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公开(公告)号：EP0556005B1
公开(公告)日：1996-04-17
申请号：EP93300892.2
申请日：1993-02-08
CPC分类号： C09K11/06 , C07F9/5355 , C07F9/5357 , C09K11/04
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公开(公告)号：EP0688849B1
公开(公告)日：2000-01-12
申请号：EP95115390.7
申请日：1993-02-08
申请人： Nycomed Amersham plc
CPC分类号： C09K11/06 , C07F9/5355 , C07F9/5357 , C09K11/04
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公开(公告)号：EP0579600A1
公开(公告)日：1994-01-26
申请号：EP91908028.0
申请日：1991-04-12
摘要： Compositions électroluminescentes transparentes comprenant le mélange d'un polymère, par exemple un poly (vinyle aromatique) hydrocarbone tritié ainsi que d'un premier et de préférence un deuxième composé organique. Le premier composé organique, qui est au moins partiellement lié au polymère, peut être un scintillateur connu tel que 2,5-diphényloxazole. Le deuxième composé peut être un décaleur spectral connu tel que 2,2'-p-phénylène-bis-(5-phényloxazole).
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公开(公告)号：EP0744451B1
公开(公告)日：1999-07-21
申请号：EP95303551.6
申请日：1995-05-25
CPC分类号： C09K11/06 , C07F9/5325 , C07F9/5355 , C09K11/04 , H01L51/0089 , H01L51/5012
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公开(公告)号：EP0913448A1
公开(公告)日：1999-05-06
申请号：EP98122846.3
申请日：1995-05-25
申请人： Nycomed Amersham PLC
CPC分类号： C09K11/06 , C07F9/5325 , C07F9/5355 , C09K11/04 , H01L51/0089 , H01L51/5012
摘要： Novel compounds obtainable by reacting together an imido-reagent such as diphenylphosphonimido-triphenylphosphorane), or a phosphine oxide such as p-tolyldiphenylphosphine oxide, with a chelate of a transition or lanthanide or actinide metal, such as tris(dibenzoylmethide) europium III, have the property of fluorescing in UV radiation. The invention includes solid polymer bodies containing such compounds, or chelates of transition or lanthanide or actinide metals generally, the bodies having the property of emitting light or infra-red radiation when subjected to a flux of ultra-violet or ionising radiation by virtue of internally generated, e.g. by tritium ionising radiation. The body is preferably of polystyrene formed by polymerising the monomer in the presence of the compound or metal chelate.
摘要翻译： 通过使亚氨基试剂如二苯基亚膦酰基 - 三苯基正膦等一起反应得到的新型化合物，或氧化膦如对二苯基二苯基氧化膦与过渡或镧系元素或锕系金属如三（二苯甲酰甲基甲酰）铕III的螯合物， 在紫外线辐射下发荧光的特性。 本发明包括含有这种化合物的固体聚合物体，或过渡或镧系元素或锕系金属的螯合物，通常具有当经受紫外线或电离辐射的通量时具有发出光或红外辐射的性质的本体 生成，例如 通过氚电离辐射。 身体优选是通过在化合物或金属螯合物的存在下聚合单体而形成的聚苯乙烯。
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公开(公告)号：EP0206245A3
公开(公告)日：1988-01-07
申请号：EP86108326
申请日：1986-06-19
发明人： Brown, Roy N. , Stout, Mike F. , Hagen, Arnulf P. , Garwin, Leo
CPC分类号： C04B41/009 , C04B41/4922 , C04B41/4944 , C04B41/4961 , C04B41/4977 , C04B41/64 , C09D5/22 , C09K11/04 , C09K11/06 , E01C7/085 , E01C7/35 , C04B41/463 , C04B41/4927 , C04B28/02
摘要： A luminescent compound comprising an oligomer or a limited molecular weight polymer of an alkylalkoxysilane comprising a phosphor group or groups, and a luminescent composition comprising such luminescent compound and a radioactive substance to provide a source of exciting radiation for the luminescent compound in the composition. The present invention further comprises a method for rendering silliceous surfaces luminescent comprising applying the compound or composition to the surface and reacting the compound or composition with water after the compound or composition has migrated into the surface to hydrolyze the compound or composition. The present invention further comprises a luminescent structure having a siliceous surface incorporating the products of the reaction between the surface, water and the compound or composition of the present invention.
摘要翻译： 包含荧光体基团和烷基烷氧基硅烷的发光化合物和包含这种发光化合物和放射性物质的发光组合物，以提供组合物中发光化合物的激发辐射源。 本发明还包括一种用于制备发光的硅质表面的方法，包括将化合物或组合物施用于表面，并且在化合物或组合物迁移到表面中以水解化合物或组合物之后，化合物或组合物与水反应。 本发明还包括具有掺入表面，水和本发明化合物或组合物之间的反应产物的硅质表面的发光结构。
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公开(公告)号：EP0206245A2
公开(公告)日：1986-12-30
申请号：EP86108326
申请日：1986-06-19
申请人： ADVANCED CHEM TECH
发明人： BROWN ROY N , STOUT MIKE F , HAGEN ARNULF P , GARWIN LEO
IPC分类号： C07F7/18 , C04B41/49 , C04B41/64 , C09D5/22 , C09K11/04 , C09K11/06 , E01C7/08 , E01C7/35 , C09K11/02
CPC分类号： C04B41/009 , C04B41/4922 , C04B41/4944 , C04B41/4961 , C04B41/4977 , C04B41/64 , C09D5/22 , C09K11/04 , C09K11/06 , E01C7/085 , E01C7/35 , C04B41/463 , C04B41/4927 , C04B28/02
摘要： A luminescent compound comprising an oligomer or a limited molecular weight polymer of an alkylalkoxysilane comprising a phosphor group or groups, and a luminescent composition comprising such luminescent compound and a radioactive substance to provide a source of exciting radiation for the luminescent compound in the composition. The present invention further comprises a method for rendering silliceous surfaces luminescent comprising applying the compound or composition to the surface and reacting the compound or composition with water after the compound or composition has migrated into the surface to hydrolyze the compound or composition. The present invention further comprises a luminescent structure having a siliceous surface incorporating the products of the reaction between the surface, water and the compound or composition of the present invention.
