摘要:
According to the invention, said material is characterized in that it contains, as an positive electrode active material, at least one iron and alkali sulfate in which the iron is in the +II oxidation state and which has the formula (Na 1-a Li b ) x Fe y (SO 4 ) z (I), where the subscripts a, b, x, y and z are selected so as to ensure the electroneutrality of the compound, with 0 2 Fe 2 (SO 4 ) 3 . The invention is useful, in particular, as a positive electrode material in an alkali-ion battery.
摘要:
The invention relates to a method for producing a battery using A + (Li + or Na + ) as an electrochemical carrier, as well as to the resulting batteries. The method involves assembling together a negative electrode, a positive electrode, and an electrolyte, and then exposing the assembly to a first charge at the operating temperature of the battery. The electrolyte is a ceramic or a solution of an A+ salt in a polar liquid, a polymer, or the mixtures thereof. The active material of the negative electrode is a material which has a redox couple, the potential of which is 0 V to 1.6 V relative to the A + /Aº couple. The active material of the positive electrode is a material which has a redox couple, the potential of which is higher than that of the couple of the negative electrode. The positive electrode used during assembly consists of a current collector having a composite material which contains the positive active material and at least one sacrificial salt of a cation E + selected from among Li + , Na + , K + and the onium cations, and a redox anion selected from among azide anions, ketocarboxylate anions, and hydrazide anions optionally in the form of a polymer.
摘要:
the invention relates to compounds (I) A a M m (YO4) y Z z (I) where A is at least one element selected from the alkaline metals, alkaline earth metals, a doping element and a hole, M being (T1-1TV), T being one or more transition metals and T' being at least on element selected from Mg, Ca, Al, and the rare earths, 0≤t O; y>0; z ≥ O. The compounds (I) are obtained from precursors of the constituent elements by means of a method comprising the following steps: dispersion of said precursors in a liquid support comprising one or more ionic liquids made up of a cation and an anion the electric charges of which balance out to give a suspension of said precursors in said liquid, heating said suspension to a temperature of 25 to 380°C and separation of said ionic liquid and the inorganic oxide of formula (I) from the reaction of said precursors.
摘要:
The invention relates to boron or aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ion components. The complexes have one of the following formulas: (I, II, III, IV, V, and VI) wherein D is B or Al; R 1 is R, R F , NO 2 , CN, C(=O)OR, RSO 2 , or R F SO 2 ; X 1 , X 2 , X 3 , and X 4 each is a divalent group >C=O, >C=NC N, >C=C(C N) 2 , >CR 2 R 3 , or >SO 2 ; Y 1 , Y 2 , and Y 3 , each is a divalent group –O-, >N(C N), >N(COR F ), >N(SO 2 R 4 ), >NR 4 , >N(COR 4 ), or >N(SO 2 R F ); R 1 , R 2 , and R 3 , each is H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group, or an alkenyl group; R 4 is an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group, or an R F CH 2 group; R F is a perfluoroalkyl group, partially fluoridated alkyl group, or a partially or totally fluoridated phenyl group; each of groups R’ 2 and R’ 3 is R or F.
摘要:
The present invention relates to a fluorinated material usable as an active electrode material, and to a method for producing same. A material of the present invention consists of particles of a fluorosulfate of formula (I): Li 1-y Fe 1-x Mn x SO 4 F (I), where 0