the article to obtain an artificial graphite block; milling the block; and carrying out particle size control. The carbon material has characteristics of: (1) R-value = (I 1360 /I 1580 ) ≥ 0.2, where R-value is defined by the ratio of D band to G band in Raman spectrum using Nd: YAG laser light of 532 nm wavelength; and (2) d(002) ≥ 0.336nm, and Lc(002) ≤ 50 nm, where d(002) and Lc(002) are crystallographic parameters calculated by Gakushin-method. The carbon material is used for the negative electrode plate of a lithium-ion secondary battery, and used in the lithium-ion secondary battery having therein the negative electrode plate.
摘要:
A lithium ion secondary cell anode, wherein carbon material including graphite having a d 002 of not more than 0.3370nm of X-ray parameters that can be obtained from the Gakushin-method for X-ray diffraction of carbon is used as a part of an active material, and a macromolecular material having a surface energy γ S of not less than 30mJm -2 is used as a binder.