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    Production of optically pure organoboranes
    5.
    发明公开
    Production of optically pure organoboranes 失效
    生产光学有机物

    公开(公告)号：EP0188235A3

    公开(公告)日：1988-06-01

    申请号：EP86100239

    申请日：1986-01-10

    申请人： ALDRICH-BORANES, INC.

    发明人： Brown, Herbert C., Ph.D.

    IPC分类号： C07F05/02 ,  C07C29/50

    CPC分类号： C07C29/48 ,  C07B2200/07 ,  C07C35/06 ,  C07C35/08 ,  C07C35/30 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2602/42 ,  C07F5/025 ,  C07F5/027 ,  C07C31/12 ,  C07C31/125 ,  C07C33/20 ,  C07C35/18 ,  C07C35/29

    摘要： A process for upgrading to essentially 100% enantiomeric excess the optical purity of an organoborane intermediate represented by the formulae:
    wherein Icp is isopinocampheyl and R * is a unsubstituted or substituted, acyclic or cyclic alkyl having from 4 to 30 carbon atoms, comprising the steps of hydroborating cis- alkene, a trans-alkene or a tertiary-alkene with monoisopinocampheylborane or diisopinocampheylborane, obtaining a solid organoborane and recrystallizing the solid organoborane to obtain an enantiomeric excess of essentially 100% ee of said organoborane.

    摘要翻译： 将由下式表示的有机硼烷中间体的光学纯度升级至基本上100％对映异构体的方法：IcpBHR *或Icp2BR *，其中Icp是异蒎烯基，R *是未取代或取代的，无环或环状的具有4-30碳 包括以下步骤：将顺式烯烃，反式烯烃或叔丁烯与单取代蒎烷基硼烷或二异蒎烷基硼烷加成硼，得到固体有机硼烷并使固体有机硼烷重结晶，得到基本上100％ee的所述有机硼烷的对映体过量。

    Bornane-3-spiro-1'-cyclopentane derivatives and perfumery compositions containing them
    8.
    发明公开
    Bornane-3-spiro-1'-cyclopentane derivatives and perfumery compositions containing them 失效
    Abkömmlingevon Bornan-3-spiro-l'-cyclopan和diese enthaltende Riechstoffzusammensetzungen。

    公开(公告)号：EP0297510A2

    公开(公告)日：1989-01-04

    申请号：EP88110301.4

    申请日：1988-06-28

    申请人： Kao Corporation

    发明人： Fujikura, Yoshiaki ,  Kitsuki, Tomohito ,  Fujita, Manabu ,  Toi, Nao

    IPC分类号： C07C43/20 ,  C07C35/30 ,  C07C69/06 ,  C07C69/14 ,  A61K7/46

    CPC分类号： C07C35/30 ,  C07C43/18 ,  C11B9/0057

    摘要： The invention provides derivatives of bornane-3-spiro-­1′-cyclopentane with woody note scent useful as a base component in perfumery formulations which comprises those having a substituting group selected from a methoxyl, ethoxyl, formyloxyl and acetoxyl groups or two of substituting groups being either a hydroxyl group and a methyl group or a hydroxyl group and an ethyl group at the 2-position synthesized by any of the reactions of bornane-3-spiro-1′-cyclopentan-2-ol or bornane-3-spiro-1′-cyclopentan-2-one with any of the reagents selected in accordance with the substituting group(s) to be introduced.
    The invention also provides perfumery compositions containing the above.

    摘要翻译： 本发明提供了具有木香味香味的衍生物，其具有木香味香料，其可用作香料制剂中的基础组分，其包含具有选自甲氧基，乙氧基，甲酰氧基和乙酰氧基的取代基或两个取代基 在2-烷基-3-螺旋-1min - 环戊烷-2-醇或己烷-3-螺环-2-醇的任何反应合成的2-位上的羟基和甲基或羟基和乙基， 1分钟 - 环戊二烯-2-酮与根据待引入的取代基选择的任何试剂。 本发明还提供含有上述物质的香料组合物。