METHOD OF MANUFACTURING CYCLOPHOSPHAZENE DERIVATIVES
    2.
    发明公开
    METHOD OF MANUFACTURING CYCLOPHOSPHAZENE DERIVATIVES 有权
    VERFAHREN ZUR HERSTELLUNG VON CYCLOPHOSPHATDERIVATEN

    公开(公告)号:EP3004122A1

    公开(公告)日:2016-04-13

    申请号:EP14727553.1

    申请日:2014-06-03

    摘要: A method of manufacturing cyclophosphazenes PFPE derivatives to be used in the lubrication of magnetic recording media is herein provided. The method comprises: a) a (per)fluoropolyether (PFPE) polyol [PFPE (Ppol)] comprising a fluoropolyoxyalkylene chain (Rf) having two chain ends, each chain end comprising at least one hydroxy group, and b) the corresponding alkoxide of perfluoropolyether (Ppol) [PFPE (Palk)] wherein the equivalent concentration of PFPE (Palk) in PFPE (Ppol) is lower than 30%, preferably ranging from 5% to 15%; 2) contacting mixture (M) with a perhalocyclophosphazene (CPhalo) to provide a mixture (M1) containing an equivalent ratio of PFPE (Palk)/(CPhalo) of at least 1; 3) allowing mixture (M1) to react until complete disappearance of P—Cl groups to provide a mixture (M2); 4) submitting mixture (M2) to hydrolysis to provide a mixture (M3); 5) optionally removing (Ppol) from mixture (M3) to provide a mixture (M4). A method of purifying mixture (M4) is also herein provided.

    摘要翻译: 本文提供了制造用于润滑磁记录介质的环磷腈PFPE衍生物的方法。 该方法包括:a)包含具有两个链端的氟聚氧化烯链(Rf)的(全)氟聚醚(PFPE)多元醇[PFPE(Ppol)],每个链端包含至少一个羟基,和b)相应的醇盐 全氟聚醚(Ppol)[PFPE(Palk)],其中PFPE(Ppol)中PFPE(Palk)的当量浓度低于30%,优选5%至15%; 2)使混合物(M)与全卤代环丙腈(CPhalo)接触以提供含有至少1的PFPE(Palk)/(CPalO)的当量比的混合物(M1) 3)允许混合物(M1)反应直到P-Cl基团完全消失以提供混合物(M2); 4)将混合物(M2)进行水解以提供混合物(M3); 5)任选地从混合物(M3)中除去(Ppol)以提供混合物(M4)。 还提供了一种纯化混合物(M4)的方法。

    ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES, AND SECONDARY BATTERY
    4.
    发明公开
    ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES, AND SECONDARY BATTERY 审中-公开
    电解质溶液用于水免费二次电池二次电池

    公开(公告)号:EP2763231A4

    公开(公告)日:2015-08-26

    申请号:EP12836601

    申请日:2012-09-21

    申请人: FUJIFILM CORP

    摘要: The present invention provides a nonaqueous electrolyte solution, which can improve flame retardancy and ameliorate performances of a battery without deteriorating the basic battery performance as far as possible, and a secondary battery. The nonaqueous electrolyte solution is a nonaqueous electrolyte solution for a secondary battery that contains metal salts including ions of metals belonging to group 1 or 2 of the periodic table and a specific cyclic compound having phosphorus and nitrogen atoms in a non-protonic solvent. The non-protonic solvent is a solvent that contains at least one kind of carboxylic acid ester compound and carbonic acid ester compound, and a ratio (M PN /Ms) between a mass (Ms) of the non-protonic solvent containing the metal salts and a mass (M PN ) of the cyclic compound is 0.01 to 1.

    ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES, AND SECONDARY BATTERY
    7.
    发明公开
    ELECTROLYTE SOLUTION FOR NONAQUEOUS SECONDARY BATTERIES, AND SECONDARY BATTERY 审中-公开
    ELEKTROLYTLÖSUNGFÜREINE WASSERFREIESEKUNDÄRBATTERIEUNDSEKUNDÄRBATTERIE

    公开(公告)号:EP2763231A1

    公开(公告)日:2014-08-06

    申请号:EP12836601.0

    申请日:2012-09-21

    摘要: The present invention provides a nonaqueous electrolyte solution, which can improve flame retardancy and ameliorate performances of a battery without deteriorating the basic battery performance as far as possible, and a secondary battery. The nonaqueous electrolyte solution is a nonaqueous electrolyte solution for a secondary battery that contains metal salts including ions of metals belonging to group 1 or 2 of the periodic table and a specific cyclic compound having phosphorus and nitrogen atoms in a non-protonic solvent. The non-protonic solvent is a solvent that contains at least one kind of carboxylic acid ester compound and carbonic acid ester compound, and a ratio (M PN /Ms) between a mass (Ms) of the non-protonic solvent containing the metal salts and a mass (M PN ) of the cyclic compound is 0.01 to 1.

    摘要翻译: 本发明提供一种非水电解质溶液,其能够尽可能地改善电池的阻燃性和改善电池的性能而不会使基本电池性能恶化,并且提供二次电池。 非水电解液是含有金属盐的二次电池用非水电解液,所​​述金属盐包括属于周期表第1族或第2族的金属的离子,以及在非质子溶剂中具有磷和氮原子的特定的环状化合物。 非质子溶剂是含有至少一种羧酸酯化合物和碳酸酯化合物的溶剂,和含有金属盐的非质子溶剂的质量(Ms)之间的比(M PN / Ms) 并且环状化合物的质量(M PN)为0.01〜1。

    AZIDIRINO DERIVATIVES OF TETRAMERIC CYCLOPHOSPHAZENES
    10.
    发明公开
    AZIDIRINO DERIVATIVES OF TETRAMERIC CYCLOPHOSPHAZENES 失效
    AZIDIRINO-DERIVATE VON TETRAMEREN-CYCLOPHOSPHAZENEN。

    公开(公告)号:EP0142543A1

    公开(公告)日:1985-05-29

    申请号:EP84902089.0

    申请日:1984-05-07

    IPC分类号: C07F9

    CPC分类号: C07F9/65817

    摘要: Dérivé aziridino d'un composé cyclochlorophosphazène tétramère de formule N4P4Cl8-nAzn, où Az représente un aziridino et n vaut 1, 2, 3, 4, 5, 6 ou 7; procédé pour lier un tel dérivé aziridino par aminolyse dans une solution de réaction d'un composé de formule N4P4Cl8-nAzn, où n vaut 0, 1, 2, 3, 4, 5, ou 6, et récupération du dérivé aziridino obtenu par "chromatographie liquide à rendement élevé", ainsi qu'un dérivé aziridino - basé sur le dérivé aziridino résultant - d'un composé cyclophosphazène substitué tétramère possédant une activité anti-tumorale et de formule N4P4R8-nAzn, où n vaut 1, 2, 3, 4, 5, 6, ou 7 et R représente les mêmes substituants ou des substituants différents.

    摘要翻译: 具有式N4P4Cl8-nAzn的四聚环磷腈腈化合物的氮丙啶衍生物,其中Az表示氮丙啶基,n = 1,2,3,4,5,6或7; 在具有式N4P4Cl8-nAzn的化合物(其中n = 0,1,2,3,4,5或6)的反应溶液中通过氨解解将这种氮丙啶衍生物键合的方法,并且将所得的氮丙啶基衍生物通过 基于所得的氮丙啶衍生物 - 具有抗肿瘤活性并具有式N4P4R8-nAzn的四聚取代环磷腈化合物的“高效液相色谱法”的方法,其中n = 1,2, 3,4,5,6或7,R代表相同或不同的取代基。