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1.发明公开CATALYST FOR OLEFIN POLYMERIZATION AND METHOD OF POLYMERIZING OLEFIN 有权KATALYSATOR ZUR OLEFINPOLYMERISIERUNG UND VERFAHREN ZUR OLEFINPOLYMERISIERUNG
公开(公告)号：EP0990664A1
公开(公告)日：2000-04-05
申请号：EP99913677.3
申请日：1999-04-15
发明人： MATSUI, Shigekazu Mitsui Chemicals, Inc. , NITABARU, Masatoshi Mitsui Chemicals, Inc. , TSURU, Kazutaka Mitsui Chemicals, Inc. , FUJITA, Terunori Mitsui Chemicals, Inc. , SUZUKI, Yasuhiko Mitsui Chemicals, Inc. , TAKAGI, Yukihiro Mitsui Chemicals, Inc. , TANAKA, Hidetsugu Mitsui Chemicals, Inc.
CPC分类号： C08F10/00 , C08F110/02 , C08F4/659 , C08F2500/17 , C08F4/64051 , C08F4/64044 , C08F4/64048 , C08F4/6411 , C08F4/6412 , C08F4/7008 , C08F4/7054 , C08F4/64113 , C08F4/64148 , C08F4/64151 , C08F4/64141
摘要： The present invention is intended to provide an olefin polymerization catalyst comprising a novel transition metal compound and having an excellent olefin polymerization activity and to provide a process for olefin polymerization using this catalyst. The olefin polymerization catalyst comprises a transition metal compound (A-1) represented by the formula (I) or a transition metal compound (A-2) represented by the formula (II), and optionally, at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and a compound (B-3) which reacts with the transition metal compound (A-1) or (A-2) to form an ion pair.
wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table; m in the formula (I) is an integer of 1 to 3, and m in the formula (II) is an integer of 1 to 6; Q is -N= or -C(R 2 )=; A is -O-, -S-, -Se- or -N(R 6 )-; R 1 to R 6 are each a hydrogen atom, a hydrocarbon group or the like, and two or more of them may be bonded to form a ring; n is a number satisfying a valence of M; and X is a halogen atom, a hydrocarbon group or the like.摘要翻译： 本发明旨在提供一种包含新型过渡金属化合物并具有优异的烯烃聚合活性的烯烃聚合催化剂，并提供使用该催化剂的烯烃聚合方法。 烯烃聚合催化剂包含由式（I）表示的过渡金属化合物（A-1）或由式（II）表示的过渡金属化合物（A-2），和任选的至少一种选自 由与过渡金属化合物（A-1）或（A-2）反应的有机金属化合物（B-1），有机铝氧化合物（B-2）和化合物（B-3） 形成离子对。
其中M是周期表第3族至第11族的过渡金属原子; 式（I）中的m为1〜3的整数，式（II）中的m为1〜6的整数， Q是-N =或-C（R 2）=; A是-O - ， - S - ， - S-或-N（R 6） - ; R 1至R 6各自为氢原子，烃基等，并且它们中的两个或多个可以键合形成环; n是满足M价的数; X为卤素原子，烃基等。 -
公开(公告)号：EP2900702B1
公开(公告)日：2018-05-02
申请号：EP13841099.8
申请日：2013-09-30
发明人： LUO, Steven , QIN, Zengquan
CPC分类号： C07F5/003 , C08F4/545 , C08F4/64117 , C08F4/6412 , C08F36/06 , C08F136/06 , C08F236/06 , C08F10/00 , C08F36/04
摘要： A novel class of organometallic complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes.
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3.发明公开
公开(公告)号：EP2050769A2
公开(公告)日：2009-04-22
申请号：EP09000431.8
申请日：1999-04-15
发明人： Matsui, Shigekazu , Nitabaru, Masatoshi , Tsuru, Kazutaka , Fujita, Terunori , Suzuki, Yasuhiko , Takagi, Yukihiro , Tanaka, Hidetsugu
CPC分类号： C08F10/00 , C08F110/02 , C08F4/659 , C08F2500/17 , C08F4/64051 , C08F4/64044 , C08F4/64048 , C08F4/6411 , C08F4/6412 , C08F4/7008 , C08F4/7054 , C08F4/64113 , C08F4/64148 , C08F4/64151 , C08F4/64141
摘要： The present invention is intended to provide an olefin polymerization catalyst comprising a transition metal compound and having an excellent olefin polymerization activity and to provide a process for olefin polymerization using this catalyst. The olefin polymerization catalyst comprises a transition metal compound (A-2) represented by the formula (II-b) and further comprises at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and a compound (B-3) which reacts with the transition metal compound (A-2) to form an ion pair.
