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1.发明公开Fe(II)-SUBSTITUTED BETA-TYPE ZEOLITE, PRODUCTION METHOD THEREFOR AND GAS ADSORBENT INCLUDING SAME, AND NITRIC OXIDE AND HYDROCARBON REMOVAL METHOD 有权FE（II）取代的β沸石，METHOD THEREFOR，因而气体吸附材料的氮氧化物和烃的去除方法
公开(公告)号：EP2876086A1
公开(公告)日：2015-05-27
申请号：EP13820472.2
申请日：2013-07-16
CPC分类号： B01J20/18 , B01D53/02 , B01D53/04 , B01D53/9481 , B01D2253/108 , B01D2253/1085 , B01D2253/1122 , B01D2253/306 , B01D2253/311 , B01D2257/404 , B01D2257/702 , B01J20/186 , B01J20/28057 , B01J20/28071 , B01J20/3085 , B01J29/7615 , C01B39/02 , C01B39/46 , F01N3/0835 , F01N3/0842
摘要： The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO 2 /Al 2 O 3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO 2 /Al 2 O 3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.
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2.发明授权Fe(II)-SUBSTITUTED BETA-TYPE ZEOLITE, PRODUCTION METHOD THEREFOR AND GAS ADSORBENT INCLUDING SAME, AND NITRIC OXIDE AND HYDROCARBON REMOVAL METHOD 有权FE（II）取代的β沸石，METHOD THEREFOR，因而气体吸附材料的氮氧化物和烃的去除方法
公开(公告)号：EP2876086B1
公开(公告)日：2016-09-14
申请号：EP13820472.2
申请日：2013-07-16
CPC分类号： B01J20/18 , B01D53/02 , B01D53/04 , B01D53/9481 , B01D2253/108 , B01D2253/1085 , B01D2253/1122 , B01D2253/306 , B01D2253/311 , B01D2257/404 , B01D2257/702 , B01J20/186 , B01J20/28057 , B01J20/28071 , B01J20/3085 , B01J29/7615 , C01B39/02 , C01B39/46 , F01N3/0835 , F01N3/0842
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公开(公告)号：EP2837596A1
公开(公告)日：2015-02-18
申请号：EP13775736.5
申请日：2013-04-09
发明人： ITABASHI Keiji , OKUBO Tatsuya , IYOKI Kenta
IPC分类号： C01B39/46
CPC分类号： C01B39/46 , B01D2253/1085 , B01D2253/306 , B01D2253/31 , B01D2255/502 , B01D2255/9202 , B01D2258/012 , B01D2258/014 , B01J20/18 , B01J20/28057 , B01J20/28071 , B01J20/28083 , B01J29/7007 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J39/04 , C01B39/06 , C01P2006/12 , C01P2006/16 , Y10T428/2982
摘要： The present invention provides a beta zeolite that is useful as a catalyst, adsorbent agent, or the like, and that is both microporous and mesoporous. The beta zeolite is characterized by (i) the SiO 2 /Al 2 O 3 ratio being 8-30, and the SiO 2 /ZnO ratio being 8-1000, (ii) the micropore surface area being 300-800 m 2 /g, (iii) the micropore volume being 0.1-0.3 cm 3 /g, and (iv) having mesopores having, in the state as synthesized, a diameter of 2-6 nm and a volume of 0.001-0.3 cm 3 /g. The beta zeolite is favorably produced by means of adding and reacting a zinc silicate beta zeolite as a seed crystal with a reaction mixture containing a silica source, an alumina source, an alkali source, and water.
摘要翻译： 本发明提供了可用作催化剂，吸附剂等的β沸石，既是微孔的又是介孔的。 β沸石的特征在于（i）SiO 2 / Al 2 O 3比为8-30，SiO 2 / ZnO比为8-1000，（ii）微孔表面积为300-800m 2 / g ，（iii）微孔体积为0.1-0.3cm 3 / g，（iv）具有在合成状态下具有2-6nm直径和0.001-0.3cm 3 / g体积的介孔。 β沸石通过将硅酸锌β沸石作为晶种与含有二氧化硅源，氧化铝源，碱源和水的反应混合物加入和反应而有利地产生。
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公开(公告)号：EP2837596B1
公开(公告)日：2016-05-18
申请号：EP13775736.5
申请日：2013-04-09
发明人： ITABASHI Keiji , OKUBO Tatsuya , IYOKI Kenta
CPC分类号： C01B39/46 , B01D2253/1085 , B01D2253/306 , B01D2253/31 , B01D2255/502 , B01D2255/9202 , B01D2258/012 , B01D2258/014 , B01J20/18 , B01J20/28057 , B01J20/28071 , B01J20/28083 , B01J29/7007 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J39/04 , C01B39/06 , C01P2006/12 , C01P2006/16 , Y10T428/2982
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公开(公告)号：EP3527535A1
公开(公告)日：2019-08-21
申请号：EP17859495.8
申请日：2017-10-11
摘要： Provided is a mordenite zeolite which can be produced without using an organic structure-directing agent, and has superior multivalent metal cation exchange capability. The mordenite zeolite according to the present invention containing silicon, a divalent metal M and aluminum in a skeletal structure, wherein the mordenite zeolite has the following atomic ratios in the state of Na-form. The mordenite zeolite preferably has a BET surface area of 250 m 2 /g or more and 500 m 2 /g or less and a micropore volume of 0.07 cc/g or more and 0.25 cc/g or less in the state of Na-form or H-form. Si/(M + Al) = 5 or more and 10 or less, M/(M + Al)= 0.1 or more and less than 1, and Na/(M + Al) = 1 or more and less than 2
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公开(公告)号：EP3006915A1
公开(公告)日：2016-04-13
申请号：EP14804477.9
申请日：2014-05-26
IPC分类号： G01N1/28 , G01N1/22 , G01N30/00 , G01N30/88 , G01N33/497
CPC分类号： A61B5/443 , A61B5/14542 , A61B5/441 , A61B2010/0083 , G01N33/497 , G01N2030/062
摘要： A skin gas measurement device includes a skin gas collecting unit that includes a skin gas collecting space having an opening that is to be attached to a skin surface, a porous material that is for adsorbing and concentrating a skin gas component that is emitted from the skin surface into the skin gas collecting space and that allows the adsorbed skin gas component to be desorbed at a relatively low temperature, and a heater for heating the porous material; and a skin gas measurement unit for measuring the skin gas component that is desorbed from the heated porous material.
摘要翻译： 本发明提供一种皮肤气体测定装置，其具备：皮肤气体收集部，其具有皮肤气体收集空间，该皮肤气体收集空间具有用于安装于皮肤表面的开口部;多孔性材料，其用于吸收并浓缩从皮肤放射的皮肤气体成分 表面进入皮肤气体收集空间并且允许吸附的皮肤气体组分在相对较低的温度下解吸并且用于加热多孔材料的加热器; 以及皮肤气体测量单元，用于测量从加热的多孔材料解吸的皮肤气体成分。
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