摘要:
A fuel cell having an excellent life property is achieved. A supported catalyst for a fuel cell includes a catalytic particle made of an alloy of platinum and gold, and a conductive carrier supporting the catalytic particle. 50% or more of gold forms a solid solution with platinum.
摘要:
A means of inhibiting the occurrence of overvoltage in an electrode catalyst for fuel cells so as to substantially prevent reduction of fuel cell performance includes an anode electrode catalyst for fuel cells, which contains a carbon support having at least one pore having a pore size of 10 nm or less and a pore volume of 1.1 to 8.4 cm 3 /g and catalyst particles having particle sizes of 3.1 nm or less and supported by the carbon support so that the density of supported catalyst particles is 15% to 40% by mass.
摘要:
PROBLEM TO BE SOLVED: To provide means for substantially increasing catalyst activity and/or increasing gas distribution in carbon carriers to substantially prevent the increase in fuel cell gas diffusion resistance in connection with an electrode catalyst for a fuel cell.SOLUTION: The present invention relates to an electrode catalyst for a fuel cell, which comprises: carbon carriers having pores; and catalyst particles including platinum or a platinum alloy and supported by the carbon carriers. The pores of the carbon carriers have a pore mode size in a range of 2.1-5.1 nm. As to the pores of the carbon carriers, the total pore volume is in a range of 21-35 cm/g. The distance between the catalyst particle and the surface of the carbon carriers is in a range of 2.0-12 nm, which is a distance at 50%-cumulative frequency.SELECTED DRAWING: Figure 1
摘要:
An electrode catalyst for fuel cells that can inhibit an increase in gas diffusion resistance includes a carbon material having a ratio of a peak intensity I A derived from an amorphous structure to a peak intensity I G derived from a graphite structure in an X-ray diffraction spectrum (ratio I A /I G ) of 0.90 or less as a catalyst-supporting carrier.
摘要:
The technology useful for the realization of a fuel cell that excels in not only the initial performance but also the post-endurance performance is provided. A supported catalyst for fuel cell includes a conductive carrier and platinum supported on the conductive carrier. A 90% particle diameter D 90 on a cumulative particle size curve obtained by determining a particle size distribution of the supported catalyst by a light scattering method is 28 µm or less.
摘要:
This invention is intended to improve the coverage of a platinum or platinum alloy surface with gold when producing a catalyst comprising carrier particles that support gold-modified platinum or platinum alloys. The invention provides a method for producing a catalyst comprising carrier particles that support gold-modified platinum or platinum alloys comprising a step of gold reduction comprising adding carrier particles that support platinum or platinum alloys, a reducing agent, and a gold precursor to a liquid medium and mixing the same, wherein the reducing agent is added to adjust the ORP value (i.e., an oxidation-reduction potential with reference to the silver-silver chloride electrode) of the liquid medium to -630 to +230 mV upon completion of addition.