(wherein M, m, A, R 1 , R 2 , R 7 - R 10 , n and X are further defined in the specification).摘要翻译： 本发明旨在提供一种包含过渡金属化合物并具有优异的烯烃聚合活性的烯烃聚合催化剂，并提供使用该催化剂的烯烃聚合方法。 烯烃聚合催化剂包含由式（II-b）表示的过渡金属化合物（A-2），并且还包含至少一种选自以下的化合物（B）：有机金属化合物（B-1），有机铝 氧化合物（B-2）和与过渡金属化合物（A-2）反应形成离子对的化合物（B-3）。 （其中M，m，A，R 1，R 2，R 7 -R 10，n和X在说明书中进一步定义）。
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4.发明授权POLYMERISATION OF ETHYLENE AND ALPHA OLEFINS WITH SINGLE SITE CATALYSTS HAVING AN ANIONIC SCORPION-LIKE LIGAND 有权聚合使用与阴离子SKORPIONARTIGEM配体的单中心催化剂ETHLYEN和α-烯烃
公开(公告)号：EP2089399B1
公开(公告)日：2012-08-08
申请号：EP07857204.7
申请日：2007-11-09
IPC分类号： C07F7/00 , C07F11/00 , C07C251/16 , C07D213/53 , C07D215/12 , C08F4/70 , C08F10/00 , C08F4/622
CPC分类号： C07F7/006 , B01J31/1815 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , C07C251/16 , C07D213/53 , C07D215/12 , C07F11/005 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F4/64113 , C08F4/69284 , C08F4/7054 , C08F4/69301 , C08F4/68284 , C08F4/6412
摘要： The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
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公开(公告)号：EP0990664B1
公开(公告)日：2009-03-11
申请号：EP99913677.3
申请日：1999-04-15
发明人： MATSUI, Shigekazu Mitsui Chemicals, Inc. , NITABARU, Masatoshi Mitsui Chemicals, Inc. , TSURU, Kazutaka Mitsui Chemicals, Inc. , FUJITA, Terunori Mitsui Chemicals, Inc. , SUZUKI, Yasuhiko Mitsui Chemicals, Inc. , TAKAGI, Yukihiro Mitsui Chemicals, Inc. , TANAKA, Hidetsugu Mitsui Chemicals, Inc.
CPC分类号： C08F10/00 , C08F110/02 , C08F4/659 , C08F2500/17 , C08F4/64051 , C08F4/64044 , C08F4/64048 , C08F4/6411 , C08F4/6412 , C08F4/7008 , C08F4/7054 , C08F4/64113 , C08F4/64148 , C08F4/64151 , C08F4/64141
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6.发明公开HETEROCYCLE-AMINE LIGANDS, COMPOSITIONS, COMPLEXES, AND CATALYSTS, AND METHODS OF MAKING AND USING THE SAME 审中-公开配体，组合物复杂，催化剂从杂环胺和方法的生产和使用
公开(公告)号：EP1794196A2
公开(公告)日：2007-06-13
申请号：EP05800266.8
申请日：2005-09-21
发明人： DIAMOND, Gary , LAPOINTE, Anne, M. , LECLERC, Margarete, K. , LONGMIRE, James , NAVA-SALGADO, Victor , SHOEMAKER, James, A.W. , SUN, Pu
CPC分类号： C07F7/006 , C07F7/00 , C07F7/28 , C08F10/00 , C08F110/06 , C08F210/16 , C08F2500/03 , C08F210/14 , C08F2500/04 , C08F4/64151 , C08F4/64117 , C08F4/6412 , C08F4/64044 , C08F4/64144
摘要： Ligands, compositions, and metal-ligand complexes that incorporate heterocycle-amine compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene to form isotactic polypropylene.
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公开(公告)号：EP2900702A1
公开(公告)日：2015-08-05
申请号：EP13841099.8
申请日：2013-09-30
发明人： LUO, Steven , QIN, Zengquan
CPC分类号： C07F5/003 , C08F4/545 , C08F4/64117 , C08F4/6412 , C08F36/06 , C08F136/06 , C08F236/06 , C08F10/00 , C08F36/04
摘要： A novel class of organometallic complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes.
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公开(公告)号：EP2050769B1
公开(公告)日：2013-05-22
申请号：EP09000431.8
申请日：1999-04-15
发明人： Matsui, Shigekazu , Nitabaru, Masatoshi , Tsuru, Kazutaka , Fujita, Terunori , Suzuki, Yasuhiko , Takagi, Yukihiro , Tanaka, Hidetsugu
CPC分类号： C08F10/00 , C08F110/02 , C08F4/659 , C08F2500/17 , C08F4/64051 , C08F4/64044 , C08F4/64048 , C08F4/6411 , C08F4/6412 , C08F4/7008 , C08F4/7054 , C08F4/64113 , C08F4/64148 , C08F4/64151 , C08F4/64141
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9.发明公开POLYMERISATION OF ETHYLENE AND ALPHA OLEFINS WITH SINGLE SITE CATALYSTS HAVING AN ANIONIC SCORPION-LIKE LIGAND 有权聚合使用与阴离子SKORPIONARTIGEM配体的单中心催化剂ETHLYEN和α-烯烃
公开(公告)号：EP2089399A1
公开(公告)日：2009-08-19
申请号：EP07857204.7
申请日：2007-11-09
IPC分类号： C07F7/00 , C07F11/00 , C07C251/16 , C07D213/53 , C07D215/12 , C08F4/70 , C08F10/00 , C08F4/622
CPC分类号： C07F7/006 , B01J31/1815 , B01J2231/122 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/62 , C07C251/16 , C07D213/53 , C07D215/12 , C07F11/005 , C08F10/00 , C08F110/02 , C08F2500/20 , C08F4/64113 , C08F4/69284 , C08F4/7054 , C08F4/69301 , C08F4/68284 , C08F4/6412
摘要： The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
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公开(公告)号：EP2900702A4
公开(公告)日：2016-06-08
申请号：EP13841099
申请日：2013-09-30
申请人： BRIDGESTONE CORP
发明人： LUO STEVEN , QIN ZENGQUAN
CPC分类号： C07F5/003 , C08F4/545 , C08F4/64117 , C08F4/6412 , C08F36/06 , C08F136/06 , C08F236/06 , C08F10/00 , C08F36/04
摘要： A novel class of organometallic complexes can be used as an ingredient of a catalyst system. The catalyst system can be used in polymerizations of ethylenically unsaturated hydrocarbon monomers that include both olefins and polyenes.
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