摘要翻译： 包含含有磷光体基团的烷基烷氧基硅烷的低聚物或有限分子量聚合物的发光化合物，以及包含这种发光化合物和放射性物质的发光组合物，以为组合物中的发光化合物提供激发辐射源。 本发明进一步包括使硅石表面发光的方法，该方法包括将化合物或组合物施加到表面上，并在化合物或组合物迁移到表面中以使化合物或组合物水解后使化合物或组合物与水反应。 本发明进一步包括具有硅质表面的发光结构，所述硅质表面包含表面，水和本发明的化合物或组合物之间的反应产物。
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公开(公告)号：EP1007634A1
公开(公告)日：2000-06-14
申请号：EP98939412.7
申请日：1998-08-14
发明人： POPE, Edward, J., A.
CPC分类号： A61K47/02 , A61K9/1611 , A61K9/1694 , A61K2035/126 , A61L27/38 , C03C4/0007 , C09K11/02 , C09K11/04 , C09K11/06 , C09K11/592 , C09K11/7734 , C12N11/04 , G02F1/0102 , G02F1/133617 , H01J29/32
摘要： Living tissue cells such as from an animal or a plant are encapsulated in inorganic microspheres. An organosilicon precursor such as tetraethoxysilane or an organometallic precursor such as aluminum tri-n-propoxide is hydrolyzed in an aqueous acidic solution to form a gel forming solution. Tissue cells are mixed with a salt solution such as Hanks' Balanced Salt Solution to form a solution containing the tissue cells. The solution containing tissue cells and the gel forming solution are mixed to form a mixture. The mixture is mixed with an oil that is immiscible with the mixture and has a lower specific density than the mixture. The resultant mixture is stirred to form microspheres encapsulating the tissue cells. The mixture containing the tissue cells and the gel forming solution may be formed into droplets and added to the top of a column containing the oil to form the microspheres.
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公开(公告)号：EP0744451A1
公开(公告)日：1996-11-27
申请号：EP95303551.6
申请日：1995-05-25
CPC分类号： C09K11/06 , C07F9/5325 , C07F9/5355 , C09K11/04 , H01L51/0089 , H01L51/5012
摘要： Novel compounds obtainable by reacting together an imido-reagent such as diphenylphosphonimidotriphenylphosphorane), or a phosphine oxide such as p-tolyldiphenylphosphine oxide, with a chelate of a transition or lanthanide or actinide metal, such as tris(dibenzoylmethide) europium III, have the property of fluorescing in UV radiation. The invention includes solid polymer bodies containing such compounds, or chelates of transition or lanthanide or actinide metals generally, the bodies having the property of emitting light or infra-red radiation when subjected to a flux of ultra-violet or ionising radiation by virtue of internally generated, e.g. by tritium ionising radiation. The body is preferably of polystyrene formed by polymerising the monomer in the presence of the compound or metal chelate.
摘要翻译： 通过使亚氨基试剂如二苯基膦酰亚氨基三苯基正膦等一起反应得到的新型化合物或氧化膦如对甲苯基二苯基氧化膦与过渡金属或镧系元素的螯合物或锕系金属如三（二苯甲酰甲基甲脒）铕III具有的性质 的紫外线辐射。 本发明包括含有这种化合物的固体聚合物体，或过渡或镧系元素或锕系金属的螯合物，通常具有当经受紫外线或电离辐射的通量时具有发出光或红外辐射的性质的本体 生成，例如 通过氚电离辐射。 身体优选是通过在化合物或金属螯合物的存在下聚合单体而形成的聚苯乙烯。
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公开(公告)号：EP0556005A1
公开(公告)日：1993-08-18
申请号：EP93300892.2
申请日：1993-02-08
CPC分类号： C09K11/06 , C07F9/5355 , C07F9/5357 , C09K11/04
摘要： Novel compounds obtainable by reacting together an imido-reagent such as diphenylphosphonimido-triphenylphosphorane) with a chelate of a transition or lanthanide or actinide metal, such as tris(dibenzoylmethide) europium III, has the property of fluorescing in UV radiation. The invention includes solid polymer bodies containing such compounds, or chelates of transition or lanthanide or actinide metals generally, the bodies having the property of emitting light by virtue of internally generated, e.g. by tritium ionising radiation. The body is preferably of polystyrene formed by polymerising the monomer in the presence of the compound or metal chelate.
摘要翻译： 通过使亚氨基试剂如二苯基亚膦酰基 - 三苯基正膦一起反应得到的新型化合物与过渡或镧系元素或锕系金属如三（二苯甲酰甲基甲酰）铕III的螯合物具有UV辐射荧光的性质。 本发明包括含有这些化合物的固体聚合物体，或过渡金属或镧系元素或锕系金属的螯合物，通常具有通过内部产生的发光特性的物质，例如， 通过氚电离辐射。 身体优选是通过在化合物或金属螯合物的存在下聚合单体而形成的聚苯乙烯。
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