Abstract:
Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.
Abstract:
Provided are a heat-resistant synthetic resin microporous film that has both good heat resistance and good mechanical strength and exhibits a suppressed decrease in mechanical strength over time, and a method for producing the heat-resistant synthetic resin microporous film. The heat-resistant synthetic resin microporous film of the present invention includes a synthetic resin microporous film, and a coating layer formed on at least part of the surface of the synthetic resin microporous film and containing a polymer of a polymerizable compound having two or more radically polymerizable functional groups per molecule. The maximum thermal shrinkage rate of the heat-resistant synthetic resin microporous film when heated from 25°C to 180°C at a temperature rising rate of 5 °C/min is 15% or less. The piercing strength thereof is 0.6 N or more. The rate of retention of the piercing strength after heating at 70°C for 168 hours is 85% or more.
Abstract:
Provided are a water dispersion of gel particles in which the gel particles which have a three-dimensional crosslinked structure including a thioether bond and an ethylenic double bond, have a hydrophilic group, and include a photopolymerization initiator are dispersed in water, a producing method of the water dispersion, and an image forming method using the water dispersion.
Abstract:
An object of the invention is to provide a curable composition having a HALS skeleton and capable of producing polymers having excellent weather resistance and outer appearance. The present invention provides a curable composition including at least a monomer component that contains a monomer (A) represented by a certain formula and a monomer (B) polymerizable with the monomer (A). In the curable composition, the content of the monomer (A) is 0.01 to 35 mol% in the monomer component, and the content of the monomer (B) is 65 to 99.99 mol% in the monomer component.
Abstract:
Disclosed is a to provide a curable composition for imprints capable of keeping a good patternability and of producing less defects even after repetitive pattern transfer. The curable composition for imprints comprising: a polymerizable compound (A); a photo-polymerization initiator (B); and a non-polymerizable compound (C) having a polyalkylene glycol structure having at least one terminal hydroxy group, or at least one etherified terminal hydroxy group, and containing substantially no fluorine atom and no silicon atom.
Abstract:
A technology for curing a photocurable resin composition by ultraviolet ray/infrared ray hybrid irradiation is provided. An infrared ray irradiation is applied at least one of before or after the application of ultraviolet ray irradiation to a photocurable resin composition, from which volatile components have been removed by a heating process, to have the photocurable resin composition cured. It becomes possible to relax the ultraviolet ray irradiation conditions for photo curing by applying an infrared ray irradiation as compared with the case in which the infrared ray irradiation is not applied, and, in particular, the scratch resistance characteristics of a cured film are significantly enhanced. Moreover, because of a combination of ultraviolet ray irradiation and infrared ray irradiation, the curing time period of a cured film can be reduced and/or stress relaxation effects can be produced . Besides, it becomes possible to control the reflectance of a cured film by varying an irradiation amount of infrared ray.
Abstract:
The present invention concerns, according to a first aspect, a kit for a polymerisable composition comprising a part A consisting of a composition comprising at least one monomer (a1) reactive towards a cationic species (b) or a Lewis or Brönsted acid species, and at least one coinitiator, and a part B comprising at least one cationic salt (e) chosen from the salts of formulae s1, s3 and s4 represented and defined in claim 1. The present invention concerns, according to a second aspect, a method for producing a coating or a composite material from a polymerisable composition comprising at least one salt (e) chosen from the salts of formulae s1, s2, s3 and s4 represented and defined in claim 10, said composition being polymerised without applying additional heat to the latter.